Properties of Natural Rubber/Styrene Butadiene Rubber/Recycled Nitrile Glove (NR/SBR/rNBRg) Blends: The Effects of Recycled Nitrile Glove (rNBRg) Particle Sizes

Article Preview

Abstract:

The effects of different particle sizes of recycled nitrile glove (rNBRg) on curing characteristics and physical properties of natural rubber/styrene butadiene rubber/recycled nitrile glove (NR/SBR/rNBRg) blends were investigated. The particle sizes of rNBRg were differentiated by the method of sizing. S1 was obtained by cutting the rNBRg into smaller sheets; S2 was obtained by passing rNBRg through 2 rolls mill for 10 times; and S3 was obtained by passing rNBRg through 2 rolls mill for 10 times and then mechanically grinded. NR/SBR/rNBRg blends were prepared at 50/30/20 composition using two roll mill at room temperature, with different particle sizes, rNBRg (S1), rNBRg (S2) and rNBRg (S3). Curing characteristics (scorch time, cure time, minimum torque and maximum torque), tensile properties and physical properties (crosslink density, resilience and hardness) of the blends were investigated. Results indicated that scorch time, cure time and minimum torque decreased as the rNBRg particle size decreased, while maximum torque and crosslink density increased. Tensile strength of the blends decreased as the rNBRg particle size reduced, which explained the formation of holes on the surfaces of tensile fracture, observed by scanning electron microscope. The rigidity of NR/SBR/rNBRg blends increased when smaller rNBRg particles were used, which explained the increased in hardness and decreased in resilience of the blends.

You might also be interested in these eBooks

Info:

* - Corresponding Author

[1] Myhre, M. and D.A. MacKillop, Rubber recycling. Rubber Chemistry and Technology, 2002. 75(3): pp.429-474.

DOI: 10.5254/1.3547678

Google Scholar

[2] Adhikari, B., D. De, and S. Maiti, Reclamation and recycling of waste rubber. Progress in polymer science, 2000. 25(7): pp.909-948.

DOI: 10.1016/s0079-6700(00)00020-4

Google Scholar

[3] De, S.K., A. Isayev, and K. Khait, Rubber recycling. 2005: CRC Press.

Google Scholar

[4] Fang, Y., M. Zhan, and Y. Wang, The status of recycling of waste rubber. Materials & Design, 2001. 22(2): pp.123-128.

DOI: 10.1016/s0261-3069(00)00052-2

Google Scholar

[5] Klingensmith, W. and B. Rodgers, Natural Rubber and Recycled Materials, in Rubber Compounding : Chemistry and Applications, B. Rodgers, Editor. 2004, Marcel Dekker: New York, N.Y. pp.1-50.

DOI: 10.1201/9781420030464.ch1

Google Scholar

[6] Klingensmith, W. and K. Baranwal, Recycling of rubber: An overview. Rubber World, 1998. 218(3): p.41.

Google Scholar

[7] Schaefer, R. and R. Isringhaus, Reclaimed rubber, in Rubber Technology. 1987, Springer. pp.505-517.

DOI: 10.1007/978-1-4615-7823-9_18

Google Scholar

[8] 8. Rodgers, B., W.H. Waddell, S. Solis, and W. Klingensmith, Rubber Compounding, in Kirk-Othmer Encyclopedia of Chemical Technology. 2000, John Wiley & Sons, Inc.

DOI: 10.1002/0471238961.1821020211120914.a01.pub2

Google Scholar

[9] Rodgers, B., W.H. Waddell, S. Solis, and W. Klingensmith, Rubber compounding. 2004: Wiley Online Library.

Google Scholar

[10] Rajan, V.V., W.K. Dierkes, R. Joseph, and J.W.M. Noordermeer, Science and technology of rubber reclamation with special attention to NR-based waste latex products. Progress in Polymer Science, 2006. 31(9): pp.811-834.

DOI: 10.1016/j.progpolymsci.2006.08.003

Google Scholar

[11] Rodgers, B., Rubber Compounding: Chemistry and Applications. 2004: Taylor & Francis.

