Photo- and Thermo-Dual-Responsive Organic/Inorganic Hybrid Materials

Xin De Tang; Ye Chen; Fa Qi Yu; Mei Shan Pei

doi:10.4028/www.scientific.net/KEM.538.181

Paper Titles

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Influence of Substrate on μc-Si: H Thin Films
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Novel Thermal-Electrical-Mechanical Model for Simulating Coupled Phenomena in High-Frequency Electronic Devices
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Low-Temperature Synthesis of Nano-Crystalline MgTi₂O₅ Powders by Aqueous Sol-Gel Process
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Photo- and Thermo-Dual-Responsive Organic/Inorganic Hybrid Materials
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Ultrasonication Induced Synthesis of Zn/ZnO Core-Shell Structures
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Determination of Transition Mechanism and Polarity of a c-Plane ZnO Bulk by Using Contactless Electroreflectance Spectrum
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Low-Temperature Synthesis of Nano-Crystalline Zn₂SiO₄ Powders by Aqueous Sol-Gel Process
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HomeKey Engineering MaterialsKey Engineering Materials Vol. 538Photo- and Thermo-Dual-Responsive...

Photo- and Thermo-Dual-Responsive Organic/Inorganic Hybrid Materials

Abstract:

Organic/inorganic hybrid materials based upon stimuli-responsive copolymers have attracted an inceasing attention. Compared with the polymeric materials, these hybrid materials can form aggregates in aqueous solution with much more stable shape-persistance due to the inorganic structure, which facilitate the mass delivery and long-term life. A novel hybrid material based on a new reactive block copolymer, poly(ethylene oxide)-block-poly{3-(trimethoxysilyl)propyl methacrylate-co-N-isopropylacrylamide-co-6-[4-(4-methoxyphenylazo)phenoxy]hexyl methacrylate} [PEO-P(TMSPMA-NIPAM-AzoMA)] was synthesized via atom transfer radical polymerization (ATRP). The vesicles were obtained by self-assembly of the resulting block copolymer in a selective solvent, and then the PTMSPMA block was subjected to hydrolysis and polycondensation reaction to fix vesicle wall in the presence of triethylamine as a catalyst. The photo- and thermo- dual-responsive properties of the vesicles were investigated.

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Key Engineering Materials (Volume 538)

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181-184

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https://doi.org/10.4028/www.scientific.net/KEM.538.181

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Online since:

January 2013

Authors:

Xin De Tang, Ye Chen, Fa Qi Yu, Mei Shan Pei

Keywords:

Hybrid Material, Photo-Responsive, Stimulus-Reponsive Polymer, Thermo-Responsive

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