Studying the Effect of Low α-Radiation Doses on CR-39 Polymers Using Positron Annihilation Lifetime and Mechanical Properties

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Positron annihilation lifetime spectroscopy (PALS) is one of the unique tools for studying free-volume defects in solid media. The microhardness test offers a simple and nondestructive tool for investigating the mechanical behavior of polymer materials. Polyallyl diglycol carbonate (CR-39) track detectors have a variety of applications in science and technology. PALS measurements and microhardness tests were verified for CR-39 irradiated with different doses of alpha particles (0 - 69.20 mGy). The variations in free volume hole size and fractional free volume were obtained by using the PALS method. The small free volume hole sizes were found at doses 27.68 and 44.98 mGy. The microhardness test for the two doses yielded medium values.

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77-83

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December 2012

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© 2012 Trans Tech Publications Ltd. All Rights Reserved

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[1] H. Zhou, M. Suzuki, G. Randers-Pehrson, D. Vannais, G. Chen, C.A. Waldren, T.K. Hei, Proceedings of the National Academy of Sciences of the United States of America (PNAS), 98.

Google Scholar

[25] (2001).

Google Scholar

[2] A. Atul Kulkarni, C.K. Vyas, H. Kim, P.C. Kalsi, T. Kim, V. Manchanda, Online optical monitor of alpha radiations using a polymeric solid state nuclear track detector CR-39, Sensors and Actuators B, 161 (2012) 697-701.

DOI: 10.1016/j.snb.2011.11.016

Google Scholar

[3] R.L. Fleischer, P.B. Price, R.M. Walker, Nuclear Tracks in Solids, University of California Press, Berkeley, CA, (1975).

Google Scholar

[4] L.H. Sperling, Introduction to Physical Polymer Science, John Wiley & Sons, Inc., (2006).

Google Scholar

[5] A. Dupasquier, A.P. Mills, Editors, Positron Spectroscopy of Solids, North-Holland, Amsterdam, (1995).

Google Scholar

[6] Ismayil, V. Ravindrachary, R.F. Bhajantri, S.D. Praveena, B. Poojary, D. Dutta, P.K. Pujari, Optical and microstructural studies on electron-irradiated PMMA: a positron annihilation study, Polymer Degradation and Stability 95 (2010) 1083-91.

DOI: 10.1016/j.polymdegradstab.2010.02.031

Google Scholar

[7] B.L. Evans, The microhardness of injection moulded polystyrene and polyethylene. Journal of Materials Science, 24 (1989) 173-82.

Google Scholar

[8] P.K. Dubey, R. Bajpai, J.M. Keller, Structural, morphological and microhardness characterization in polymer complex of laser dye rhodamine (Rh6G) doped polymethyl methacrylate, Microsyst. Technol., 14 (2008) 1165-71.

DOI: 10.1007/s00542-008-0650-z

Google Scholar

[9] W. Enge, Introduction to plastic nuclear track detectors. Nuclear Tracks, 4 (1980) 283-308.

Google Scholar

[10] M.F. Eissa, Optical properties of CR-39 track etch detectors irradiated by alpha particles with different energies. Journal of Materials Science and Engineering, 5 (2011) 26-31.

Google Scholar

[11] E.H. Lee, G.R. Rao, L.K. Mansur, LET Effect on cross-linking and scission mechanisms of PMMA during irradiation, Radiation Physics and Chemistry, 55 (1999) 293-305.

DOI: 10.1016/s0969-806x(99)00184-x

Google Scholar

[12] F. Ziegler, SRIM-2008, available online at: www. SRIM2008. org.

Google Scholar

[13] J. Kansy, Programs for positron lifetime analysis adjusted to the PC Windows environment. Materials Science Forum, 363-365 (2001) 652- 4.

DOI: 10.4028/www.scientific.net/msf.363-365.652

Google Scholar

[14] S.J. Tao, Positronium annihilation in molecular substances. Journal of Chemical Physics, 56 (1972) 5499-510.

Google Scholar

[15] M. Eldrup, D. Lightbody, N. Sherwood, The temperature dependence of positron lifetimes in solid cyclohexane. Journal of Chemical Physics, 63 (1981) 51-8.

DOI: 10.1016/0301-0104(81)80307-2

Google Scholar

[16] H. Nakanishi, S.J. Wang, Y.C. Jean in S.C. Sharma (Ed. ). Positron Annihilation Studies of Fluids, World Scientific, Singapore, (1988).

Google Scholar

[17] Y.Y. Wang, H. Nakanishi, Y.C. Jean, T.C. Sandreczki, Positron annihilation in amine-cured epoxy polymers - pressure dependence, Journal of Polymer Science B, 28 (1990) 1431-41.

DOI: 10.1002/polb.1990.090280902

Google Scholar

[18] R. Kumar, S. Rajguru, D. Das, R. Prasad, SHI induced modification in CR-39 polycarbonate by positron annihilation lifetime studies, Radiat. Meas., 36 (2003) 151-4.

DOI: 10.1016/s1350-4487(03)00113-6

Google Scholar