Layered Double Hydroxides (LDHs) Type Materials Used in Water Treatment

Article Preview

Abstract:

Layered double hydroxides (LDHs) or LDHs matrices used for water treatment have been reviewed in this article. These aggregated nanoparticles can be obtained by sol-gel, hydrothermal or coprecipitation method, therefore their shape, size, properties (such as magnetic, acido-bazic, red-ox, texture and assembly) and applications are tailored as a function of synthesis method and process parameters respectively. Among other materials used in water treatment we chose layered double hydroxides generally named LDHs or in particular case hydrotalcites (MgAlLDHs). During calcination layered structure is destroyed giving rise to new structures like mixed oxides partially crystallized. LDHs and calcined LDHs type materials were able to uptake selected products. An important issue for removal of undesirable species for human health was M2+/M3+ cation ratio. Results show a better uptake of anionic compounds for thermally activated LDHs due to their “memory effect”. A large variety of LDHs was investigated in order to demonstrate their adsorption capacity for anionic compounds, cations, gas compounds even microorganisms. Nowadays one of the atractive issues of nanoscience is both the synthesis of these nanostructures and the assembly and organization way but the interest of scientists is to find new properties and applications in order to protect the environment. These cost effective, eco-friendly materials revealed new opportunities for waste water treatment.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

273-278

Citation:

Online since:

August 2015

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2015 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] J. Liu, C. Duan, J. Zhou, X. Li, G. Qian, Z.P. Xu, Adsorption of bacteria onto layered double hydroxide particles to form bio-granule-like aggregates, Applied Clay Science, 75–76 (2013) 39–45.

DOI: 10.1016/j.clay.2013.02.007

Google Scholar

[2] F.L. Theiss, S.J. Couperthwaite, G.A. Ayoko, R.L. Frost, A review of the removal of anions and oxyanions of the halogen elements from aqueous solution by layered double hydroxides, Journal of Colloid and Interface Science, 417 (2014) 356–368.

DOI: 10.1016/j.jcis.2013.11.040

Google Scholar

[3] M.A. Othman, W.M. Zahid, A.E. Abasaeed, Selectivity of layered double hydroxides and their derivative mixed metal oxides as sorbents of hydrogen sulfide. Journal of Hazardous Materials 254– 255 (2013) 221– 227.

DOI: 10.1016/j.jhazmat.2013.03.030

Google Scholar

[4] Y. Lin, Q. Fang, B. Chen, Perchlorate uptake and molecular mechanisms by magnesium/ aluminum carbonate layered double hydroxides and the calcined layered double hydroxides, Chemical Engineering Journal, 237 (2014) 38–46.

DOI: 10.1016/j.cej.2013.10.004

Google Scholar

[5] A. Halajnia, S. Oustan, N. Najafi, A.R. Khataee, A. Lakzian, The adsorption characteristics of nitrate on Mg–Fe and Mg–Al layered double hydroxides in a simulated soil solution, Applied Clay Science, 70 (2012) 28–36.

DOI: 10.1016/j.clay.2012.09.007

Google Scholar

[6] E.D. Isaacs-Paez, R. Leyva-Ramos, A. Jacobo-Azuara, J.M. Martinez-Rosales, J.V. Flores-Cano, Adsorption of boron on calcined AlMg layered double hydroxide from aqueous solutions. Mechanism and effect of operating conditions, Chemical Engineering Journal, 245 (2014).

DOI: 10.1016/j.cej.2014.02.031

Google Scholar

[7] C. Novillo, D. Guaya, A.P. Avendaño, C. Armijos, J.L. Cortina, I. Cota, Evaluation of phosphate removal capacity of Mg/Al layered double hydroxides from aqueous solutions, Fuel 138 (2014) 72–79.

DOI: 10.1016/j.fuel.2014.07.010

Google Scholar

[8] K. Yang, L. Yan, Y. Yang, S. Yu, R. Shan, H. Yu, B. Zhu, B. Du, Adsorptive removal of phosphate by Mg–Al and Zn–Al layered double hydroxides: Kinetics, isotherms and mechanisms, Separation and Purification Technology, 124 (2014) 36–42.

DOI: 10.1016/j.seppur.2013.12.042

Google Scholar

[9] W. Wang, J. Zhoua, G. Achari, J. Yu, W. Cai, Cr(VI) removal from aqueous solutions by hydrothermal syntheticlayered double hydroxides: Adsorption performance, coexistinganions and regeneration studies, Colloids and Surfaces A: Physicochem, Eng. Aspects, 457 (2014).

DOI: 10.1016/j.colsurfa.2014.05.034

Google Scholar

[10] Y. Guo, Z. Zhu, Y. Qiu, J. Zhao, Adsorption of arsenate on Cu/Mg/Fe/La layered double hydroxide from aqueous solutions, Journal of Hazardous Materials, 239– 240 (2012) 279– 288.

DOI: 10.1016/j.jhazmat.2012.08.075

Google Scholar

[11] S. Li, H. Baic, J. Wang, X. Jing, Q. Liu, M. Zhang, R. Chen, L. Liu, C. Jiao, In situ grown of nano-hydroxyapatite on magnetic CaAl-layered double hydroxides and its application in uranium removal, Chemical Engineering Journal, 193–194 (2012).

DOI: 10.1016/j.cej.2012.04.025

Google Scholar

[12] M.A. González, I. Pavlovic, R. Rojas-Delgado, C. Barriga, Removal of Cu2+, Pb2+ and Cd2+ by layered double hydroxide–humate hybrid, Sorbate and sorbent comparative studies, Chemical Engineering Journal, 254 (2014) 605–611.

DOI: 10.1016/j.cej.2014.05.132

Google Scholar

[13] R. Shan, L. Yan, Y. Yang, K. Yang, S. Yu, H. Yu, B. Zhu, B. Du., Highly efficient removal of three red dyes by adsorption onto Mg–Al-layered double hydroxide. Journal of Industrial and Engineering Chemistry, 21 (2015) 561–568.

DOI: 10.1016/j.jiec.2014.03.019

Google Scholar

[14] A. Gök, M.K. Gök, Y.S. Așci¸ M. Lalikoglu, Equilibrium, kinetics and thermodynamic studies for separationof malic acid on layered double hydroxide (LDH), Fluid Phase Equilibria 372(2014) 15–20.

DOI: 10.1016/j.fluid.2014.03.023

Google Scholar

[15] C. Zhang, S. Yang, H. Chen, H. He, C. Sun, Adsorption behavior and mechanism of reactive brilliant red X-3B inaqueous solution over three kinds of hydrotalcite-like LDHs, Applied Surface Science, 301 (2014) 329–337.

DOI: 10.1016/j.apsusc.2014.02.073

Google Scholar

[16] R. Extremera, I. Pavlovic, M.R. Pérez, C. Barriga, Removal of acid orange 10 by calcined Mg/Al layered double hydroxides from water and recovery of the adsorbed dye, Chemical Engineering Journal, 213 (2012) 392–400.

DOI: 10.1016/j.cej.2012.10.042

Google Scholar