Analysis of CO and NH3 Reductive Gases Mixture by Chemically Modified Nanocrystalline Tin Dioxide

Artem Marikutsa; Marina Rumyantseva; Alexander Gaskov

doi:10.4028/www.scientific.net/KEM.605.227

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HomeKey Engineering MaterialsKey Engineering Materials Vol. 605Analysis of CO and NH3 Reductive Gases Mixture by...

Analysis of CO and NH₃ Reductive Gases Mixture by Chemically Modified Nanocrystalline Tin Dioxide

Abstract:

The possibility to discriminate two reducing gases CO and NH₃ in their mixture by semiconductor gas sensors based on modified nanocrystalline tin dioxide was demonstrated. The selectivity was achieved by the optimization of SnO₂ microstructure, surface modifier and operating temperature. Introducing catalytic clusters of palladium or ruthenium oxides increased tin dioxide sensitivity to CO at low temperature and to ammonia at raised temperature, respectively. Cross-sensing tests verified that SnO₂/RuO₂ sensors are selective to NH₃ in comparison with CO, while SnO₂/PdO displayed a complex behaviour in the presence of both gases. Possible sensor signal formation routes are discussed regarding the modifiers catalytic action and their distinctive influence on surface active sites.

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Periodical:

Key Engineering Materials (Volume 605)

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227-230

DOI:

https://doi.org/10.4028/www.scientific.net/KEM.605.227

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Online since:

April 2014

Authors:

Artem Marikutsa*, Marina Rumyantseva, Alexander Gaskov

Keywords:

Active Sites, Gas Mixture Analysis, Semiconductor Gas Sensor, Surface Modification, TiN Dioxide

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References

[1] H. Liu, J. Park, G. Wang: Sensor Lett. 8 (2010) pp.243-246.

Google Scholar

[2] P.K. Basu, P. Bhattacharyya, N. Saha, H. Saha, S. Basu: Sensor Lett. 6 (2008) p.219–225.

Google Scholar

[3] A.K. Santra, D.W. Goodman: Electrochimica Acta. 47 (2002), p.3595.

Google Scholar

[4] S.F. Yina, B.Q. Xub, X.P. Zhouc, C.T. Au: Applied Catalysis A: General 277 (2004), p.1.

Google Scholar

[5] A. Cabot, J. Arbiol, J.R. Morante, U. Weimar, N. Barsan, W. Gopel: Sens. Actuators B 70 (2000), p.87.

Google Scholar

[6] A.V. Marikutsa, M.N. Rumyantseva, L.V. Yashina, A.M. Gaskov: Solid State Chem. 183 (2010), p.2389.

Google Scholar

[7] A. Marikutsa, V. Krivetskiy, L. Yashina, M. Rumyantseva, E. Konstantinova, A. Ponzoni, E. Comini, A. Abakumov, A. Gaskov: Sens. Actuators B 175 (2012), p.186.

DOI: 10.1016/j.snb.2012.03.003

Google Scholar

[8] A.V. Marikutsa, M.N. Rumyantseva, A.M. Gaskov, E.A. Konstantinova, D.A. Grishina, D.M. Deygen: Thin Solid Films 520 (2011), p.904.

DOI: 10.1016/j.tsf.2011.04.176

Google Scholar

[9] D.D. Frolov, Y.N. Kotovshchikov, I.V. Morozov, A.I. Boltalin, A.A. Fedorova, A.V. Marikutsa, M.N. Rumyantseva, A.M. Gaskov, E.M. Sadovskaya, A.M. Abakumov: Solid State Chem. 186 (2012), p.1.

DOI: 10.1016/j.jssc.2011.11.028

Google Scholar