Enhanced Performance of Alkaline Niobate-Based Ceramics Manufactured by Two-Step Sintering

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In this paper, a typical Li- and Ta/Sb- modified alkaline niobate-based ceramics are prepared by conventional sintering and two-step sintering respectively. The ceramics sintered by two-step sintering exhibit better electrical properties than the samples prepared by conventional sintering. The related mechanisms are also discussed in terms of phase-structures and microstructures. Results show that two-step sintering can restrain the volatilization of alkali elements and compositional segregation during the process of sintering dense alkaline niobate-based ceramics, and enhance the electrical properties accordingly. Therefore, two-step sintering is a promising approach to achieve high performance alkaline niobate-based ceramics.

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Key Engineering Materials (Volumes 512-515)

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372-376

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June 2012

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© 2012 Trans Tech Publications Ltd. All Rights Reserved

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[1] T. Karaki, K. Yan, and M. Adachi, Barium Titanate Piezoelectric Ceramics Manufactured by Two-Step Sintering, Jpn. J. Appl. Phys. 46 (2007) 7035-38.

DOI: 10.1143/jjap.46.7035

Google Scholar

[2] J. R. Gomah-Pettry, E. Said, P. Marchet, and J. P. Mercurio, Sodium-bismuth Titanate Based Lead-Free Ferroelectric Materials, J. Eur. Ceram. Soc. 24 (2004) 1165-69.

DOI: 10.1016/s0955-2219(03)00473-4

Google Scholar

[3] W. Liu and X. Ren, Large Piezoelectric Effect in Pb-Free Ceramics, Phys. Rev. Lett. 103 (2009) 257602.

Google Scholar

[4] Y. Saito, H. Takao, T. Tani, T. Nonoyama, K. Takatori, T. Homma, T. Nagaya, and M. Nakamura, Lead-free piezoceramics, Nature 432 (2004) 84-87.

DOI: 10.1038/nature03028

Google Scholar

[5] K. Wang and J. F. Li, Domain Engineering of Lead-Free Li-Modified (K, Na) NbO3 Polycrystals with Highly Enhanced Piezoelectricity, Adv. Funct. Mater. 20 (2010) 1924-29.

DOI: 10.1002/adfm.201000284

Google Scholar

[6] J. Fu, R. Z. Zuo, X. H. Wang, and L. T. Li, Polymorphic Phase Transition and Enhanced Piezoelectric Properties of LiTaO3-modified (Na0.52K0.48)(Nb0.93Sb0.07)O3 Lead-free Ceramics, J. Phys. D: Appl. Phys. 42 (2009) 012006.

DOI: 10.1088/0022-3727/42/1/012006

Google Scholar

[7] P. Zhao, B.-P. Zhang and J.-F. Li, Enhancing Piezoelectric d33 Coefficient in Li/Ta-codoped Lead-free (Na,K)NbO3 Ceramics by Compensating Na and K at a Fixed Ratio, Appl. Phys. Lett. 91 (2007) 172901.

DOI: 10.1063/1.2794405

Google Scholar

[8] R. E. Jaeger and L. Egerton, Hot Pressing of Potassium-Sodium Niobates, J. Am. Ceram. Soc. 45 (1962) 209-13.

DOI: 10.1111/j.1151-2916.1962.tb11127.x

Google Scholar

[9] J. F. Li, K. Wang, B. P. Zhang, and L. M. Zhang, Ferroelectric and Piezoelectric Properties of Fine-Grained Na0.5K0.5NbO3 Lead-free Piezoelectric Ceramics Prepared by Spark Plasma Sintering, J. Am. Ceram. Soc. 89 (2006) 706-09.

DOI: 10.1111/j.1551-2916.2005.00743.x

Google Scholar

[10] M. Matsubara, T. Yamaguchi, K. Kikuta, and S. Hirano, Sintering and Piezoelectric Properties of Potassium Sodium Niobate Ceramics With Newly Developed Sintering Aid, Jpn. J. Appl. Phys. 44 (2005) 258-63.

DOI: 10.1143/jjap.44.258

Google Scholar

[11] I. W. Chen and X. H. Wang, Sintering Dense Nanocrystalline Ceramics Without Final-stage Grain Growth, Nature 404 (2000) 168-71.

DOI: 10.1038/35004548

Google Scholar

[12] J. Fang, X. H. Wang, Z. B. Tian, C. F. Zhong, R. Z. Zuo, and L. T. Li, Two-Step Sintering: An Approach to Broaden the Sintering Temperature Range of Alkaline Niobate-Based Lead-Free Piezoceramics, J. Am. Ceram. Soc. 93[11] (2010) 3552-55.

DOI: 10.1111/j.1551-2916.2010.04085.x

Google Scholar

[13] Y. Dai, X. Zhang, and G. Zhou, Phase Transitional Behavior in K0.5Na0.5NbO3-LiTaO3 Ceramics, Appl. Phys. Lett. 90 (2007) 262903.

Google Scholar

[14] Z. Y. Shen, Y. H. Zhen, K. Wang, and J. F. Li, Influence of Sintering Temperature on Grain Growth and Phase Structure of Compositionally Optimized High-Performance Li/Ta-Modified (Na,K)NbO3 Ceramics, J. Am. Ceram. Soc. 92 (2009) 1748-52.

DOI: 10.1111/j.1551-2916.2009.03128.x

Google Scholar

[15] A. Safari and M. Abazari, Lead-free Piezoelectric Ceramics And Thin Films, IEEE Trans Ultrason Ferroelectr Freq Control 57 (2010) 2165-76.

DOI: 10.1109/tuffc.2010.1674

Google Scholar

[16] B. Jaffe, W. R. Cook, and H. Jaffe, Piezoelectric Ceramics, Academic Press, New York, 1971.

Google Scholar

[17] J. Fang, X. H. Wang, Z. B. Tian, C. F. Zhong, R. Z. Zuo, and L. T. Li, Narrow Sintering Temperature Window for (K, Na)NbO3-based Lead-free Piezoceramics Caused by Compositional Segregation, Phys. Status Solidi A 208 (2011) 791–94.

DOI: 10.1002/pssa.201026500

Google Scholar