Characterization of Surfactant Flooding for Light Oil Using Gum Arabic

Article Preview

Abstract:

Surfactant flooding, a chemical IOR technique is one of the viable EOR processes for recovering additional oil after water flooding. This is because it reduces the interfacial tension between the oil and water and allows trapped oil to be released for mobilization by a polymer.In this research, two sets of experiments were performed. First, the optimum surfactant concentration was determined through surfactant polymer flooding using a range of surfactant concentration of 0.1% to 0.6% and 15% of polymer. Secondly, another set of experiments to determine the optimum flow rate for surfactant flooding was carried out using the optimum surfactant concentration obtained. Lauryl Sulphate (Sodium Dodecyl Sulphate, SDS), an anionic surfactant, was used to alter the interfacial tension and reduce capillary pressure while Gum Arabic, an organic adhesive gotten from the hardened sap of the Acacia Senegal and Acacia Seyal trees, having a similar molecular structure and chemical characteristics with Xanthan Gum, was the polymer used to mobilize the oil.The results show that above 0.5%, oil recovery decreases with increase in concentration such that between 0.5 and 0.6%, a decrease of (20% -19%) is recorded. This suggests that it would be uneconomical to exceed surfactant concentration of 0.5%. It is shown in the result of the first set of experiments that a range of oil recovery of 59% to 76% for water flooding and a range of 11.64% to 20.02% additional oil recovery for surfactant Polymer flooding for a range of surfactant flow rate of surfactant concentration of 0.1% to 0.6%. For the second sets of experiments, a range of oil recovery of 64% to 68% for water flooding and a range of 15% to 24% additional oil recovery for surfactant flooding for a range of surfactant flow rate of surfactant flow rate of 1cc/min to 6cc/min. The Optimum surfactant flow rate resulting in the highest oil recovery for the chosen core size is 3cc/min. It's highly encouraged that the critical displacement rate is maintained to prevent the development of slug fingers.In summary, an optimum Surfactant flow rate is required for better performance of a Surfactant flooding.

You might also be interested in these eBooks

Info:

Pages:

136-147

Citation:

Online since:

December 2015

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2016 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] Kiampey S. A, Donaldson E. C, 61st Annual Technical Conference and Exhibition, New Orleans, L.A., October (1986).

Google Scholar

[2] Rosen, M.J.; " Surfactants and Interfacial Phenomena, John Wiley & Sons Inc., New York City (1978).

Google Scholar

[3] Bourrel, M. and Schechter, R, S ;. " Microemulsions and related systems, Marcel Dekker Inc., New York City (1988).

Google Scholar

[4] Ottewill, R.H.; Introduction, , Surfactants, T.F. Tadrosn (ed), Ademic Press, San Francisco1-18, (1984).

Google Scholar

[5] Lake, L.W.; Enhanced Oil Recovery, Prentice-Hall Inc., Englewood Cliffs, NJ (1989).

Google Scholar

[6] Garrett H.E.; "Surface Active Chemicals, Pergsmon Press, New York City (1972).

Google Scholar

[7] W.B. Gogarty, Micellar/Polymer Flooding An overview (SPE-7041), Journal of Petroleum Technology 30 (8), (1978) 1089-1101.

DOI: 10.2118/7041-pa

Google Scholar

[8] J. George, Hirasaki, SPE, A. Clarence, Miller, SPE and Maura Puerto, Rice University, Recent Advances in surfactant EOR, SPE December (2011).

DOI: 10.2118/115386-pa

Google Scholar

[9] L.C. Uren and E.H. Fahmy. Factors influencing the recovery of petroleum from unconsolidated sands by waterflooding. Trans. AIME, 77, 318–335 (1927). 4.

DOI: 10.2118/927318-g

Google Scholar

[10] W.G. Halbert and C.G. Inks, Miscible Waterflooding Using a Phosphate Ester Solubilizer. Paper SPE 3697 presented at the SPE 42nd Annual California Regional Meeting, Los Angeles, California, 4-5 Nov. (1971).

DOI: 10.2118/3697-ms

Google Scholar

[11] L.W. Holm,. Use of Soluble Oils for Oil Recovery. J. Pet. Technol. 23(12): (1971) 1475-1483.

Google Scholar

[12] R.N. Healy and R.L. Reed, and C.W. Carpenter, A Laboratory Study of Microemulsion Flooding. Paper SPE 4752 presented at the SPE Oil Recovery Symposium, Tulsa, 22-24 April. (1975).

Google Scholar

[13] K.D. Dreher and R.D. Sydansk, Observation of Oil-Bank Formation During Micellar Flooding. Paper SPE 5838 presented at the SPE Oil Recovery Symposium, Tulsa, Oklahoma, 22-24 March. (1976).

DOI: 10.2118/5838-ms

Google Scholar

[14] R.N. Healy and R.L. Reed, Immiscible Microemulsion Flooding. Paper SPE 5817 presented at the SPE 4th Symposium on Improved Oil Recovery, Tulsa, 22-24 March. (1977).

Google Scholar

[15] R.C. Nelson, G. A. Pope,. Phase Relationships in Chemical Flooding. Soc. Pet. Eng. J. 18(5): (1978) 325-338.

Google Scholar

[16] C.J. Glover, M.C. Puerto, J.M. Maerker, and E.L. Sandvik, Surfactant Phase Behavior and Retention in Porous Media. Paper SPE 7053 presented at the SPE 5th Symposium on Improved Methods for Oil Recovery, Tulsa, 16-19 April. (1979).

