Surface Functionalization of Ordered Mesoporous Carbon by Immobilization of Diamine for Cobalt-Ion Adsorption

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Abstract:

Highly ordered mesoporous carbon (CMK-3) was fabricated for the adsorption of cobalt from aqueous solutions. With the high surface area of1112.7m2/g and pore size of 17.2 nm, its abundant mesopores were benefit for providing channels for liquid propagate. In order to improve the adsorption properties,CMK-3 was modified by hydroxylation and amination. Fourier transform infrared (FTIR) spectroscopy can be seen that the amino group was successfully grafted onto the CMK-3 with highly ordered mesoporous structure. The functionalized ordered mesoporous carbon (CMK-3-EDA) ,CMK-3 and CMK-3-OX were used as absents for the adsorption of Co (II) from aqueous solution. The results showed that CMK-3-EDA were more twice effective in adsorption of Co (II) compared to CMK-3, which indicated that CMK-3-EDA had great potential for the adsorption of Co (II).

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Key Engineering Materials (Volumes 602-603)

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300-303

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March 2014

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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[1] B. Ma, S. h. Oh, W. S. Shin, Removal of Co2+, Sr2+ and Cs+ from aqueous solution by phosphate-modified montmorillonite (PMM), Desalination. 276 (2011) 336–346.

DOI: 10.1016/j.desal.2011.03.072

Google Scholar

[2] M. Stachowicz, T. Hiemstra, Multi-competitive interaction of As(III) and As(V) oxyanions with Ca2+, Mg2+, PO3−, and CO2− ions on goethite, J. Colloid Interf. Sci. 320(2008) 400–414.

DOI: 10.1016/j.jcis.2008.01.007

Google Scholar

[3] C. Tian, W. Tao, Selective adsorption behavior of Cu(II) and Cr(VI) heavy metal ions by functionalized ordered mesoporous carbon, Acta Phys. Chim. Sin. 26(2010) 3249-3256.

Google Scholar

[4] G. Liu, S. Zheng, adsorption of aqueous alkylphenolethoxylate surfactants by mesoporous carbon CMK-3, J. Colloid Interf. Sci. 302 (2006) 47–53.

Google Scholar

[5] W. Jiang, L. Sun. Ordered mesoporous carbon CMK-3 modified with Cu(I) for Selective ethylene/ethane adsorption. Sep. Sci. Technol. 48 (2013) 968-976.

DOI: 10.1080/01496395.2012.712600

Google Scholar

[6] Y. Meng, D. Gu, A family of highly ordered mesoporous polymer resin and carbon structures from organic-organic Self-Assembly, Chem. Mater. 18(2006) 4447-4464.

DOI: 10.1021/cm060921u

Google Scholar

[7] H. Tamai, K. Shiraki, surface functionalization of mesoporous and microporous activated carbons by immobilization of diamine, J. Colloid Interf. Sci. 295 (2006) 299–302.

DOI: 10.1016/j.jcis.2005.08.012

Google Scholar