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Effect of Pore-Forming Agent on Porous Mullite Ceramics from Pyrolysis of Alumina Powders Filled Silicone Resin
Abstract:
Mesoporous and macroporous mullite ceramics were fabricated from pyrolysis of alumina nanopowders filled silicone resin. The effect of pore-forming agent (carbon nanopowders) on the pore structure and mechanical property of the porous mullite ceramics were investigated. By varying the carbon content, the porosity and flexural strength of the obtained ceramics could be easily tuned. Both of the open porosity and average pore size of the obtained samples increased at elevated carbon content, and reached the maximum value of 61.0%, 225.5 nm respectively when the carbon content got the highest point (40 Vol.%). The flexural strength of nanoporous mullite ceramics changed almost with an opposite trend of open porosity, with the biggest value of 36 MPa when 10 Vol.% carbon was adopted. The microstructure of porous mullite ceramics consists of dense region and loose region when the added carbon content was at relatively low level. However, the dense area gradually disappeared with the increasing of carbon content.
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208-211
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March 2014
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© 2014 Trans Tech Publications Ltd. All Rights Reserved
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