DOI: 10.2118/7053-pa

Google Scholar

[17] K.O. Meyers and S. J Salter, The Effect of Oil Brine Ratio on Surfactant Adsorption from Microemulsions. Paper SPE 8989 presented at the SPE 55th Annual Fall Technical Conference and Exhibition, Dallas, Texas, 21-24 Sep. (1980).

DOI: 10.2118/8989-ms

Google Scholar

[18] M.C. Puerto, and R.L. Reed, A Three-Parameter Representation of Surfactant/Oil/Brine Interaction. Soc. Pet. Eng. J. 23(4): (1983) 669-682.

DOI: 10.2118/10678-pa

Google Scholar

[19] M. Bouabboune, N. Hammouch, and S. Benhadid, Comparison between Microemulsion and Surfactant Solution Flooding Effeciency for Enhanced Oil Recovery in TinFouyé Oil Field. PAPER 2006-058, the Petroleum Society's 7th Canadian International Petroleum Conference and 57th Annual Technical Meeting, Calgary, Alberta, Canada. (2006).

DOI: 10.2118/2006-058

Google Scholar

[20] H.J. Hill, J. Reisberg, G. L. Stegemeier, Aqueous Surfactant Systems for Oil Recovery, Journal of Petroleum Technology, Vol 25, Issue 02, (1973), 186-194.

DOI: 10.2118/3798-pa

Google Scholar

[21] P. Somasundaran, D.W. Fuerstenau, Mechanism of alkyl sulfonate adsorption at alumina–water interface. J. Phys. Chem. (1966) 70, 90.

DOI: 10.1021/j100873a014

Google Scholar

[22] P. Somasundaran, D.W. Fuerstenau. Heat and entropy of adsorption and association of long-chain surfactants at aluminaaqueous solution interface. Trans. SME (1972a) 252, 275.

Google Scholar

[23] J. Scamehorn, R.S. Schecter, W.H. Wade, Adsorption of surfactants on mineral oxide surfaces from aqueous solutions I: isometrically pure anionic surfactants. J. Colloid Interface Sci. (1982) 86, 463.

DOI: 10.1016/0021-9797(82)90013-3

Google Scholar

[24] Feng Xu, Xiao Guo, Wanbin Wang, Nan Zhang, Sha Jia, Xiaoqin Wang, Case Study: Numerical Simulation of Surfactant flooding in low Permeability Oil field. A paper presented at SPE Enhanced Oil recovery Conference held in Kuala Lumpur, Malaysia, 19-21 July (2011).

DOI: 10.2118/145036-ms

Google Scholar

[25] Abhijit Samanta, Keka Ojha; Ashis Sarkar, Ajay Mandal, Surfactant and Surfactant-Polymer Flooding for Enhanced Oil Recovery. Advances in Petroleum Exploration and Development Vol. 2, No. 1, (2011), pp.13-18.

DOI: 10.1515/energyo.s13202-012-0021-2

Google Scholar

[26] S.O. Onuoha SPE, O. A Olafuyi SPE. University of Benin. Alkali/Surfactant/Polymer flooding using Gum Arabic; A comparative analysis. This paper was presented at the Nigeria Annual International Conference and Exhibition held in Lagos, Nigeria, 30 July-1 August (2013).

DOI: 10.2118/167572-ms

Google Scholar

[27] P.A. Williams and G.O. Philips, Handbook of Hydrocolloids , Gum Arabic, North East Wales Institute Wrexham. Wood publishing Ltd, Cambridge, UK, (1985) 155-168.

Google Scholar

[28] http: / www. intracen . org/mns. Bulletin on Gum Arabic Market News Services (MNS), Quarterly Edition, Sept. (2008).

Google Scholar

[29] M. Glicksman and R. Sand, Gum Arabic. in L. Whistler, editor: Industrial Gums, Chapter x, Academic press, NY, (1973) P. 197-263.

DOI: 10.1016/b978-0-12-746252-3.50015-0

Google Scholar

[30] C.L. Mantell. Technology of Gum Arabic. In American Chemical Society, Division of Colloid Chemistry (editor), Natural Plant Hydrocolloids, Washington, DC, (1954) pp.20-32.

DOI: 10.1021/ba-1954-0011.ch005

Google Scholar

[31] M.K. Sabah El-Kheir, A.E.A. Yagoub and A.A. Abu Baker. Emulsion-stabilizing Effect of Gum from Acacia senegal (L) Willd: The Role of Quality and Grade of Gum, Oil type, Temperature, Stirring time and Concentration. Pakistan Journal ofNutrition, 7(3): ( 2008) 395-399.

DOI: 10.3923/pjn.2008.395.399

Google Scholar

[32] Tarek Ahmed, Reservoir Engineering Handbook. 2nd Edition, 782-802.

Google Scholar

[33] E. Hoff, B. Nystrom, & B. Lindman, Polymer-Surfactant Interactions in Dilute Mixtures of a Nonionic Cellulose Derivative and an Anionic Surfactant. Langmuir, (2001). 17, 28-34.

DOI: 10.1021/la001175p

Google Scholar

[34] W. Hongyan, C. Xulong, Z. Jichao, & Z. Aimei,. Development and Application of Dilute Surfactant-PolymerFlooding System for Shengli Oilfield. J. Pet. Sci. Eng., (2009) 65, 45-50.

DOI: 10.1016/j.petrol.2008.12.021

Google Scholar