Paper Titles

Synthesized Silver Carbon Nanotubes and Zinc Oxide Nanoparticles and their Ability to Remove Methylene Blue Dye
p.1

Effectiveness of Calcium Deficiency in Nanosized Hydroxyapatite for Removal of Fe(II), Cu(II), Ni(II) and Cr(VI) Ions from Aqueous Solutions
p.17

Synthesis and Antimicrobial Activity of Fe:TiO₂ Particles
p.28

Nanomaterials for Consolidation and Protection of Egyptian Faience Form Matteria, Egypt
p.39

Structure and Optical Properties of ZnO and ZnO₂ Nanoparticles
p.49

Tuning the Rheology of Nano-Sized Silica Suspensions with Silicon Nitride Particles
p.63

Mathematical Modeling of Junctionless Triple Material Double Gate MOSFET for Low Power Applications
p.71

Fish Gelatin Antimicrobial Electrospun Nanofibers for Active Food-Packaging Applications
p.80

A Specific NH₃ Gas Sensor of a Thick MWCNTs-OH Network for Detection at Room Temperature
p.98

HomeJournal of Nano ResearchJournal of Nano Research Vol. 56Synthesis and Antimicrobial Activity of Fe:TiO2...

Synthesis and Antimicrobial Activity of Fe:TiO₂ Particles

Article Preview

Abstract:

TiO₂ and iron-doped TiO₂ were synthesized by sol-gel method. TiO₂ and 0.5 %mol Fe:TiO₂ were calcined at 500 and 800 °C for 3 h. The synthesized particles were characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), UV-VIS diffuse reflectance spectrophotometry (UV/DRS), scanning electron microscopy (SEM) and scanning electron microscope-energy dispersive X-Ray analysis (SEM-EDX). The XRD patterns of all samples that were calcined at 500 °C showed only anatase phase. On increasing temperature from 500 to 800 °C, the anatase phase transformed to rutile phase. For 0.5 %mol Fe:TiO₂, pseudobrookite (Fe₂TiO₅) phase was observed at 800 °C. The particles that contained rutile showed higher antibacterial activities against E. coli, B. subtilis, and S. aureus than anatase phase, under fluorescent irradiation.

You might also be interested in these eBooks

Journal of Nano Research Vol. 56

Info:

Periodical:

Journal of Nano Research (Volume 56)

Pages:

28-38

DOI:

https://doi.org/10.4028/www.scientific.net/JNanoR.56.28

Citation:

Cite this paper

Online since:

February 2019

Authors:

Uraiwan Werapun*, Jaraslak Pechwang

Keywords:

Anatase Phase, Antibacterial Activity, Calcination Temperature, Pseudobrookite, Rutile Phase, Titanium Dioxide

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

© 2019 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] Y. Zhou, G. Jiang, Study on properties of composite oxides TiO2/SiO2, Chin. J. Chem. Eng. 10 (2002) 349-353.

[2] M.M. Khan, S.A. Ansari, D. Pradhan, M.O. Ansari, J. Lee, M.H. Cho, Band gap engineered TiO2 nanoparticles for visible light induced photoelectrochemical and photocatalytic studies, J. Mater. Chem. A, 2 (2014) 637-644.

DOI: 10.1039/c3ta14052k

[3] Y. Kikuchi, K. Sunada, T. Iyoda, K. Hashimoto, A. Fujishima, Photocatalytic bactericidal effect of TiO2 thin films: dynamic view of the active oxygen species responsible for the effect, J. Photochem. Photobiol., A: Chemistry, 106 (1997) 51-56.

DOI: 10.1016/s1010-6030(97)00038-5

[4] V. Binas, D. Venieri, D. Kotzias, G. Kiriakidis, Modified TiO2 based photocatalysts for improved air and health quality, J. Materiomics. 3 (2017) 3-16.

DOI: 10.1016/j.jmat.2016.11.002

[5] R. Zallen, M.P. Moret, The optical absorption edge of brookite TiO2, Solid State Commun., 137 (2006) 154-157.

