Synthesis of Pour Point Depressant from Black Soldier Fly Maggot Oil

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Abstract:

This Final Project research focuses on the synthesis of pour point depressant (PPD) from Black Soldier Fly (BSF) Maggot Oil to reduce the pour point of crude oil samples. Crude oil itself is a non-renewable energy source that is still in high demand in Indonesia, especially as a vehicle fuel. Crude oil contains paraffin wax, which can crystallize and hinder the transportation and production processes of crude oil. Therefore, this study aims to produce PPD from BSF maggots as an additive for crude oil to ensure its smooth flow. Maggots were chosen due to their high fatty acid content, ranging from 29% to 32%, making them a potential source for PPD. The method used for PPD synthesis involves esterification using a reflux process. Pour point testing will be conducted using the ASTM D-5853 method. The synthesized PPD could lower the pour point of crude oil by up to 24°C from the original 39°C. Characterization using FTIR testing successfully revealed C-O vibrations (ester groups) at the wave number range of 1158 – 1155 cm-1 while eliminating O-H vibrations (carboxylic acid groups). GC-MS characterization was also conducted to identify the formed ester compounds. The GC-MS results showed that PPD 1 had the highest ester content at 87.71%. Keywords: Crude Oil, Esterification, Pour Point Depressant, Maggot, Paraffin, Pour Point.

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[1] M. Idris, "Berapa Produksi Minyak Indonesia saat ini?," 2022. [Online]. Available: https://money.kompas.com/read/2022/07/16/000300326/berapa-produksi-minyak-indonesia-saat-ini-.

Google Scholar

[2] Pasasa, N. V. A., Kasmungin, S., & Pramana, A. A. (2017, October). Studi Pemilihan Pour Point Depressant Untuk Penanggulangan Masalah Transportasi Minyak Parafinik Pada Lapangan X. In Prosiding Seminar Nasional Cendekiawan (pp.211-217).

Google Scholar

[3] Ayundari, D. P. N., & Sutjahjo, D. H. (2018). Rancang Bangun Alat Uji Pour Point Untuk Mengukur Titik Tuang Bahan Bakar. Jurnal Rekayasa Mesin, 5(1).

Google Scholar

[4] Afriana, D., & Dhamayanthie, I. (2018). Analisa Fraksi Gasoil Berdasarkan Uji Sifat Fisika. IPTEK Journal of Proceedings Series, (2)

DOI: 10.12962/j23546026.y2018i1.3382

Google Scholar

[5] Kurnianto, M., & Prasetyo, A. (2018). Prediksi Kedalaman Terbentuknya Wax Pada Sumur X Lapangan Y. PETRO: Jurnal Ilmiah Teknik Perminyakan, 7(2), 65-72.

DOI: 10.25105/petro.v7i2.3678

Google Scholar

[6] Prabowo, A. S. (2021). Peranan Penting Injeksi Pour Point Depressant (PPD) Untuk Menjaga Aliran Crude Oil Saat Terjadinya Penurunan Temperatur Pada Export Line Lapangan AS (Doctoral dissertation, Universitas Islam Riau).

Google Scholar

[7] Yang, F., Zhao, Y., Sjöblom, J., Li, C., & Paso, K. G. (2015). Polymeric wax inhibitors and point depressants for waxy crude oils: a critical review. Journal of Dispersion Science and Technology, 36(2), 213-225.

DOI: 10.1080/01932691.2014.901917

Google Scholar

[8] Nurfajrin, Z. D., Satiyawira, B., & Putra, R. A. (2021, November). Comparison of pour point depressant (PPD) ethylene-vinyl acetate (EVA) and nano-montmorillonite. In IOP Conference Series: Earth and Environmental Science (Vol. 894, No. 1, p.012019). IOP Publishing.

DOI: 10.1088/1755-1315/894/1/012019

Google Scholar

[9] Nur, A. A., & Subekti, H. (2021, December). Mgs-25 Ethylene-Vinyl Acetate (Eva) Copolymer Sebagai Pour Point Depressant Pada Waxy Crude Oil. In Prosiding Seminar Nasional Teknologi Energi dan Mineral (Vol. 1, No. 2, pp.101-107).

