Preliminary Studies on the use of Sugar Cane Bagasse Ash (SCBA) in the Manufacture of Alkali Activated Binders

Article Preview

Abstract:

Alkali activated binders require the addition of a mineral-rich amorphous silica and alumina. This paper proposes the use of a mineral residue from the burning of sugar cane bagasse. The alkali activated mixtures were prepared containing binary mixtures of sugar cane bagasse ash (SCBA) and other mineral admixtures: fly ash (FA) or blast furnace slag (BFS). As alkaline activators, mixtures of alkali (Na+ or K+) hydroxide and alkali (Na+ or K+) silicate were used. Alkali-activated pastes and mortars containing binary systems SCBA/FA or SCBA/BFS were prepared and cured at 65 oC. Microstructural properties of these alternative binders were assessed by means of TGA, SEM, XRD and pH measurements. Mechanical strength of mortars was performed after 3 and 7 days at 65 oC. Compressive mechanical strengths of these mortars were in the range 30-55 MPa, showing the good mechanical performance achieved by the alkali activation. Microstructural studies suggested the development of stable matrices and the formation of typical gel.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

689-698

Citation:

Online since:

March 2014

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2014 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] M.M. Tashima, C.F. Fioriti, J.L. Akasaki, J. Payá, L.C. Sousa, J.L. Pinheiro Melges. High reactive rice husk ash (RHA): production method and pozzolanic reactivity,. Ambiente Construído, 2012, 12: 151-163.

DOI: 10.1590/s1678-86212012000200010

Google Scholar

[2] L.M. Ordoñez. "Reutilización de la ceniza de cáscara de arroz como material de construcción: Valorización y optimización de sus propiedades puzolánicas (PhD Thesis). Universidad Politécnica de Valencia, (2007).

DOI: 10.4995/thesis/10251/54126

Google Scholar

[3] J. Monzó, J. Payá, M.V. Borrachero, A. Córcoles. Use of sewage sludge ash (SSA)-cement admixtures in mortars,. Cem Concr Res 1996; 26(9): 1389-1398.

DOI: 10.1016/0008-8846(96)00119-6

Google Scholar

[4] M. García De Lomas, M.I. Sánchez De Rojas, M. Frías. Pozzolanic reaction of a spent fluid catalytic cracking catalyst in FCC-cement mortars,. J Therm Anal Calorim 2007, 90: 443-447.

DOI: 10.1007/s10973-006-7921-7

Google Scholar

[5] J. Payá, J. Monzó, M.V. Borrachero. Fluid catalytic cracking catalyst residue (FC3R) An excellent mineral by-product for improving early-strength development of cement mixtures,. Cem Concr Res 1999; 29: 1773-1779.

DOI: 10.1016/s0008-8846(99)00164-7

Google Scholar

[6] F. Puertas, I. García-Díaz, A. Barba, M.F. Gazulla, M. Palacios, M.P. Gómez, S. Martínez-Ramírez. Ceramic wastes as alternative raw materials for Portland cement clinker production,. Cem Concr Comp 2008 30(9): 798-805.

DOI: 10.1016/j.cemconcomp.2008.06.003

Google Scholar

[7] C. Shi, A. Fernández-Jiménez, A. Palomo. New cements for the 21st century: The pursuit of an alternative to Portland cement,. Cem Concr Res 2011; 41: 750-763.

DOI: 10.1016/j.cemconres.2011.03.016

Google Scholar

[8] P. Duxson, A. Fernández-Jiménez, J.L. Provis, G.C. Lukey, A. Palomo, J.S.J. van Deventer. Geopolymer technology: the current state of the art,. J Mater Sci 2007; 42: 2917-2933.

DOI: 10.1007/s10853-006-0637-z

Google Scholar

[9] M. Frías, E. Villar-Cociña, E.V. Morales, H. Savastano. Study of the pozzolanic reaction kinetics in sugar cane bagasse–clay ash/calcium hydroxide system: kinetic parameters and pozzolanic activity,. Adv Cem Res 2009; 21(1): 23-30.

DOI: 10.1680/adcr.2007.00042

Google Scholar

[10] G.C. Cordeiro, R.D. Toledo Filho, E.M.R. Fairbairn. Effect of calcination temperature on the pozzolanic activity of sugar cane bagasse ash,. Constr Build Mater 2009; 23(10): 22-28.

DOI: 10.1016/j.conbuildmat.2009.02.013

Google Scholar

[11] J. Payá, J. Monzó, M.V. Borrachero, L. Díaz-Pinzón, L.M. Ordoñez. Sugar-cane bagasse ash (SCBA): studies on its properties for reusing in concrete production,. J Chem Tech Biotech 2002; 77(3): 321-325.

DOI: 10.1002/jctb.549

Google Scholar

[12] G.C. Cordeiro, R.D. Toledo Filho, L.M. Tavares, E.M.R. Fairbairn, E.M.R. Pozzolanic activity and filler effect of sugar cane bagasse ash in Portland cement and lime mortars,. Cem Concr Comp 2008; 30(5): 410-418.

DOI: 10.1016/j.cemconcomp.2008.01.001

Google Scholar

[13] J. Payá. La transmutación sostenible de los residuos para nuevas materias primas en el ámbito del concreto,. Dyna 2012; 79: 38-47.

Google Scholar