DOI: 10.1016/j.ssc.2005.10.024

[6] D. Wang, L. Xiao, Q. Luo, X. Li, J. An, Y. Duan, Highly efficient visible light TiO2 photocatalyst prepared by sol–gel method at temperatures lower than 300° C, J. Hazard. Mater., 192 (2011) 150-159.

DOI: 10.1016/j.jhazmat.2011.04.110

[7] G.J. Yang, C.J. Li, X.C. Huang, C.X. Li, Y.Y. Wang, Influence of Silver Doping on Photocatalytic Activity of Liquid-Flame-Sprayed-Nanostructured TiO2 Coating, J. Therm. Spray Technol., 16 (2007) 881-885.

DOI: 10.1007/s11666-007-9110-z

[8] L. Li, H. Zhuang, D. Bu, Characterization and activity of visible-light-driven TiO2 photocatalyst codoped with lanthanum and iodine, Appl. Surf. Sci., 257 (2011) 9221-9225.

DOI: 10.1016/j.apsusc.2011.06.007

[9] Z. Li, W. Shen, W. He, X. Zu, Effect of Fe-doped TiO2 nanoparticle derived from modified hydrothermal process on the photocatalytic degradation performance on methylene blue, J. Hazard. Mater., 155 (2008) 590-594.

DOI: 10.1016/j.jhazmat.2007.11.095

[10] C. Su, B.Y. Hong, C.M. Tseng, Sol–gel preparation and photocatalysis of titanium dioxide, Catal. Today, 96 (2004) 119-126.

DOI: 10.1016/j.cattod.2004.06.132

[11] S. Gelover, P. Mondragón, A. Jiménez, Titanium dioxide sol–gel deposited over glass and its application as a photocatalyst for water decontamination, J. Photochem. Photobiol., A: Chemistry, 165 (2004) 241-246.

DOI: 10.1016/j.jphotochem.2004.03.023

[12] F. Chekin, S. Bagheri, S.B.A. Hamid, Synthesis of Pt doped TiO2 nanoparticles: characterization and application for electrocatalytic oxidation of l-methionine, Sens. Actuators, B: Chemical, 177 (2013) 898-903.

DOI: 10.1016/j.snb.2012.12.002

[13] M. Zaharescu, C. Pirlog, M. Crisan, M. Gartner, A. Vasilescu, TiO2-based vitreous coatings obtained by sol-gel method. J. Non-Cryst. Solids, 160 (1993) 162-166.

DOI: 10.1016/0022-3093(93)90296-a

[14] M. Oves, M. Arshad, M.S. Khan, A.S. Ahmed, A. Azam, I.M. Ismail, Anti-microbial activity of cobalt doped zinc oxide nanoparticles: Targeting water borne bacteria, J. Saudi. Chem. Soc., 19 (2015) 581-588.

DOI: 10.1016/j.jscs.2015.05.003

[15] C.C. Trapalis, P. Keivanidis, G. Kordas, M. Zaharescu, M. Crisan, A. Szatvanyi, M. Gartner, TiO2 (Fe3+) nanostructured thin films with antibacterial properties, Thin Solid Films, 433 (2003) 186-190.

DOI: 10.1016/s0040-6090(03)00331-6

[16] A.M. Stoyanova, H.Y. Hitkova, N.K. Ivanova, A.D. Bachvarova-Nedelcheva, R.S. Iordanova, M.P. Sredkova, Photocatalytic and antibacterial activity of Fe-doped TiO2 nanoparticles prepared by nonhydrolytic sol-gel method, Bulg. Chem. Commun., 45 (2013) 497-504.

[17] P. Kokila, V. Senthilkumar, K.P. Nazeer, Preparation and photo catalytic activity of Fe3+-doped TiO2 nanoparticles, Arch. Phys. Res., 2 (2011) 246-253.

