Analysis of the TiO2 Nanotubes Structure Ordering in the Correlation-Spectral Representation

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In the paper, the array ordering of the TiO2 nanotubes obtained by method of the anodic oxidation in different modes in the fluorine-containing aqueous-non-aqueous electrolytes containing glycerin as well as the surface-active reagents is considered. It was shown that such characteristics as the two-dimensional Fourier-spectrum, autocorrelation function and its spectrum allow us to identify the ordering nature and to obtain the preliminary quantitative estimates of SEM order.

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353-358

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September 2018

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© 2018 Trans Tech Publications Ltd. All Rights Reserved

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[1] J.M. Macak, Wachstum anodischer selbst-organisierter Titandioxid Nanoröhren Schichten, Ph.D. thesis, University of Erlangen-Nurnberg, (2008).

Google Scholar

[2] D.I. Petukhov, I.V. Kolesnik, A.A. Eliseev, A.V. Lukashin, and Yu.D. Tretyakov, Al'ternativnaya energetika i ekologiya 45 (2007) 65-69.

Google Scholar

[3] Yu.A. Chaplygin, Nanotechnology in electronics, Tekhnosfera, Moscow, (2013).

Google Scholar

[4] A.N. Belov, The formation of nanostructures based on porous anodic metal oxides, Ph.D. thesis, Moscow State University, (2011).

Google Scholar

[5] A.N. Belov, I.M. Gavrilin, S.A. Gavrilov, A.A. Dronov, and A.S. Shulyatyev, Highly ordered arrays of TiO2 nanotubes in photovoltaic converters on flexible media, Izvestiya Vuzov. Elektronika. 88 (2011) 39-40.

Google Scholar

[6] D. Fang, Z. Lio, K. Huang, and D.C. Lagoudas, Effect of heat treatment on morphology, crystalline structure and photocatalysis properties of TiO2 nanotubes on Ti substrate and freestanding membrane, App. Surface S. 257 (2011) 6451-6461.

DOI: 10.1016/j.apsusc.2011.02.037

Google Scholar

[7] J.M. Macak, P.J. Barczuk, H. Tsuchiya, M.Z. Novakovska, A. Ghicov, M. Chojak, S. Bauer, S. Virtanen, P.J. Kulesza, and P. Schmuki, Self-organized nanotubular TiO2 matrix as support for dispersed Pt/Ru nanoparticles: Enhancement of the electrocatalytic oxidation of methanol, Electrochem. Comm. 7 (2005).

DOI: 10.1016/j.elecom.2005.09.031

Google Scholar

[8] J.M. Macak, H. Tsuchiya, A. Ghicov, K. Yasuda, R. Hahn, S. Bauer, and P. Schmuki, TiO2 nanotubes: Self-organized electrochemical formation, properties and applications, Current Opinion in Solid State and Materials Sci. 11 (2007) 3-18.

DOI: 10.1016/j.cossms.2007.08.004

Google Scholar

[9] A. Fujishima and K. Honda, Electrochemical Photolysis of Water at a Semi-conductor Electrode, Nature 238 (1972) 37-38.

DOI: 10.1038/238037a0

Google Scholar

[10] M.V.H. Rao, B.K. Mathur, K.L. Chopra, Evaluation of the scaling exponent of selfaffine fractal surface from a single scanning probe microscope image, App. Phys. Lett. 65 (1994) 124-126.

DOI: 10.1063/1.113055

Google Scholar

[11] A. Mihalyuk, P. Titov, V. Yudin, Penrose tiling fractality in coordination Cayley's tree graphs representation, Physica A 389 (2010) 4127-4139.

DOI: 10.1016/j.physa.2010.06.008

Google Scholar

[12] S.P. Petrovic, L. Rozic, Morphology and fractal Dimension of TiO2 thin films, Maced. J. Chem. Chem. Eng. 32 (2013) 309-317.

Google Scholar

[13] V.V. Yudin, P.L. Titov, A.N. Mikhalyuk, Percolation of entropy functionals on Cayley tree graphs as a method of order-disorder character diagnostics of complex structure, Bulletin of the RAS: Physics 73 (2009) 1269-1276.

DOI: 10.3103/s1062873809090202

Google Scholar

[14] O.V. Lozovaya, M.P. Tarasevich, I.V. Bogdanovskaya, I.V. Kasatkina, and A.I. Scherbakova, Electrochemical synthesis, investigation and modification of TiO2 nanotubes, Fizikokhimiya poverkhnosti i zaschita materialov 47 (2011) 45-50.

Google Scholar

[15] D. Jasin, A. Abu-Rabi, S. Mentus, and D. Jovanovic, Oxygen reduction reaction on spontaneously and potentiodynamically formed Au/TiO2 composite, Electrochim. Acta. 52 (2007) 4581-4588.

DOI: 10.1016/j.electacta.2006.12.071

Google Scholar

[16] N.B. Kondrikov, P.L. Titov, S.A. Schegoleva, M.A. Khorin, Influence of formation conditions on the level of arrays ordering of anodic titanium oxide nanotubes, Physics Procedia 86 (2017) 37-43.

DOI: 10.1016/j.phpro.2017.01.015

Google Scholar

[17] M.B. Priestley, Spectral analysis and time series, Academic Press, New York, (1982).

Google Scholar

[18] P.F. Dunn, Measurement and Data Analysis for Engineering and Science, McGraw-Hill, New York, (2005).

Google Scholar

[19] V.V. Yudin, P.L. Titov, A.N. Mikhalyuk, Entropic measure of the order-disorder character in lattice systems in the representation of coordination Cayley tree graphs, Theoretical and Mathematical Physics 164 (2010) 905-919.

DOI: 10.1007/s11232-010-0072-9

Google Scholar