Properties of Polypropylene/Carbon Nanotube Composites Compatibilized by Maleic Anhydride Grafted SEBS

Article Preview

Abstract:

Isotactic polypropylene (PP)/carbon nanotube (CNT) composites compatibilized by maleic anhydride grafted styrene-ethylene/butylenes-styrene copolymer (MA-SEBS) were prepared by melt compunding and compression moulding. The melt compouding torque, thermal properties, dynamical mechanical behavior, mechanical and anti-static properties of the PP/CNT composites were systematically invertigated. The results indicated that MA-SEBS is an effective compatilizer for the PP/CNT composites. The melting and crsytallization temperatures (Tm and Tc), crystallinity degree (Xc) of the PP phase in PP/CNT composites increase remarkably with the CNT content. Compared with PP/CNT composites, the incorporation of MA-SEBS increases Tm, but decreases Tc, crystallization rate and Xc of PP phases in PP/MA-SEBS/CNT composites. Owing to MA-SEBS as a compatibilizer to enhance formation of a perfect percolation network, the thermal, mechanical and anti-static properties of PP/CNT are improved.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

223-228

Citation:

Online since:

June 2006

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2006 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] R.H. Baughman, A.A. Zakhidov and W.A. de Heer: Science Vol. 297 (2002), p.787.

Google Scholar

[2] H.D. Wagner, O. Lourie, Y. Feldman and R. Tenne: Appl. Phys. Lett. Vol. 72 (1998), p.188.

Google Scholar

[3] O. Lourie, D.M. Cox and H.D. Wagne: Phys. Rev. Lett. Vol. 81 (1998), p.1638.

Google Scholar

[4] X. L. Xie, K. L. Fung, R. K. Y. Li, S. C. Tjong and Y. -W. Mai: J. Polym. Sci., Polym. Phys. Vol. 40 (2002), p.214.

Google Scholar

[5] D.W. Van Krevelen: Properties of Polymers (3rd rev. ed.; Elsevier Scientific, Amsterdam, 1997).

Google Scholar

[6] J. D. Hoffman, G. T. Davis and J.I. Jr. Lauritzen: Treatise on Solid State Chemistry, (Edited. By Hannay NB, Vol. 3, Plenum Press: New York, 1976), p.528.

Google Scholar

[7] X.P. Zhou, R.K.Y. Li, X.L. Xie and S.C. Tjong: J. Appl. Polym. Sci. Vol. 88 (2003), p.1055. 0246810 1000000 1E9 1E12 1E15 1E18 ρs, Ω CNT content, wt% PP matrix WPP/WMA-SEBS=90/10.

Google Scholar