Preparation and Characterization of Amorphous SiO2 Coating SiCp/Cu Composites

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Abstract:

Hybrid sol–gel process was used to fabricate the precursor particles of amorphous SiO2 coating at the composites of SiCp⁄Cu, and then formed by Vacuum hot-pressed method. Various methods were used to measure the sintered compacts of different SiC volume fraction. The results showed that the densities, bending strength and conductivity were decreased slightly with the increases in the amounts of SiC, and the vickers hardness were increased first and then decreased. The techniques of DTA–TG, SEM–EDS and XRD were used to characterize the phases and the morphologies of the composite particles and composites. It was inferred that the formation of SiO2–Cu2O eutectic mixture in this system and the viscous interaction of amorphous SiO2 improved the interfacial modification of the composites of SiCp⁄Cu.

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Key Engineering Materials (Volumes 512-515)

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945-950

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June 2012

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© 2012 Trans Tech Publications Ltd. All Rights Reserved

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[1] K.M. Shu, G.C.Tu, The microstructure and the thermal expansion characteristics of Cu/SiCp composites, Mater. Sci. Eng., A. 349 (2003) 236-247.

DOI: 10.1016/s0921-5093(02)00788-8

Google Scholar

[2] T. Kock, A. Brendel, H. Bolt, Interface reactions between silicon carbide and inter-layers in silicon carbide-copper metal-matrix composites, J. Nucl. Mater. 362 (2007) 197-201.

DOI: 10.1016/j.jnucmat.2007.01.022

Google Scholar

[3] L. Zhang, X.H. Qu, X.B. He, et al, Thermo-physical and mechanical properties of high volume fraction SiCp/Cu composites prepared by pressureless infiltration, Mater. Sci. Eng., A. 489 (2008) 285-293.

DOI: 10.1016/j.msea.2007.12.028

Google Scholar

[4] P. Yih and D.D.L. Chung, Silicon carbide whisker copper-matrix composites fabricated by hot pressing copper coated whiskers, J. Mater. Sci. 31 (1996) 399-406.

DOI: 10.1007/bf01139157

Google Scholar

[5] S.C. Tsang, C.H. Yu, X. Gao and Tam, Phys Silica-Encapsulated Nanomagnetic Particle as a New Recoverable Biocatalyst Carrier, J. Am. Chem. Soc. 110 (2006) 16914-16922.

DOI: 10.1021/jp062275s

Google Scholar

[6] X. Su, J. Zhao, X. Zhao, et al, A facile synthesis of Cu2O/SiO2 and Cu/SiO2 core-shell octahedral nanocomposites, Nanotechnology. 19 (2008) 365610.

DOI: 10.1088/0957-4484/19/36/365610

Google Scholar

[7] L. Guan, B.B. Fan et al, Preparation of SiO2-SiC composites with a precursor method, Ceram. Int. 35 (2009) 1905-1908.

Google Scholar

[8] D.D. Qin, C. Shen, H. Wang, et al, Preparation of SiC-SiO2-CuO composites, J Mater Sci. 42 (2007) 7457-7460.

DOI: 10.1007/s10853-007-1574-1

Google Scholar

[9] R. Zhang, H.L. Wang, L. Gao, et al, Thermochemical Behavior of Cu Coated SiC Composite Particles, J. Inorg. Mater. 20 (2005) 39.

Google Scholar

[10] C.H. Wang, Master Degree Thesis, Zhengzhou University, Henan, China (2007), pp.73-74.

Google Scholar

[11] L. Xin, Master Degree Thesis, Zhengzhou University, Henan, China (2006), pp.32-34.

Google Scholar