Fabrication of Graphene/Zirconia Nanocomposite by Mixing Graphite Oxide and Zirconia Nanopowders and Pressureless Sintering

Article Preview

Abstract:

Graphene has unique two-dimensional nanostructure with high specific surface areas, superior mechanical properties which has promising applications for the development of high performance nanocomposite materials. Most of previous work on graphene nanocomposites addresses on polymer matrix. In the present work, we have fabricated zirconia and graphene nanocomposites (ZrO2/GNS) by simple mechanical mixing and pressureless sintering process. Microstructural observations of the composite show the homogeneous and random distributions of graphene nanosheet in the zirconia matrix. Scanning electronic microscopy observes partially pulled out graphene nanosheets with well combined interface with the matrix in fractural surface, showing promising reinforcement effects.

You might also be interested in these eBooks

Info:

Periodical:

Key Engineering Materials (Volumes 512-515)

Pages:

65-68

Citation:

Online since:

June 2012

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2012 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] M.D. Stoller, S.J. Park, Y.W. Zhu, et al, Graphene-Based Ultracapacitors. Nano Lett. 8 (2008) 3498-3502.

DOI: 10.1021/nl802558y

Google Scholar

[2] C. Lee, X.D. Wei, J.W. Kysar, et al, Measurement of the elastic properties and intrinsic strength of monolayer graphene. Science. 321 (2008) 385-388.

DOI: 10.1126/science.1157996

Google Scholar

[3] S. Stankovich, D.A. Dikin, G.H.B. Dommett, et al, Graphene-based composite materials. Nature. 442 (2006) 282-286.

DOI: 10.1038/nature04969

Google Scholar

[4] Y.C. Fan, L.J. Wang, J.L. Li, et al, Preparation and electrical properties of graphene nanosheet/Al2O3 composites. Carbon. 48 (2010) 1743-1749.

DOI: 10.1016/j.carbon.2010.01.017

Google Scholar

[5] K. Wang, Y.F. Wang, Z.J. Fan, et al, Preparation of graphene nanosheet/alumina composites by spark plasma sintering. Mater. Res. Bull. 46 (2011) 315-318.

DOI: 10.1016/j.materresbull.2010.11.005

Google Scholar

[6] F. Ji, Y.L. Li, J.M. Feng, et al, Electrochemical performance of graphene nanosheets and ceramic composites as anodes for lithium batteries. J. Mater. Chem. 19 (2009) 9063-9067.

DOI: 10.1039/b915838c

Google Scholar

[7] D. Du, J. Liu, X.Y. Zhang, et al, One-step electrochemical deposition of a graphene-ZrO2 nanocomposites: Preparation, characterization and application for detection of organophosphorus agents. J. Mater. Chem. 21 (2011) 8032-8037.

DOI: 10.1039/c1jm10696a

Google Scholar

[8] G.I. Titelman, V. Gelman, S. Bron, et al, Characteristics and microstructure of aqueous colloidal dispersions of graphite oxide. Carbon. 43 (2005) 641-649.

DOI: 10.1016/j.carbon.2004.10.035

Google Scholar

[9] A.C. Ferrari, Raman spectroscopy of graphene and graphite: Disorder, electron-phonon couping, doping and nonadiabatic effects. Solid State Commun. 143 (2007) 47-57.

DOI: 10.1016/j.ssc.2007.03.052

Google Scholar

[10] M.J. Li, Z.C. Feng, G. Xiong, et al, Phase transformation in the surface region of zirconia detected by UV Raman spectroscopy. J. Phys. Chem. B. 105 (2001) 8107-8111.

DOI: 10.1021/jp010526l

Google Scholar