Google Scholar

[12] Sombatsompop, N., Dynamic mechanical properties of SBR and EPDM vulcanisates filled with cryogenically pulverized flexible polyurethane foam particles. Journal of applied polymer science, 1999. 74(5): pp.1129-1139.

DOI: 10.1002/(sici)1097-4628(19991031)74:5<1129::aid-app9>3.0.co;2-q

Google Scholar

[13] Phadke, A., A. Bhowmick, and S. De, Effect of cryoground rubber on properties of NR. Journal of applied polymer science, 1986. 32(3): pp.4063-4074.

DOI: 10.1002/app.1986.070320322

Google Scholar

[14] Sreeja, T.D. and S.K.N. Kutty, Cure Characteristics And Mechanical Properties Of Natural Rubber/Reclaimed Rubber Blends. Polymer-Plastics Technology and Engineering, 2000. 39(3): pp.501-512.

DOI: 10.1081/ppt-100100043

Google Scholar

[15] Ismail, H., R. Nordin, and A.M. Noor, The comparison properties of recycle rubber powder, carbon black, and calcium carbonate filled natural rubber compounds. Polymer-Plastics Technology and Engineering, 2002. 41(5): pp.847-862.

DOI: 10.1081/ppt-120014392

Google Scholar

[16] Zulkepli, N.N., H. Ismail, and A. Rashid, Effects of different particle sizes of recycled acrylonitrile-butadiene rubber and its blend ratios on mechanical and morphological properties and curing characteristics of SBR/NBRr blends. Iran Polym J, 2009. 18(2): pp.139-148.

DOI: 10.4028/www.scientific.net/amr.795.377

Google Scholar

[17] Yahya, N., N. Zakaria, N.N. Zulkepli, H. Ismail, M.A.A.M. Salleh, and S. Ragunathan, Natural rubber/styrene butadiene rubber/recycled nitrile glove (NR/SBR/rNBRg) ternary blend: Curing characteristics and swelling test. Key Engineering Materials, 2014. 594: pp.634-638.

DOI: 10.4028/www.scientific.net/kem.594-595.634

Google Scholar

[18] Nik Zakaria, N.Y., N. Noriman, I. Hanafi, S.T. Sam, and R. Santiagoo, Natural rubber/styrene butadiene rubber/recycled nitrile glove (NR/SBR/rNBRg) ternary blend: Tensile properties & morphology. (2013).

DOI: 10.4028/www.scientific.net/kem.594-595.634

Google Scholar

[19] Flory, P.J. and J. Rehner Jr, Crosslink density equation. The Journal of Chemicals and Physics, 1943. 11: p.5120.

Google Scholar

[20] Mathew, G., R.P. Singh, R. Lakshminarayanan, and S. Thomas, Use of natural rubber prophylactics waste as a potential filler in styrene–butadiene rubber compounds. Journal of Applied Polymer Science, 1996. 61(11): p.2035-(2050).

DOI: 10.1002/(sici)1097-4628(19960912)61:11<2035::aid-app19>3.0.co;2-7

Google Scholar

[21] Nasir, M.R.J., N.N. Zulkepli, M.M.A.B. Abdullah, M.F. Omar, H. Ismail, and A.V. Sandu, The Effects of Different Particle Sizes of Recycled Acrylonitrile Butadiene Rubber and its Blend Ratios on Mechanical and Morphological Properties of vNBR/rNBR Blends. MATERIALE PLASTICE, 2014. 51(2): pp.201-204.

DOI: 10.4028/www.scientific.net/kem.594-595.735

Google Scholar

[22] Ahmad, H., H. Ismail, and A. Azura, Comparison properties of natural rubber/virgin acrylonitrile–butadiene rubber and natural rubber/recycled acrylonitrile–butadiene rubber blends. Iranian Polymer Journal, 2015. 24(3): pp.185-195.

DOI: 10.1007/s13726-015-0310-y

Google Scholar