Application of Multi-Element Targets for the Formation of High Entropy Coatings

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The development of modern technologies in various industries cannot be imagined without the development and use of new materials, including new highly entropic alloys (HEA) and coatings based on them, as more advanced in terms of performance compared to traditional materials and coatings. Methods for producing various highly entropic alloys are described in many literature. Almost all such technologies at the moment cannot be applicable in the mass production of parts due to the high cost and lack of appropriate infrastructure and production technologies. However, obtaining coatings formed on the basis of highly entropic alloys for various parts of mechanisms and machines is currently a highly promising direction in improving the operational properties of work surfaces. The goal of this work is to create highly entropic coatings obtained by magnetron sputtering of special multicomponent targets. The paper shows the possibility of synthesis of coatings of the predicted composition and properties. A coating based on a matrix target made of 12Kh18N10T steel with pressed multicomponent Cr-Ni-Zr-Ti-Cu pellets was synthesized. The elemental composition of the coating and its properties were determined, the microhardness was measured, and the functional properties were established.

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August 2021

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[1] A.A. Andreev, L.P. Sablev, S.N. Grigor'ev, Vacuum Arc Coatings, NSC KIPT, Kharkiv, (2010).

Google Scholar

[2] S.G. Psakh'e, K.P Zol'nikov, I.S. Konovalenko, Synthesis and Properties of Nanocrystalline and Substructure Materials, Tomsk University Press, Tomsk, (2007).

Google Scholar

[3] A. Kavalejro, D. de Khossona, Nanostructured Coatings, Technosphere, Moscow, (2011).

Google Scholar

[4] M.M.M. Bilek, D.R. Mckenzie, R.N. Tarant et al., Plasma-based ion implantation utilizing a cathodic arc plasma, Surface and Coating Technology. 156 (2003) 136-142.

DOI: 10.1016/s0257-8972(02)00078-6

Google Scholar

[5] W. Yeh, S.K. Chen, S.J. Lin, J.Y. Gan, T.S. Chin, T.T. Shun, C.H. Tsau, S.Y. Chang, Nanostructured high-entropy alloys with multiple principal elements: novel alloy design concepts and outcomes, Advanced Engineering Materials. 6 (2004) 299-303.

DOI: 10.1002/adem.200300567

Google Scholar

[6] B. Cantor, L.T.H. Chang, P. Knight, A.J.B. Vincent, Microstructural development in equiatomic multicomponent alloys, Materials Science and Engineering A. 375-377 (2004) 213-218.

DOI: 10.1016/j.msea.2003.10.257

Google Scholar

[7] M.H. Tsai, J.W. Yeh, High-entropy alloys: a critical review, Mater. Res. Lett. 2 (2014) 107-123.

Google Scholar

[8] O.N. Senkov, J.M. Scott, S.V. Senkova, Miracle microstructure and room temperature properties of a highentropy TaNbHfZrTi alloy, J. of Alloys and Compounds. 509 (2011) 6043-6048.

DOI: 10.1016/j.jallcom.2011.02.171

Google Scholar

[9] C.Y. Hsu, C.C. Juan, W.R. Wang, T.S. Sheu, J.W. Yeh, S.K. Chen, On the superior hot hardness and softening resistance of AlCoCrxFeMo0.5Ni high-entropy alloys, Materials Science and Engineering A. 528 (2011) 3581-3588.

DOI: 10.1016/j.msea.2011.01.072

Google Scholar

[10] S.A. Firstov, V.F. Gorban', N.A. Krapivka, EH.P. Pechkovskij, N.I. Danilenko, M.V. Karpec, Mechanical properties of cast multicomponent alloys at high temperatures, Modern Problems of Physical Materials Science. 17 (2008) 126-139.

Google Scholar

[11] M. Braica, V. Braica, M. Balaceanua, C.N. Zoitaa, A. Vladescua, E. Grigore, Characteristics of (TiAlCrNbY)C films deposited by reactive magnetron sputtering, Surface & Coatings Technology. 204 (2010) 2010-2014.

DOI: 10.1016/j.surfcoat.2009.10.049

Google Scholar

[12] P.K. Huang, J.W. Yeh, Effects of nitrogen content on structure and mechanical properties of multi- (AlCrNbSiTiV)N coating element, Surface & Coatings Technology. 204 (2010) 1891-1896.

DOI: 10.1016/j.surfcoat.2009.01.016

Google Scholar

[13] P.J. Martin, A. Bendavid, J.M. Cairney, M. Hoffman, Nanocomposite Ti-S-N, Zr-S-N, Ti-AlSi-N, Ti-Al-V-Si thin film coatings deposited by vacuum arc deposition, Surface and Coatings Technology. 200 (2005) 131-134.

DOI: 10.1016/j.surfcoat.2004.06.012

Google Scholar

[14] O. I. Yurkova, V. V. Cherniavsky, O. I. Kravchenko, Formation of structure and phase composition of nanocrystalline CuNiAlFeCr alloy by the mechanical alloying method, Metallophysics and New Technologies. 36 (2014) 477-490.

DOI: 10.15407/mfint.36.04.0477

Google Scholar

[15] V.G. Pushin, N.N. Kuranova, N.I. Kourov, R.Z. Valiev, EH.Z. Valiev, V.V. Makarov, A.V. Pushin. A.N. Uksusnikov, Baroelastic shape memory effects in titanium nickelide alloys subjected to plastic deformation under high pressure, Technical Physics Journal. 82 8 (2012) 67-75.

DOI: 10.1134/s106378421208018x

Google Scholar

[16] P.H. Mayrhofer, C. Mitterer, L. Hultman, H. Clemens, Microstructure design of hard coating, Progress in Materials Science. 51 (2006) 1032-1114.

DOI: 10.1016/j.pmatsci.2006.02.002

Google Scholar

[17] S.A. Firstov, V.F. Gorban', A.O. Andreev, N.A. Krapivka, Superhard coatings from high-entropy alloys, Science and Innovation. 9(5) (2013) 32-39.

Google Scholar