Co-Pyrolysis of Biomass and Plastic Waste: A Study on Bio-Oil Yield from Mixed Empty Fruit Bunch and Plastics

Article Preview

Abstract:

The co-pyrolysis of biomass and plastic waste offers a promising pathway for renewable fuel production and sustainable waste management. In this study, the co-pyrolysis of empty fruit bunches (EFB) and polypropylene (PP) was investigated to evaluate the influence of temperature and blending ratio on product distribution. Experiments were conducted in a semi-batch reactor at temperatures ranging from 400 to 600 °C with a fixed 50:50 blending ratio, and at 500 °C with varying ratios of EFB:PP (75:25, 50:50, 25:75). The results demonstrated that temperature strongly influenced product yields, with bio-oil production reaching its maximum at 500–550 °C. However, 500 °C was identified as the most favorable condition, providing high bio-oil yield more than 45% while minimizing secondary cracking and excessive gas formation. The blending ratio also played a significant role, with the 50:50 mixture producing the highest liquid yield (46.54%) due to synergistic interactions between hydrogen-rich PP and oxygen-rich EFB, which enhanced radical stabilization and suppressed char formation. At higher PP proportions, gas yields increased substantially, whereas pure PP produced high bio-oil (52.7%) with minimal char but elevated gas fractions. A comparative analysis with literature confirmed the strong influence of feedstock composition, reactor configuration, and operating conditions on product selectivity. Overall, the findings highlight that co-pyrolysis of EFB and PP at 500 °C and a 50:50 blending ratio provides an optimum balance for maximizing bio-oil production, offering a viable strategy for integrating biomass and plastic waste valorization into renewable energy pathways.

You might also be interested in these eBooks

Info:

Periodical:

Engineering Headway (Volume 38)

Pages:

3-10

Citation:

Online since:

June 2026

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2026 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] F.B. Ahmad, Z. Zhang, W.O.S. Doherty, I.M. O'Hara, The outlook of the production of advanced fuels and chemicals from integrated oil palm biomass biorefinery, Renew. Sustain. Energy Rev. 109 (2019) 386–411.

DOI: 10.1016/j.rser.2019.04.009

Google Scholar

[2] D. Statistik, Statistik Kelapa Sawit Indonesia 2022, 16th ed., Badan Pusat Statistik, 2022.

Google Scholar

[3] R.I. Mainil, Y. Matsumura, New Application of Supercritical Water Gasification to Palm Oil Mill Effluent: Gasification and Phosphorus Recovery, Energy and Fuels. 33 (2019) 11145–11152.

DOI: 10.1021/acs.energyfuels.9b02729

Google Scholar

[4] A. Irawan, T. Kurniawan, H. Alwan, Darisman, D. Pujianti, Y. Bindar, M.S.A. Bakar, A.B.D. Nandiyanto, Influence temperature and holding time of empty fruit bunch slow pyrolysis to phenolic in biocrude oil, Automot. Exp. 4 (2021) 150–160.

DOI: 10.31603/ae.5049

Google Scholar

[5] Sunarno, I. Zahrina, S. Reni Yenti, R. Sri Irianty, P. Setia Utama, Catalytic co-pyrolysis of palm oil empty fruit bunch and waste tire using calcium oxide catalysts for upgrading bio-oil, Mater. Today Proc. 87 (2023) 321–326.

DOI: 10.1016/j.matpr.2023.03.290

Google Scholar

[6] Sunarno, Zultiniar, A.H. Santoso, P.S. Utama, Catalytic co-pyrolysis palm oil empty fruit bunch and low-density polyethylene of plastic waste into high grade bio-oil, IOP Conf. Ser. Mater. Sci. Eng. 1053 (2021) 012101.

DOI: 10.1088/1757-899x/1053/1/012101

Google Scholar

[7] R.I. Mainil, J.J. Panjaitan, A.K. Mainil, H. Putra, A. Aziz, Oil Production from Polypropylene Plastic via Pyrolysis, AIP Conf. Proc. 3223 (2025).

DOI: 10.1063/5.0243224

Google Scholar

[8] Ida Bagus Alit, I Gede Bawa Susana, I Made Mara, Conversion of LDPE and PP plastic waste into fuel by pyrolysis method, Glob. J. Eng. Technol. Adv. 10 (2022) 073–078.

