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HomeKey Engineering MaterialsKey Engineering Materials Vols. 474-476Synthesis, Kinetics and Electrochemical Properties...

Synthesis, Kinetics and Electrochemical Properties of a New Photochromic Diarylethene

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Abstract:

A new unsymmetrical photochromic diarylethene [1-(2-methyl-5-(3-methoxyphenyl)-3-thienyl), 2-(2-methyl-3-benzothienyl)] perfluorocyclopentene (1a), was synthesized, and its photochromic properties such as photochromism, kinetics and electrochemical properties were investigated in detail. The results showed that the compound exhibited excellent photochromism both in solution and in PMMA film with alternating irradiation by UV/Vis light. The kinetic and electrochemical experiments indicated that the cyclization/cycloreversion process of the compound was determined to be the zeroth/first order reaction, and the electrochemcial switching property can be potential use for electrochemistry data storage. At last, using this dithienylethene as recording medium was performed successfully.

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Advanced Materials and Computer Science

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Periodical:

Key Engineering Materials (Volumes 474-476)

Pages:

1543-1546

DOI:

https://doi.org/10.4028/www.scientific.net/KEM.474-476.1543

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Online since:

April 2011

Authors:

Shou Zhi Pu, Ren Jie Wang, Hong Ying Xia, Gang Liu

Keywords:

Diarylethene, Electrochemical (EC), Optical Storage, Photochromism

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© 2011 Trans Tech Publications Ltd. All Rights Reserved

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