Control of Particle Size and Morphology of MOF-199 Crystals via a Reaction-Diffusion Framework

Razan Issa; Mohamad Hmadeh; Mazen Al-Ghoul

doi:10.4028/www.scientific.net/DDF.380.39

Paper Titles

Designing, Processing and Isothermal Transformation of Al-Si Medium Carbon Ultrafine High Strength Bainitic Steel
p.1

Metallurgists’ Insights on Diffusion-Assisted Dissimilar-Joints of Light- and Heavy-Alloys
p.12

Growth Kinetics and Mechanical Characterization of a Hard Boron Coating on a Tool Steel
p.29

Structure of Partly Vacuum Extracted MgH₂ Samples
p.35

Control of Particle Size and Morphology of MOF-199 Crystals via a Reaction-Diffusion Framework
p.39

Transient Liquid Diffusion Bonding of AISI304 Stainless Steel with a Nickel Base Interlayer
p.48

Moisture Measuring Device Based on Non-Destructive Method of Gamma Ray’s Attenuation
p.55

Manufacturing Fiber-Reinforced Polymer Composite Using RTM Process: An Analytical Approach
p.60

The Effect of the Drying Temperature on the Moisture Removal and Mechanical Properties of Sisal Fibers
p.66

HomeDefect and Diffusion ForumDefect and Diffusion Forum Vol. 380Control of Particle Size and Morphology of MOF-199...

Control of Particle Size and Morphology of MOF-199 Crystals via a Reaction-Diffusion Framework

Abstract:

A reaction-diffusion framework (RDF) is used to synthesize and control the size and morphology of single crystals of metal-organic framework-199 (MOF-199). The framework consists of diffusing copper ions (Cu²⁺, outer electrolyte) into a hydrogel medium containing the organic linker, 1,3,5-benzenetricarboxylic acid (BTC, inner electrolyte). The resulting supersaturation gradient, and its nonlinear coupling with nucleation and growth kinetics, provides means to control the crystal size, distrubution and morphology along the diffusion flux. This method is rapid, efficient, scalable, and environmentally friendly. By using this method we demonstrate how assorted experimental parameters, such as temperature, concentrations, and nature of the gel matrix can be easily tuned to produce different particle size distributions and various morphologies.

You might also be interested in these eBooks

Recent Trends in Mass Transport in Solids and Liquids

View Preview

Info:

Periodical:

Defect and Diffusion Forum (Volume 380)

Pages:

39-47

DOI:

https://doi.org/10.4028/www.scientific.net/DDF.380.39

Citation:

Cite this paper

Online since:

November 2017

Authors:

Razan Issa*, Mohamad Hmadeh, Mazen Al-Ghoul

Keywords:

Crystal Growth, Metal-Organic Framework, MOF-199, Nucleation, Reaction-Diffusion

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

Citation:

* - Corresponding Author

References

[1] H. Furukawa, K.E. Cordova, M. O'Keeffe, O.M. Yaghi: Science Vol. 341 (2013), pp.1230444-12.

Google Scholar

[2] L.E. Kreno, K. Leong, O.K. Farha, M. Allendorf, R.P. Van Duyne, J.T. Hupp: Chem. Rev. Vol. 112 (2012), pp.1105-1125.

DOI: 10.1021/cr200324t

Google Scholar

[3] C.V. McGuire, R.S. Forgan: Chem. Commun. Vol. 51 (2015), pp.5199-5217.

Google Scholar

[4] A.J. Howarth, Y. Liu, P. Li, Z. Li, T.C. Wang, J.T. Hupp, O.K. Farha: Nat. Rev. Mater. Vol. 1 (2016), pp.1-15.

Google Scholar

[5] O.M. Yaghi, M. O'Keeffe, N.W. Ockwig, H.K. Chae, M. Eddaoudi, J. Kim: Nature Vol. 423 (2003), pp.705-714.

DOI: 10.1038/nature01650

Google Scholar

[6] A. Macchioni, Ion pairing in transition-metal organometallic chemistry, Chem. Rev. Vol. 105 (2005), p.2039-(2074).

DOI: 10.1021/cr0300439

Google Scholar

[7] X. Huang, Y. Chen, Z. Lin, X. Ren, Y. Song, Z. Xu, X. Dong, X. Li, C. Hu, B. Wang: Chem. Commun. Vol. 50 (2014), pp.2624-2627.

Google Scholar

[8] V.I. Isaeva, E.V. Belyaeva, A.N. Fitch, V.V. Chernyshev, S.N. Klyamkin, L.M. Kustov: Cryst. Growth Des. Vol. 13 (2013), pp.5305-5315.

DOI: 10.1021/cg401106z

Google Scholar

[9] A. Coskun, M. Hmadeh, G. Barin, F. Gándara, Q. Li, E. Choi, N.L. Strutt, D.B. Cordes, A.M. Slawin, J.F. Stoddart: Angew. Chem. Int. Ed. (English) Vol. 51 (2012), pp.2160-2163.

DOI: 10.1002/anie.201107873

Google Scholar

[10] H. Deng, S. Grunder, K.E. Cordova, C. Valente, H. Furukawa, M. Hmadeh, F. Gándara, A.C. Whalley, Z. Liu, S. Asahina: Science Vol. 336 (2012), pp.1018-1023.

DOI: 10.1126/science.1220131

Google Scholar

[11] G.A. Al Akhrass, M. Ammar, H. El-Rassy, M. Al-Ghoul: RSC Adv. Vol. 6 (2016), pp.3433-3439.

DOI: 10.1039/c5ra22692a

Google Scholar

[12] P. Zhao, G.I. Lampronti, G.O. Lloyd, M.T. Wharmby, S. b. Facq, A.K. Cheetham, S.A. Redfern: Chem. Mat. Vol. 26 (2014), pp.1767-1769.

DOI: 10.1021/cm500407f

Google Scholar

[13] D. Saliba, A. Ezzeddine, A. -H. Emwas, N.M. Khashab, M. Al-Ghoul: Cryst. Growth Des. Vol. 16 (2016), pp.4327-4335.

Google Scholar

[14] D. Saliba, A. Ezzeddine, R. Sougrat, N.M. Khashab, M. Hmadeh, M. Al‐Ghoul: ChemSusChem Vol. 9 (2016), pp.800-805.

DOI: 10.1002/cssc.201600088

Google Scholar