Nanomaterials for Conservation of Artistic Stones: Performance and Removal Tests by Laser Cleaning

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In this work, nanomaterials were used as consolidants and protective layers for artistic stones. Synthetized nanocomposites were applied on marble and their performances as protective and water repellent coating were characterized. For the preparation of the novel nanocomposites, SiO2 and TiO2 nanoparticles were synthesized by laser pyrolysis and were dispersed in acrylic polymer and silicon-based resin. To evaluate the retreatability of water repellent treatments, the capability of laser to remove protective layers was explored. Laser cleaning tests with different working parameters have been carried out to optimize the effectiveness of the process. The effects of laser treatments on stone surfaces and on the applied nanocomposites were estimated by using confocal optical microscopy and Laser-Induced Fluorescence (LIF).

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225-233

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March 2017

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© 2017 Trans Tech Publications Ltd. All Rights Reserved

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[1] G.G. Amoroso, V. Fassina, Stone decay and conservation, Material Science Monographs 11, Elsevier, Amsterdam, (1983).

Google Scholar

[2] P. Baglioni, R. Giorgi, Soft and hard nanomaterials for restoration and conservation of cultural heritage, Soft Matter, 2 (2006) 293-303.

DOI: 10.1039/b516442g

Google Scholar

[3] P.N. Manoudis, I. Karapanagiotis, A. Tsakalof, I. Zuburtikudis, C. Panayiotou, Superhydrophobic Composite Films Produced on Various Substrates, Langmuir, 24 (2008) 11225-11232.

DOI: 10.1021/la801817e

Google Scholar

[4] R. D'Amato, L. Caneve, C. Giancristofaro, F. Persia, L. Pilloni, A. Rinaldi, Development of nanocomposites for conservation of artistic stones, Proc. IMechE Part N: J. Nanoengineering and Nanosystems, 228 (2014) 19–26.

DOI: 10.1177/1740349913496404

Google Scholar

[5] C. Giancristofaro, R. D'Amato, L. Caneve, L. Pilloni, A. Rinaldi, F. Persia, Performance of Nanocomposites for Preservation of Artistic Stones, AIP Conf. Proc., 1603 (2014) 86-92.

DOI: 10.1063/1.4883046

Google Scholar

[6] D. Aslanidou, I. Karapanagiotis, C. Panayiotou, Tuning the wetting properties of siloxane-nanoparticle coatings to induce superhydrophobicity and superoleophobicity for stone protection, Mater. Des., 108 (2016) 736-744.

DOI: 10.1016/j.matdes.2016.07.014

Google Scholar

[7] International Charters for Conservation and Restoration. Documentation. ICOMOS, München, 179p. Monuments & Sites (2001-), Vol. I. (2004).

Google Scholar

[8] R. D'Amato, M. Falconieri, S. Gagliardi, E. Popovici, E. Serra, G. Terranova, E. Borsella, Synthesis of ceramic nanoparticles by laser pyrolysis: from research to applications, J. Anal. App. Pyrolysis, 104 (2013) 461-469.

DOI: 10.1016/j.jaap.2013.05.026

Google Scholar

[9] V. Spizzichino, F. Angelini, L. Caneve, F. Colao, R. Corrias, L. Ruggiero, In situ study of modern synthetic material and pigments in contemporary paintings by laser-induced fluorescence scanning, Studies in Conservation, 60 (2015) S178-S184.

DOI: 10.1179/0039363015z.000000000222

Google Scholar