Effects of Chromium Content on Thermal Shock Cycle Resistance of (TiCr)N Hard Reactive Films

Article Preview

Abstract:

The (TiCr)N hard reactive films with 4 different Ti/Cr atomic ratios are prepared by using multi-arc ion plating. The Ti and Cr targets are used as cathodes in the co-deposition process. The high speed steel (HSS) specimens are adopted as substrate. The thermal shock cycle tests in air cooling (AC) way for the (TiCr)N films are carried out. The test temperatures are chosen as 600 °C and 700 °C, respectively. The changes of the surface compositions and morphology in the thermal shock cycle tests are investigated. The effects of Cr content in the (TiCr)N films, the temperature at which the thermal shock cycle tests are performed and the cycling times on the thermal shock resistance of the (TiCr)N films are discussed and analyzed in detail. The thermal shock behaviors of the (TiCr)N films show that the thermal shock cycling process of the (TiCr)N films consists of two stages, the steady-state oxidation stage with the increase of oxygen content at the early stage of thermal cycles, and, the instable oxidation stage with the oxidation aggravation and the occurrence of the surface cracks. The simple increase of Cr content in the (TiCr)N film does not improve the thermal shock resistance of the (TiCr)N films but easy to aggravate the surface oxidation process during the thermal shock cycles.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

150-155

Citation:

Online since:

June 2017

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2017 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] J. G. Han, H. S. Myung, H. M. Lee, L. R. Shaginyan, Microstructure and mechanical properties of Ti–Ag–N and Ti–Cr–N superhard nanostructured coatings, Surf. Coat. Technol. 174-175 (2003) 738-742.

DOI: 10.1016/s0257-8972(03)00565-6

Google Scholar

[2] D. J. Li, F. Liu, M. X. Wang, J. J. Zhang, Q. X. Liu, Structural and mechanical properties of multilayered gradient CrN/ZrN coatings, Thin Solid Films 506-507 (2006) 202-206.

DOI: 10.1016/j.tsf.2005.08.031

Google Scholar

[3] G. G. Fuentes, M. J. Díaz de Cerio, J. A. García, R. Martínez, R. Bueno, R. J. Rodríguez, M. Rico, F. Montalá, Y. Qin, Gradient CrCN cathodic arc PVD coatings, Thin Solid Films 517(20) (2009) 5894-5899.

DOI: 10.1016/j.tsf.2008.08.005

Google Scholar

[4] Z. H. Cai, Y. L. Di, J. W. He et al. Investigation of Microstructure and Tribological Properties of Crx Ti1-xN Composite Films on Piston Ring, Adv. Mater. Res. 287-290 (2011) 2148-2151.

Google Scholar

[5] S. Samapisut, U. Tipparach, G. Heness, G. McCredie, Effect of magnetrondischarge power and N2 flow rate for preparation of TiCrN thin film, Procedia Eng. 32 (2012) 1135-1138.

DOI: 10.1016/j.proeng.2012.02.067

Google Scholar

[6] G. Kirchhoff, Th. Gobel, H. -A. Bahr, H. Balke, K. Wetzig, K. Bartsch, Damage analysis for thermally cycled (Ti, Al)N coatings—estimation of strength and interface fracture toughness, Surf. Coat. Technol. 179(1) (2004) 39-46.

DOI: 10.1016/s0257-8972(03)00794-1

Google Scholar

[7] J. Zhang, H. Lv, G. Cui, Z. Jing, C. Wang, Effects of bias voltage on the microstructure and mechanical properties of (Ti, Al, Cr)N hard films with N-gradient distributions, Thin Solid Films, 519(15) (2011) 4818-4823.

DOI: 10.1016/j.tsf.2011.01.036

Google Scholar

[8] C. Mitterbauer, W. Grogger, P. Wilhartitz, F. Hofer, Electron-irradiation damage in chromium nitrides and chromium oxynitride thin films, Micron 37(5) (2006) 385-388.

DOI: 10.1016/j.micron.2006.01.006

Google Scholar

[9] L. Wu, J. Gao, Z. Liu, L. Liang, F. Xia, H. Cao, Thermal aging characteristics of CrNxOy solar selective absorber coating for flat plate solar thermal collector applications, Sol. Energy Mater. Sol. Cells, 114 (2013) 186-191.

DOI: 10.1016/j.solmat.2013.03.005

Google Scholar

[10] Y. Feng, J. Zhang, Investigation of Microstructure and Mechanical Properties of (CrTiNb)N Films, Adv. Mater. Res. 287-290 (2014) 808-811.

Google Scholar