Magnetic and Mössbauer Studies in Molecular-Based Magnets NBu₄M_A^II[Fe^III(OX)₃](MA=Co, Fe)

Abstract:

The mixed valency character and antiferromagnetic coupling in molecule magnets materials NBu₄MAII[Fe^III(OX)₃]（MA=Co、Fe） were investigated by magnetic measurements and Mössbauer spectroscopy .In the sample NBu₄CoII[Fe^III(OX)₃],the appearence of temperature point of spin-glass phase transition and magnetic phase transition under the zero-field-cooled AC magnetic measurements with the temperature range 5-100 K.The sample NBu₄Fe^II[Fe^III(OX)₃] were carried out in the cooling modes in a field,and the sample exhibits multiple magnetic pole reversals in the warming mode magnetic measurements.The phenomenon of multiple magnetic pole reversals occurs in some of those ferrimagnetic materials consisting of magnetic anisotropy ions and two or more types of antiferromagnetically ordered magnetic ions.The compound NBu₄Fe^II[Fe^III(OX)₃] contains two different spin carries; ie: Fe(II) (S_Fe(II) = 2), Fe(III) (S_Fe(III) = 5/2) comes from the Mössbauer studies.

• Periodical: Key Engineering Materials (Volume 538)
• Pages: 215-218
• DOI: https://doi.org/10.4028/www.scientific.net/KEM.538.215
• Online since: January 2013
• Authors: Qing Lin, Qing Mei Zhang, Guo Dong Tang, Yun He, Xue Hui Long
• Keywords: Compensation Temperature, Magnetism, Mixed Valency, Molecular-Based Magnet

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