Effect of Dispersant Content on Nanograined BME MLCC Powder Prepared by Aqueous Chemical Coating Method

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Dispersion plays an important role in aqueous chemical coating process for the preparation of BaTiO3 based next generation BME MLCC powder, since it affects coating coverage and layer morphology of the BaTiO3 particles as well as the microstructure and dielectric properties of the ceramics. In this paper, Poly (acrylic acid-co-maleic acid) (PAM) is used as dispersant, its content influences are carefully investigated. It is known that low content of dispersant leads to not only poor dispersion, low coverage and irregular coating layer of BaTiO3 particles, but also bad temperature coefficient of capacitances and inhomogeneous microstructure of the resultant BaTiO3 ceramics, while excessive dispersant deteriorates the microstructure and performance by reducing the density of ceramic. With proper dispersant content, the particles are dispersed and coated perfectly, finally the dense X7R-satisfied ceramic are obtained with average grain size 103nm and fine microstructure, meeting the requirement of next generation MLCCs.

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Key Engineering Materials (Volumes 512-515)

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153-157

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June 2012

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© 2012 Trans Tech Publications Ltd. All Rights Reserved

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[1] H. Kishi, Y. Mizuno, and H. Chazono: "Base-metal electrode-multilayer ceramic capacitors: Past, present and future perspectives, " Jpn. J. Appl. Phys. 42 (2003) 1.

DOI: 10.1143/jjap.42.1

Google Scholar

[2] M. J. Pan and C. A. Randall: "A Brief Introduction to Ceramic Capacitors, " Ieee Electr. Insul. M. 26 (2010) 44.

DOI: 10.1109/mei.2010.5482787

Google Scholar

[3] R. L. Brutchey, G. S. Cheng, Q. Gu, and D. E. Morse: "Positive temperature coefficient of resistivity in donor-doped BaTiO3 ceramics derived from nanocrystals synthesized at low temperature, " Adv. Mater. 20 (2008) 1029.

DOI: 10.1002/adma.200701804

Google Scholar

[4] V. V. Mitic, Z. S. Nikolic, V. B. Pavlovic, et al.: "Influence of Rare-Earth Dopants on Barium Titanate Ceramics Microstructure and Corresponding Electrical Properties, " J. Am. Ceram. Soc. 93 (2010) 132.

DOI: 10.1111/j.1551-2916.2009.03309.x

Google Scholar

[5] Z. B. Tian, X. H. Wang, Y. C. Zhang, et al.: "Formation of Core-Shell Structure in Ultrafine-Grained BaTiO3-Based Ceramics Through Nanodopant Method, " J. Am. Ceram. Soc. 93 (2010) 171.

DOI: 10.1111/j.1551-2916.2009.03371.x

Google Scholar

[6] C. H. Kim, K. J. Park, Y. J. Yoon, et al.: "Role of yttrium and magnesium in the formation of core-shell structure of BaTiO3 grains in MLCC, " J. Eur. Ceram. Soc. 28 (2008) 1213.

DOI: 10.1016/j.jeurceramsoc.2007.09.042

Google Scholar

[7] C. H. Kim, K. J. Park, Y. J. Yoon, et al.: "Effects of milling condition on the formation of core-shell structure in BaTiO3 grains, " J. Eur. Ceram. Soc. 28 (2008) 2589.

Google Scholar

[8] J. Y. Lee, J. H. Lee, S. H. Hong, Y. K. Lee, and J. Y. Choi: "Coating BaTiO3 nanolayers on spherical Ni powders for multilayer ceramic capacitors," Adv. Mater. 15 (2003) 1655.

DOI: 10.1002/adma.200305418

Google Scholar

[9] R. Z. Liu, Y. Z. Zhao, R. X. Huang, Y. J. Zhao, and H. P. Zhou: "Multiferroic ferrite/perovskite oxide core/shell nanostructures," J. Mater. Chem. 20 (2010) 10665.

DOI: 10.1039/c0jm02602f

Google Scholar

[10] Z. B. Tian, X. H. Wang, L. K. Shu, et al.: "Preparation of Nano BaTiO3-Based Ceramics for Multilayer Ceramic Capacitor Application by Chemical Coating Method," J. Am. Ceram. Soc. 92 (2009) 830.

DOI: 10.1111/j.1551-2916.2009.02979.x

Google Scholar

[11] Y. C. Zhang, X. H. Wang, Z. B. Tian, K. H. Hur, and L. T. Li: "Preparation of BME MLCC powders by aqueous chemical coating method," J. Am. Ceram. Soc. 94 (2011) 3286.

DOI: 10.1111/j.1551-2916.2011.04543.x

Google Scholar

[12] J. L. Zhao, X. H. Wang, R. Z. Chen, and L. T. Li: "Dispersion of barium titanate in aqueous media, " Ceram. Int. 33 (2007) 207.

Google Scholar