DOI: 10.30574/gjeta.2022.10.3.0055

Google Scholar

[9] G. Li, T. Yang, W. Xiao, X. Yao, M. Su, M. Pan, X. Wang, T. Lyu, Enhanced biofuel production by co-pyrolysis of distiller's grains and waste plastics: A quantitative appraisal of kinetic behaviors and product characteristics, Chemosphere. 342 (2023) 140137.

DOI: 10.1016/j.chemosphere.2023.140137

Google Scholar

[10] H. Ko, M. Lee, R. Sen, J. Choi, S. Oh, Pyrolysis Characteristics of Empty Fruit Bunches at Different Temperatures and Heating Rates, Energies. 18 (2025).

DOI: 10.3390/en18061404

Google Scholar

[11] S. Handoko, N. Nurhadi, S. Mujiati, R. Fitriani, Characterization of pyrolysis products of oil palm empty fruit bunch, IOP Conf. Ser. Earth Environ. Sci. 749 (2021).

DOI: 10.1088/1755-1315/749/1/012041

Google Scholar

[12] D. Hariadi, S.M. Saleh, R. Anwar Yamin, S. Aprilia, Utilization of LDPE plastic waste on the quality of pyrolysis oil as an asphalt solvent alternative, Therm. Sci. Eng. Prog. 23 (2021) 100872.

DOI: 10.1016/j.tsep.2021.100872

Google Scholar

[13] S.H. Zein, C.T. Grogan, O.Y. Yansaneh, A. Putranto, Pyrolysis of High-Density Polyethylene Waste Plastic to Liquid Fuels—Modelling and Economic Analysis, Processes. 10 (2022) 1–18.

DOI: 10.3390/pr10081503

Google Scholar

[14] J. Escalante, W.H. Chen, M. Tabatabaei, A.T. Hoang, E.E. Kwon, K.Y. Andrew Lin, A. Saravanakumar, Pyrolysis of lignocellulosic, algal, plastic, and other biomass wastes for biofuel production and circular bioeconomy: A review of thermogravimetric analysis (TGA) approach, Renew. Sustain. Energy Rev. 169 (2022) 112914.

DOI: 10.1016/j.rser.2022.112914

Google Scholar

[15] E. Kusrini, D. Supramono, V. Degirmenci, S. Pranata, A.A. Bawono, F.N. Ani, IMPROVING THE QUALITY OF PYROLYSIS OIL FROM CO-FIRING HIGH- DENSITY POLYETHYLENE PLASTIC WASTE AND PALM EMPTY FRUIT BUNCHES, Int. J. Technol. 7 (2018) 1498–1508.

DOI: 10.14716/ijtech.v9i7.2531

Google Scholar

[16] M.A. Al-maari, M. Azmier, A. Taufik, M. Din, H. Hassan, A. Mubarak, Co-pyrolysis of oil palm empty fruit bunch and oil palm frond with low-density polyethylene and polypropylene for bio-oil production, Arab. J. Chem. 14 (2021) 103282.

DOI: 10.1016/j.arabjc.2021.103282

Google Scholar

[17] Sunarno, E. Saputra, M.I. Fermi, P.S. Utama, Non-catalytic co-pyrolysis of empty fruit bunch of palm and solid tire waste into upgrade bio-oil, Int. J. Renew. Energy Res. 10 (2020) 687–692.

DOI: 10.20508/ijrer.v10i2.10690.g7940

Google Scholar

[18] N. Valentino, O. Farobie, D.A. Sugeng, I. Masfuri, N. Rahmawati, H.N. Anindita, T. Anggoro, T.P. Rini, B. Dwiratna, E. Rosyadi, Co-pyrolysis of oil palm empty fruit bunch and polypropylene: synergistic effects on blending ratios and product quality, BIO Web Conf. 171 (2025) 1–10.

DOI: 10.1051/bioconf/202517102002

Google Scholar

[19] Sunarno, R.P. Sari, T. Frimacia, S.R. Yenti, P.S. Utama, E. Saputra, Catalytic Co-Pyrolysis of Palm Oil Empty Fruit Bunch and Coal into Liquid Oil, Int. J. Renew. Energy Dev. 11 (2022) 463–469.

DOI: 10.14710/ijred.2022.42193

Google Scholar