Development of Preparation Processes for CNT/Si3N4 Composites

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Silicon nitride based composites with different amount (1, 3 and 5 wt%) of carbon nanotubes have been prepared. Optimisation of the manufacturing processes has been conducted to preserve the carbon nanotubes in composites and to avoid damaging during high temperature processing. The first results show that carbon nanotubes have a good contact to the surface of silicon nitride grains. With increasing the carbon nanotube content a lower densification rate was obtained together with the deterioration of the mechanical characteristics of composites. In the case of 1wt% and 3 wt% carbon nanotube addition the increase of pressure resulted in increase of bending strength. It was found that microstructure features achieved by properly designed sintering parameters are the main responsible factors for the strength improvements.

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135-141

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July 2005

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© 2005 Trans Tech Publications Ltd. All Rights Reserved

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[1] S. Rochie, Carbon nanotubes: exceptional mechanical and electrical properties, Ann. Chim. Sci. Mat., 2000, 25, pp.529-532.

Google Scholar

[2] E. T. Thostenson, Z. Ren, T. W. Chou, Advances in the science and technology of carbon nanotubes and their composites: a review, Comp. Sci. and Techn. 61 (2001) 1899-(1912).

DOI: 10.1016/s0266-3538(01)00094-x

Google Scholar

[3] K. T. Lau, D. Hui, The revolutionary creation of new advanced materials-carbon nanotube composites, Composites: Part B 33 (2002) 263-277.

DOI: 10.1016/s1359-8368(02)00012-4

Google Scholar

[4] K.T. Lau, D. Hui, Effectiveness of using carbon nanotubes as nano-reinforcements for advanced composite structures, Carbon 40 (2002) 1597-1617.

DOI: 10.1016/s0008-6223(02)00157-4

Google Scholar

[5] S. R. Dong, J.P. Tu, X.B. Zhang, An investigation of the sliding wear behavior of Cu-matrix composite reinforced by carbon nanotubes, Mater. Sci. Eng. A 313 (2001) 83.

DOI: 10.1016/s0921-5093(01)00963-7

Google Scholar

[6] R. Z. Ma, J. Wu, B.Q. Wei, J. Liang, D.H. Wu, Processing and properties of carbon nanotubes-nano-SiC ceramic, J. Mater. Sci. 33 (1998) 5243-5263.

Google Scholar

[7] Cs. Balázsi, Z. Kónya, F. Wéber, L. P. Biró, P. Arató, Preparation and characterization of carbon nanotube reinforced silicon nitride composites, Mat. Sci. Eng. C 23/6-8 (2003) 11331137.

DOI: 10.1016/j.msec.2003.09.085

Google Scholar

[8] G. -D. Zhan, J. D. Kuntz, J. Wan, A. K. Mukherjee, Single-wall carbon nanotubes as attractive toughening agents in alumina-based nanocomposites, Nature Mat. 2 (2003) 38-42.

DOI: 10.1038/nmat793

Google Scholar

[9] G. -D. Zhan, J. D. Kuntz, J. E. Garay, A. K. Mukherjee, Electrical properties of nanoceramics reinforced with ropes of single-walled carbon nanotubes, Appl. Phys. Lett. Vol 83, Nr. 6, 11 August (2003).

DOI: 10.1063/1.1600511

Google Scholar

[10] W. A. Curtin, B. W. Sheldon, CNT-reinforced ceramics and metals, Materials Today, Vol. 7, Issue 11, November 2004, Pages 44-49.

DOI: 10.1016/s1369-7021(04)00508-5

Google Scholar

[11] X. Wang, N. P. Padture, H. Tanaka, Contact-damage-resistant ceramic/single-wall carbon nanotubes and ceramic/graphite composites, Nature Materials, Vol. 3, August 2004, 539-544.

DOI: 10.1038/nmat1161

Google Scholar

[12] J. D. Kuntz, G. -D. Zhan, A. K. Mukherjee, Nanocrystalline-Matrix Ceramic Composites for Improved Fracture Toughness, MRS Bulletin, January 2004, Vol. 29, Nr. 1, pp.22-27.

DOI: 10.1557/mrs2004.12

Google Scholar

[13] Z. Kónya, I. Vesselényi, K. Niesz, A. Kukovecz, A. Demortier, A. Fonseca, J. Delhalle, Z. Mekhalif, J. B. Nagy, A. A. Koós, Z. Osváth, A. Kocsonya, L. P. Biró, I. Kiricsi, Large scale production of short functionalized carbon nanotubes, Chem. Phys. Lett. 360 (2002).

DOI: 10.1016/s0009-2614(02)00900-4

Google Scholar

[14] Cs. Balázsi, Z. Kónya, Zs. Kasztovszky, F. Wéber, Z. Vértesy, L. P. Biró, I. Kiricsi, P. Arató, Examination of carbon nanotube reinforced silicon nitride composites, Proceedings of Fifth International Conference on High Temperature Ceramic Matrix Composites (HTCMC-5) New Frontiers and Horizons, Seattle, Washington, USA, (published by The American Ceramic Society), (2004).

DOI: 10.4028/www.scientific.net/msf.554.123

Google Scholar