[18] J.L. Endrino, R.G.S.V. Prasad, D. Basavaraju, K.N. Rao, A. Mosquera, C.S. Naveen, A.R. Phani, Antimicrobial properties of nanostructured TiO2 plus Fe additive thin films synthesized by a cost-effective sol–gel process, Nanosci. Nanotech. Let., 3 (2011) 629-636.

DOI: 10.1166/nnl.2011.1238

[19] W. Zhang, Y. Chen, S. Yu, S. Chen, Y. Yin, Preparation and antibacterial behavior of Fe3+-doped nanostructured TiO2 thin films, Thin Solid Films, 516 (2008) 4690-4694.

DOI: 10.1016/j.tsf.2007.08.053

[20] S. Boonyod, W. Sutthisripok, L. Sikong, Antibacterial activity of TiO2 and Fe3+ doped TiO2 nanoparticles synthesized at low temperature, Adv. Mat. Res, 214 (2011) 197-201.

DOI: 10.4028/www.scientific.net/amr.214.197

[21] J.A. Wang, R. Limas-Ballesteros, T. Lopez, A. Moreno, R. Gomez, O. Novaro, X. Bokhimi, Quantitative determination of titanium lattice defects and solid-state reaction mechanism in iron-doped TiO2 photocatalysts, J. Phys. Chem. B, 105 (2001) 9692-9698.

DOI: 10.1021/jp0044429

[22] I. Ganesh, P.P. Kumar, A.K. Gupta, P.S. Sekhar, K. Radha, G. Padmanabham, G. Sundararajan, Preparation and characterization of Fe-doped TiO2 powders for solar light response and photocatalytic applications, Process. Appl. Ceram. 6 (2012) 21-36.

DOI: 10.2298/pac1201021g

[23] Z. Li, W. Shen, W. He, X. Zu, Effect of Fe-doped TiO2 nanoparticle derived from modified hydrothermal process on the photocatalytic degradation performance on methylene blue, J. Hazard. Mater., 155 (2008) 590-594.

DOI: 10.1016/j.jhazmat.2007.11.095

[24] J. Wang, W. Sun, Z. Zhang, Z. Jiang, X. Wang, R. Xu, R. Li, X. Zhang, Preparation of Fe-doped mixed crystal TiO2 catalyst and investigation of its sonocatalytic activity during degradation of azo fuchsine under ultrasonic irradiation, J. Colloid Interface Sci., 320 (2008) 202-209.

DOI: 10.1016/j.jcis.2007.12.013

[25] Z. Mesgari, M. Gharagozlou, A. Khosravi, K. Gharanjig, Spectrophotometric studies of visible light induced photocatalytic degradation of methyl orange using phthalocyanine-modified Fe-doped TiO2 nanocrystals, Spectrochim. Acta, Part A, 92 (2012) 148-153.

DOI: 10.1016/j.saa.2012.02.055

[26] K. Naeem, F. Ouyang, Preparation of Fe3+-doped TiO2 nanoparticles and its photocatalytic activity under UV light, Physica B: Condensed Matter, 405 (2010) 221-226.

DOI: 10.1016/j.physb.2009.08.060

[27] S. Sood, A. Umar, S.K. Mehta, S.K. Kansal, Highly effective Fe-doped TiO2 nanoparticles photocatalysts for visible-light driven photocatalytic degradation of toxic organic compounds, J. Colloid Interface Sci., 450 (2015) 213-223.

DOI: 10.1016/j.jcis.2015.03.018

[28] H. Lipson, H. Steeple, Interpretation of X-ray powder diffraction patterns, Macmillan, New York, (1970).

[29] C.Y.W. Lin, D. Channei, P. Koshy, A. Nakaruk, C.C. Sorrell, Effect of Fe doping on TiO2 films prepared by spin coating, Ceram. Int., 38 (2012) 3943-3946.

DOI: 10.1016/j.ceramint.2012.01.047

[30] M. Effendi, Effect of doping Fe on TiO2 thin films prepared by spin coating method, J. Basic. Appl. Sci., 12 (2012), 107-110.

