Thermophysical and Mechanical Properties of Carbonated Hydroxyapatite

Article Preview

Abstract:

The carbonated hydroxyapatite (CHA) was synthesized by precipitation-calcination method. The influences of carbonate subsitution on high-temperature sintering, thermal expansion coefficient (CET) and flexural strength were investigated by the high-temperature dilatometer, scanning electron microscopy (SEM) and universal testing machine. The results showed that the sintering temperatures of CHA were related to the initial carbonate contents. The sintering temperature decreased with increasing initial carbonate contents. The CET of CHAs decreased with the increase of carbonate content, due to the stoma caused by the partially decompostion of CHAs. The CHA ceramics tested were as strong in flexure strength when compared to non-carbonated hydroxyapatite.

You might also be interested in these eBooks

Info:

Periodical:

Key Engineering Materials (Volumes 512-515)

Pages:

989-993

Citation:

Online since:

June 2012

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2012 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] K.Degroot, C.P.A T.Klein, A.A. Driessen, Calcium phosphate bioceramics, J. Head and Neck Pathol. 4 (1985) 90-94.

Google Scholar

[2] S. Anna, P. Zofia, P. Czesawa, FTIR and XRD evaluation of carbonated hydroxyapatite powders synthesized by wet methods J Mol Struct. 744–747(2005) 657-661.

DOI: 10.1016/j.molstruc.2004.11.078

Google Scholar

[3] F.C.M. Driessens, J H M Woltgens, R M H Verbeeck, Preliminary semi-quantitative study of some gradients in human tooth enamel by infrared spectroscopy Bioceramics of calcium phosphates, J. Bull.Soc. Chim. Belg, 93(1984) 161-167.

DOI: 10.1002/bscb.19840930212

Google Scholar

[4] K.A. Hing, L. Di-silvio, I. R. Gibson et al.: Effect of fluoride substitution on the biocompatibility of hydroxy apatite, Bioceramics. 10(1997) 19-22.

DOI: 10.1016/b978-008042692-1/50005-4

Google Scholar

[5] L. G. Ellies, J. M. Carter, R. J. Natiella et al. Quantitative analysis of early in vivo tissue response to synthetic apatite implants,J. Biomed.Mater.Res. 22 (1988) 137-148.

DOI: 10.1002/jbm.820220206

Google Scholar

[6] P. O'Hare, B.J. Meenan, G.A. Burke et al.: Biomaterials. Biological responses to hydroxyapatite surfaces deposited via a co-incident microblasting technique. 31 (2010) 515-522.

DOI: 10.1016/j.biomaterials.2009.09.067

Google Scholar

[7] O.Gunduz, Z.Ahmad, N.Ekren et al. Reinforcing of Biologically Derived Apatite with Commercial Inert Glass, J. Therm.Comp Mater. 22 (2009) 407-411.

DOI: 10.1177/0892705709105974

Google Scholar

[8] D.J. Curran, T.J. Fleming,G. Kawachi et al,Characterisation and mechanical testing of hydrothermally treated HA/ZrO2 composites, J.Mater. Sci.Mater.Med. 20 (2009) 2235-2241.

DOI: 10.1007/s10856-009-3801-6

Google Scholar

[9] Q.X Zhu and J.Q Wu, Investigation on heat treatment of carbonated hydroxyapatite, Funct Mater. 38(2007) 2055-2058.

Google Scholar

[10] Q.X Zhu and J.Q Wu, Effect of initial carbonate content and heat treatments on preparation and properties of carbonated hydroxyapatite J chin ceram soc. (35)2007 866-870.

Google Scholar

[11] A.A. Baig, J.L. Fox, J Hsu et al.: Effect of Carbonate Content and Crystallinity on the Metastable Equilibrium Solubility Behavior of Carbonated Apatites, J Colloid Interface Sci. 179(1996) 608-617.

DOI: 10.1006/jcis.1996.0255

Google Scholar

[12] L G Ellies, D G A Nelson, J D B Featherstone, Quantitative analysis of early in vivo tissue response to synthetic apatite implants, J Biomed Mater Res, 22(1988) 541-553.

DOI: 10.1002/jbm.820220206

Google Scholar

[13] J E Barralet, S M Best, W Bonfield, Effect of sintering parameters on the density and microstructure of carbonate hydroxyapatite, J Mater Sci Mater Med, 11(2000) 719-724.

Google Scholar

[14] T Toru, T Ikoma, S Yasushi et al. Thermal expansion of type A carbonate apatite, Mater. Sci. Eng., B, 173(2010) 171-175.

Google Scholar

[15] T.I. Ivanova, O.V. Frank Kamenetskaya, A.B. Kol'tsov et al: Crystal Structure of Calcium-Deficient Carbonated Hydroxyapatite. Thermal Decomposition, J. Solid State Chem. 160 (2001) 340-349.

DOI: 10.1006/jssc.2000.9238

Google Scholar

[16] M.H. Luo, Q.Q Xu and Q.X Zhu, An investigation on thermal decomposition and reconstitution of hydroxyapatite,Chin Ceram. 43 (2007) 15-17.

Google Scholar