Fabrication of c-Axis-Oriented Zeolite L Seed Layer on Porous Zirconia Substrate by Electrophoretic Deposition in Strong Magnetic Field

Article Preview

Abstract:

Orientation technique based on the magneto-scientific crystal alignment phenomenon combined with electrophoretic deposition (EPD) technique was applied for the seeding process of zeolite L particles. Well-dispersed, ethanol-based zeolite L suspension was prepared and then consolidated on porous zirconia substrates by EPD. Conducting polypyrrole film synthesized on the zirconia substrate was used as an anodic substrate for the EPD process. The EPD was performed in a superconducting magnet with applying 12 T strong magnetic field to the suspension. The degree of orientation was characterized by XRD and compared with that of the zeolite L layer prepared by slip casting in a 12 T strong magnetic field using the same suspension.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

274-279

Citation:

Online since:

July 2015

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2015 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] M. C. Lovallo and M. Tsapatsis, Preferentially oriented submicron silicalite membranes, AIChE J. 42.

DOI: 10.1002/aic.690421104

Google Scholar

[11] 3020-3029 (1996).

Google Scholar

[2] Gang Li, E. Kikuchi and M. Matsukata, The control of phase and orientation in zeolite membranes by the secondary growth method, Micropor. Mesopor. Mater. 62.

Google Scholar

[3] 211-220 (2003).

Google Scholar

[3] C. Matsunaga, T. Uchikoshi, T. Suzuki, Y. Sakka, and M. Matsuda, Hydrothermal transformation of magnetically orientation-controlled seed layer into orientation-retained dense continuous film in clear reaction solution, J. Ceram. Soc. Jpn. 121.

DOI: 10.2109/jcersj2.121.550

Google Scholar

[7] 550-554 (2013).

Google Scholar

[4] C. Matsunaga, T. Uchikoshi, T. S. Suzuki, Y. Sakka, and M. Matsuda, Orientation control of mordenite zeolite in strong magnetic field, Micropor. Mesopor. Mater. 151, 188–194 (2012).

DOI: 10.1016/j.micromeso.2011.10.038

Google Scholar

[5] Ch. Baerlocher, L. B. McCusker and D. H. Olson, ATLAS OF ZEOLITE FRAMEWORK TYPES, sixth revised edition, Elsevier, Amsterdam, 2007, p.196.

DOI: 10.1016/b978-044453064-6/50279-6

Google Scholar

[6] Y. Wang , H. Li , B. Liu, Q. Gan, Q. Dong, G. Calzaferri and Z. Sun, Fabrication of oriented zeolite L monolayer via covalent molecular linkers, J. Solis State Chem. 181, 2469-2472 (2008).

DOI: 10.1016/j.jssc.2008.06.023

Google Scholar

[7] C. Matsunaga, T. Uchikoshi, T. S. Suzuki, Y. Sakka, and M. Matsuda, Fabrication of the c-axis oriented zeolite L compacts using strong magnetic field, Mater. Lett. 93, 408-410 (2013).

DOI: 10.1016/j.matlet.2012.12.004

Google Scholar

[8] T. Uchikoshi, C. Matsunaga, T. S. Suzuki, Y. Sakka and M. Matsuda, Electrophoretic deposition of orientation-controlled zeolite L layer on porous ceramic substrate, J. Ceram. Soc. Jpn. 121.

DOI: 10.2109/jcersj2.121.370

Google Scholar

[4] 370-372 (2013).

Google Scholar

[9] T. Uchikoshi, T. S. Suzuki, H. Okuyama and Y. Sakka, Electrophoretic deposition of α-alumina particles in a strong magnetic field, J. Mater. Res. 18.

DOI: 10.1557/jmr.2003.0035

Google Scholar

[2] 254-256 (2003).

Google Scholar

[10] T. Uchikoshi, S. Furumi, , N. Shirahata, T. S. Suzuki and Y. Sakka, Conductive Polymer Coating on Nonconductive Ceramic Substrates for Use in the Electrophoretic Deposition Process, J. Am. Ceram. Soc. 91, 1674-1677 (2008).

DOI: 10.1111/j.1551-2916.2007.02228.x

Google Scholar

[11] L. Kreethawate, S. Larpkiattaworn, S. Jiemsirilers, L. Besra and T. Uchikoshi, Application of electrophoretic deposition for inner surface coating of porous ceramic tubes, Surf. Coat. Tech., 205.

DOI: 10.1016/j.surfcoat.2010.08.069

Google Scholar

[7] 1922-1928 (2010).

Google Scholar

[12] T. Uchikoshi, T. S. Suzuki, H. Okuyama and Y. Sakka, Fabrication of textured alumina by electrophoretic deposition in a strong magnetic field, J. Mater. Sci., 39, 861-865 (2004).

DOI: 10.1023/b:jmsc.0000012915.76707.ca

Google Scholar

[13] M. M. J. Treacy andJ. B. Higgins, COLLECTION OF SIMULATED XRD POWDER PATTERNS FOR ZEOLITES, fifth revised edition, Elsevier, Amsterdam, 2007, pp.256-257.

DOI: 10.1016/b978-044453067-7/50593-1

Google Scholar

[14] F. K. Lotgering, Topotactical reactions with ferrimagnetic oxides having hexagonal crystal structures‒I, J. Inorg. Nucl. Chem. 9, 113-123 (1959).

DOI: 10.1016/0022-1902(59)80070-1

Google Scholar

[15] T. Ban, J. Morimoto and Y. Ohya, Fabrication of zeolite L film with different orientations using anisotropic growth of seed crystals by secondary growth method, Mater. Chem. Phys. 109, 347-351 (2008).

DOI: 10.1016/j.matchemphys.2007.12.001

Google Scholar