DOI: 10.53026/sntem.v2i1.745

Google Scholar

[10] Putra, R. A. (2022). Studi laboratorium perbandingan Pour Point Depressant (PPD) Ethylene Vinyl Acetate (EVA) dan Nano-montmotillonite. SKRIPSI-2021.

Google Scholar

[11] Izzatusholekha, I., Jabbar, M. F. A., Rahmawati, R., Salmah, S., & Prasdianto, R. (2022, October). Lalat Tentara Hitam (Black Soldier Fly) Sebagai Pengurai Sampah Organik (Black Soldier Fly As An Organic Waste Decomposer). In Prosiding Seminar Nasional Pengabdian Masyarakat LPPM UMJ (Vol. 1, No. 1).

DOI: 10.33024/jikk.v10i8.10306

Google Scholar

[12] Santi, S., Astuti, A. T. B., & Pasamboang, J. (2020). Nilai Nutrisi Maggot Black Solder Fly (Hermetia Illucens) dengan Berbagai Media. AGROVITAL: Jurnal Ilmu Pertanian, 5(2), 91-93.

DOI: 10.35329/agrovital.v5i2.1747

Google Scholar

[13] Putra, A. T. M., Salim, A., Fauziah, R. N., & Alzana, N. (2022, June). Pemanfaatan Senyawa Antimicrobial Maggot (Hematia Illuecens) Sebagai Agen Bakteriolitik Gram Negatif. In Prosiding Seminar Nasional Teknologi Agribisnis Peternakan (Stap) (Vol. 9, pp.813-819).

Google Scholar

[14] Ewald, N., Vidakovic, A., Langeland, M., Kiessling, A., Sampels, S., & Lalander, C. (2020). Fatty acid composition of black soldier fly larvae (Hermetia illucens)–Possibilities and limitations for modification through diet. Waste management, 102, 40-47.

DOI: 10.1016/j.wasman.2019.10.014

Google Scholar

[15] Afdhol, M. K., Rita, N., Hidayat, F., & Erfando, T. (2022). Pembuatan Green-Solvent Dari Limbah Kulit Nanas dan Pemanfaatannya Sebagai Wax Inhibitor. Lembaran publikasi minyak dan gas bumi, 56(3), 125-130.

DOI: 10.29017/LPMGB.56.3.1098

Google Scholar

[16] Shittu, O. M., & Achugasim, O. (2023). Modified and Unmodified Jatropha Curcas Seed Oils as Pour Point Depressants for a Nigerian Waxy Crude Oil. Journal of Applied Sciences and Environmental Management, 27(2), 237-242.

DOI: 10.4314/jasem.v27i2.8

Google Scholar

[17] Kathumbi, L. K., Home, P. G., Raude, J. M., & Gathitu, B. B. (2022). Performance of Citric Acid as a Catalyst and Support Catalyst When Synthesized with NaOH and CaO in Transesterification of Biodiesel from Black Soldier Fly Larvae Fed on Kitchen Waste. Fuels, 3(2), 295-315.-.

DOI: 10.3390/fuels3020018

Google Scholar

[18] Kamari, A., Ishak, S., Hussin, M. I. A. M., Wong, S. T. S., Jumadi, J., & Yahaya, N. M. (2020, December). Optimization and characterization studies of biodiesel production from black soldier fly larvae fed by soya residue. In IOP Conference Series: Materials Science and Engineering (Vol. 980, No. 1, p.012057). IOP Publishing.

DOI: 10.1088/1757-899X/980/1/012057

Google Scholar

[19] Patra, S., & Migas, M. I. P. Perbandingan Hasil Pengujian Pour Point pada Crude Oil Menggunakan Metode Uji ASTM D 97 dan ASTM D 5853.

DOI: 10.37525/sp/2022-1/315

Google Scholar

[20] Afifa, S. (2022). Sintesis Polietilena Glikol Ester dari Ampas Kopi serta Aplikasinya Sebagai Pour Point Depressant (Bachelor dissertation, Sayyidah Afifa).

Google Scholar