[31] T. Watanabe, A. Nakajima, R. Wang, M. Minabe, S. Koizumi, A. Fujishima, K. Hashimoto, Photocatalytic activity and photoinduced hydrophilicity of titanium dioxide coated glass, Thin solid films, 351 (1999) 260-263.

DOI: 10.1016/s0040-6090(99)00205-9

[32] S. Zhan, J. Yang, Y. Liu, N. Wang, J. Dai, H. Yu, X. Gao, Y. Li, Mesoporous Fe2O3-doped TiO2 nanostructured fibers with higher photocatalytic activity, J. Colloid Interface Sci., 355 (2011) 328-333.

DOI: 10.1016/j.jcis.2010.12.024

[33] A.M. Peiro, J. Peral, C. Domingo, X. Domenech, J.A. Ayllón, Low-temperature deposition of TiO2 thin films with photocatalytic activity from colloidal anatase aqueous solutions, Chem. Mater., 13 (2001) 2567-2573.

DOI: 10.1021/cm0012419

[34] Y. Luo, Z. Lu, Y. Jiang, D. Wang, L. Yang, P. Huo, Z. Da, X. Bai, X. Xie, P. Yang, Selective photodegradation of 1-methylimidazole-2-thiol by the magnetic and dual conductive imprinted photocatalysts based on TiO2/Fe3O4/MWCNTs, Chem. Eng. J. 240 (2014) 244-252.

DOI: 10.1016/j.cej.2013.11.088

[35] N. Nasralla, M. Yeganeh, Y. Astuti, S. Piticharoenphun, N. Shahtahmasebi, A. Kompany, M. Karimipour, B.G. Mendis, N.R.J. Poolton, L. Šiller, Structural and spectroscopic study of Fe-doped TiO2 nanoparticles prepared by sol-gel method, Sci. Iran., 20 (2013) 1018-1022.

DOI: 10.1016/j.physb.2017.02.010

[36] W. Zhao, Z. Bai, A. Ren, B. Guo, C. Wu, Sunlight photocatalytic activity of CdS modified TiO2 loaded on activated carbon fibers, Appl. Surf. Sci., 256 (2010) 3493-3498.

DOI: 10.1016/j.apsusc.2009.12.062

[37] D.I. Anwar, D. Mulyadi, Synthesis of Fe-TiO2 Composite as a Photocatalyst for Degradation of Methylene Blue, Procedia Chem., 17 (2015) 49-54.

DOI: 10.1016/j.proche.2015.12.131

[38] W.C. Hung, Y.C. Chen, H. Chu, T.K. Tseng, Synthesis and characterization of TiO2 and Fe/TiO2 nanoparticles and their performance for photocatalytic degradation of 1,2-dichloroethane, Appl. Surf. Sci., 255 (2008) 2205-2213.

DOI: 10.1016/j.apsusc.2008.07.079

[39] J. Zhu, W. Zheng, B. He, J. Zhang, M. Anpo, Characterization of Fe-TiO2 photocatalysts synthesized by hydrothermal method and their photocatalytic reactivity for photodegradation of XRG dye diluted in water, J. Mol. Catal. A: Chem., 216 (2004) 35-43.

DOI: 10.1016/j.molcata.2004.01.008

[40] U. Arellano, M. Asomoza, F. Ramirez, Antimicrobial activity of Fe–TiO2 thin film photocatalysts, J. Photochem. Photobiol., A: Chemistry, 222 (2011) 159-165.

DOI: 10.1016/j.jphotochem.2011.05.016

[41] L. Caballero, K.A. Whitehead, N.S. Allen, J. Verran, Inactivation of Escherichia coli on immobilized TiO2 using fluorescent light, J. Photochem. Photobiol., A: Chemistry, 202 (2009) 92-98.

DOI: 10.1016/j.jphotochem.2008.11.005