Reactant Consumption and Thermal Decomposition Analysis in a Two-Step Combustible Slab

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The significance of this paper is to analyse thermal decomposition and reactant consumption in a stockpile of reactive materials, such as that of coal, hay or wood, for example. The study is modelled in a rectangular slab and a two-step combustion process like the one taking place in fuel combustion of an automobile is assumed. The coupling of Runge-Kutta-Fehlberg (RKF) method and Shooting technique is applied to solve the differential equations governing the problem. The combustion process that is so complicated is investigated by consideration of effects of some embedded kinetic parameters, such as the activation energy, on the temperature and the reactant (O2) consumption. It was discovered that parameters such as the activation energy, tend to lower the temperature of the system and correspondingly reduce the O2 consumption rate, whereas parameters like the rate of reaction, increase the temperature during the combustion process, to reduce the O2 concentration of the system. The results also indicate that parameters like the rate of reaction, which increase the temperature profiles, fast-track the exothermic chemical reaction to deplete the reactant faster. However, those that reduce the temperature of the system preserve the reactant concentration.

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59-72

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June 2019

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© 2019 Trans Tech Publications Ltd. All Rights Reserved

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[1] R. S. Lebelo, Thermal Stability Investigation in a Reactive Sphere of Combustible Material, Adv. Math. Phys., (2016) 1 – 6.

Google Scholar

[2] R. S. Lebelo, BR Mabuza, Numerical investigation of thermal stability in media of different physical geometries, J. Eng. Appl. Sci. 12(24) (2017) 7555-7561.

Google Scholar

[3] R. S. Lebelo and O. D. Makinde, Numerical investigation of CO2 emission and thermal stability of a convective and radiative stockpile of reactive material in a cylindrical pipe, Adv. Mech. Eng., 7 (12) (2015) 1–11.

DOI: 10.1063/1.4898446

Google Scholar

[4] R. S. Lebelo, KC Moloi, Heat loss analysis in a radiating slab of variable thermal conductivity, Int. J. Eng. Tech., 7 (2.23) (2018) 228-231.

DOI: 10.14419/ijet.v7i2.23.11924

Google Scholar

[5] RS Lebelo, OD Makinde, T Chinyoka, Thermal decomposition analysis in a sphere of combustible materials. Adv. Mech. Eng., 9(2) (2017) 1–14.

DOI: 10.1177/1687814017692515

Google Scholar

[6] O. D. Makinde, Hermite-Pade´ approach to thermal stability of reacting masses in a slab with asymmetric convective cooling,, J Frankl Inst., 349 (2012) 957–965.

DOI: 10.1016/j.jfranklin.2011.12.001

Google Scholar

[7] O.D. Makinde, M.S. Tshehla, 2013, Analysis of thermal stability in a convecting and radiating two-step reactive slab, Adv. Mech. Eng. (2013) 1-9.

DOI: 10.1155/2013/294961

Google Scholar

[8] RS Lebelo, KC Moloi, KO Okosun, M Mukamuri, SO Adesanya, MS Muthuvalu, 2018, Two-step low-temperature oxidation for thermal stability analysis of a combustible sphere, AEJ (2018) 57 2829–2835.

DOI: 10.1016/j.aej.2018.01.006

Google Scholar

[9] O.S. Makinde, K.S. Adegbie, O.A. Fasoranbaku, Mathematical modelling of two-step exothermic reactions with and without reactants consumption, FUTA J. Res. Sci. 1(2013)44-53.

Google Scholar

[10] J.C. Quick, D. C. Glick, Carbon dioxide from coal combustion: variation with rank of US coal, Fuel, 79 (7) (2000) 803–812.

DOI: 10.1016/s0016-2361(99)00197-0

Google Scholar

[11] O.D. Makinde, T. Chinyoka, and R. S. Lebelo, 2011, Numerical Investigation into CO2 Emission, O2 Depletion, and Thermal Decomposition in a Reacting Slab, Math. Probl. Eng. (2011) 1-19.

DOI: 10.1155/2011/208426

Google Scholar

[12] R. S. Lebelo, O.D. Makinde, Modelling the impact of radiative heat loss on CO2 emission, O2 depletion and thermal stability in a reactive slab, IJST, Trans. Mech. Eng. 39(M2) (2015)351-365.

Google Scholar

[13] A. R. A. Aitken, et al., Repeated large-scale retreat and advances of Totten Glacier indicated by inland bed erosion, Nature, 533 (2016) 385-389.

DOI: 10.1038/nature17447

Google Scholar

[14] A. Arisoy, B.B. Beamish, E. Cetezen, Modelling spontaneous combustion of Coal, Turk. J. Eng. Environ. Sci. 30 (2006) 193–201.

Google Scholar

[15] R Hendershot, TD. Lebrecht, NC Easterbrook, Use Oxygen to Improve Combustion and Oxidation, Chem. Eng. Prog. 106(7) (2010) 57-61.

Google Scholar

[16] BS Haynes, Combustion research for chemical processing, Proc. Comb. Inst., 37 (1)2019 1-32.

Google Scholar