Determination of the Effect of Magnesium Hydrophosphate on the Physical-Rheological and Chemical-Colloidal Properties of Aluminosilicate-Based Flame Retardant Paints

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The effect of magnesium hydrophosphate on rheokinetic, chemical-colloidal and flame retardant properties of flame retardant aluminosilicate paints for wood has been investigated. It is shown that the introduction of magnesium hydrophosphate in the paint composition in the amount of 1-1.5% allows to stabilize the change of dynamic viscosity from 164500 to 120000 cP in the range of speeds from 0.35 to 1 RPM, as well as to provide wettability (s=0. 659-0.6603) and stability of spread ability (k=-43.48 and k=- 43.65) of the paint on pine substrate, which corresponds to the criterion requirements. According to the data of fire tests it was found that modification of aluminosilicate bases of paints with magnesium hydrophosphate in the amount of 1-1.5% puts them in the category of difficult combustible and difficult to ignite, the temperature of flue gases did not exceed the critical value (<260С), mass loss did not exceed 5.4-7.2%, which corresponds to the I group of flammability G1 according to the standard. According to the shear force data (SS=24.95 to 176.45 dynes/cm2 and SS=23.18 to 172.4 dynes/cm2) the investigated formulations can be applied on wooden surfaces by air spraying with a screw paint feed.

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139-145

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February 2025

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[1] S. Guzii, Studies of the effect of viscosity stabilizers of fire-retardant aluminosilicate paints for wood products and structures. Journal of Modern Technology and Engineering. 6 (1) (2022) 24-33.

Google Scholar

[2] S. Guzii, Fire Protection of Wood and Structures with Mineral Paints. Trends Tech Sci Res. 5(5) (2022) 555671.

Google Scholar

[3] S. Guzii, Reducing the Combustibility of Wood Products by Treating their Surface with Intumescent Paints on a Water-Dispersion Basis. Trends Tech Sci Res. 6(1) (2023) 555676.

DOI: 10.19080/ttsr.2023.06.555676

Google Scholar

[4] P. Yin, H. Cai, W. Liao, et al., Design and preparation of flame-resistant geopolymer coatings for timber. J Mater Sci.. 58 (2023)13865–13874.

DOI: 10.1007/s10853-023-08886-6

Google Scholar

[5] W. Ya Chao, et al. Nano-ZnO modified geopolymer composite coatings for flame-retarding plywood. Construction and Building Materials. 338 4 (2022) 127649.

DOI: 10.1016/j.conbuildmat.2022.127649

Google Scholar

[6] J. Temuujin, W. Rickard, M. Lee, A. van Riessen, Preparation and thermal properties of fire resistant metakaolin-based geopolymer-type coatings. Journal of Non-Crystalline Solids. 357 5 (2011) 1399–1404.

DOI: 10.1016/j.jnoncrysol.2010.09.063

Google Scholar

[7] F.U.A. Shaikh, S. Sharany, J. Haque, Sanjayan, Behavior of fly ash geopolymer as fire resistant coating for timber. Journal of Sustainable Cement-Based Materials. 8:5 (2019) 259–274.

DOI: 10.1080/21650373.2018.1537015

Google Scholar

[8] M.S. Mohd Basri, F. Mustapha, N. Mazlan, M.R. Ishak, Rice-Husk-Ash-Based Geopolymer Coating: Fire-Retardant, Optimize Composition, Microstructural, Thermal and Element Characteristics Analysis. Polymers. 13 (2021) 3747.

DOI: 10.3390/polym13213747

Google Scholar

[9] V.A. Voytovich, Protection of wood from burning. J. StroyPROFIL. 2 (48) (2006) 12–21.

Google Scholar

[10] S. Guzii, I. Bazhelka, N. Svitlychna, V. Lashchivskiy, Protection of Wood from Burning with Paints on Alkaline Aluminosilicates-Based. Materials Science Forum. 1006 (2020) 19–24.

DOI: 10.4028/www.scientific.net/msf.1006.19

Google Scholar

[11] S. Guzii, T. Kurska, et al. Features of the organic-mineral intumescent paints structure formation for wooden constructions fire protection. IOP Conf. Ser.: Mater. Sci. Eng. 1162 (2021) 012003.

DOI: 10.1088/1757-899x/1162/1/012003

Google Scholar

[12] P. Kryvenko, V. Kyrychok, S. Guzii, Influence of the ratio of oxides and temperature on the structure formation of alkaline hydro-aluminosilicates. Eastern-European Journal of Enterprise Technologies. 5(5–83) (2016) 40–48.

DOI: 10.15587/1729-4061.2016.79605

Google Scholar

[13] S. Guzii, P. Kryvenko, O. Guzii, S. Yushkevych, Determining the effect of the composition of an aluminosilicate binder on the rheotechnological properties of adhesives for wood. Eastern-European Journal of Enterprise Technologies. 6/6(102) (2019) 30–37.

DOI: 10.15587/1729-4061.2019.185728

Google Scholar

[14] S. Guzii, Investigation of the influence of organomineral additives on the colloid-chemical properties of geocement dispersion. Technology audit and production reserves. 3/1(35) (2017) 38-43.

DOI: 10.15587/2312-8372.2017.105678

Google Scholar

[15] E.N. Glazacheva, M.V. Uspenskaya, Colloidal chemistry. Methodical instructions for laboratory work. ITMO University, St. Petersburg. (2015) 62.

Google Scholar

[16] A. Kravchenko, S. Guziy, Determining the fire resistance properties of timber, protected by geocement-based coatings. Eastern-European Journal of Enterprise Technologies. 1(5) (2015) 38–41.

DOI: 10.15587/1729-4061.2015.36843

Google Scholar

[17] DSTU B V.2.7-19-95 (GOST 30244-94). Construction materials. Test methods for flammability.

Google Scholar

[18] N.O. Duzhylova, Physical and chemical features of structure formation of gas-silicate matrix in the system "CaO-Al2O3-Ca(OH)2-SiO2-Al-FeMn-H2O". Resource-efficient materials, structures, buildings and constructions. 22 (2011) 56–62.

Google Scholar

[19] J. Kruželák, A. Kvasničáková, K. Hložeková and I. Hudec, Progress in polymers and polymer composites used as efficient materials for EMI shielding. Nanoscale Adv. 3 (2021) 123.

DOI: 10.1039/d0na00760a

Google Scholar