Effect of Plasticizers on Morphology, Mechanical Properties and Water Absorption of Wheat Gluten and Epoxidized Natural Rubber Blend

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Wheat gluten (WG) plastics are inherently brittle and sensitive to water. In this research, wheat gluten was blended with epoxidized natural rubber containing 50 mol% epoxide group (ENR-50) to improve flexibility and water resistance of WG plastics. Three plasticizers (i.e. glycerol (Gly), polyethylene glycol (PEG) and dioctyl phthalate (DOP) were used to enhance polymer chain mobility and process ability of WG phase in the blends. Differential scanning calorimetry (DSC) was used to evaluate plasticizing efficiency of plasticizers on WG. The DSC result revealed that an excellent plasticizer for WG was glycerol which could remarkably reduce glass transition temperature (Tg) of WG. Furthermore, effect of plasticizer types and contents (0, 10, 20 and 30wt% with respect to protein weight) on morphology, mechanical properties and water absorption of the WG/ENR blends was investigated. It was found that an enhancement in ductility and impact strength of the blends was observed with increasing plasticizer content. Among the plasticized WG/ENR blends, the glycerol-plasticized blend provided better homogenous morphology and superior results in tensile and impact properties. On the other hand, the Gly-plasticized WG/ENR blend showed a low water resistance compared with the blends plasticized with PEG and DOP as well as the unplasticized WG/ENR blend.

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287-293

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June 2017

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© 2017 Trans Tech Publications Ltd. All Rights Reserved

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[1] S. W. Lim, I. K. Jung, K. H. Lee, B. S. Jin, Structure and properties of biodegradable gluten/ aliphatic polyester blends, Eur. Polym. J. 35 (1999) 1875-1881.

DOI: 10.1016/s0014-3057(98)00273-0

Google Scholar

[2] V. L. Finkenstadt, A. A. Mohamed, G. Biresaw, J. L. Willett, Mechanical properties of green composites with polycaprolactone and wheat gluten, J. Appl. Polym. Sci. 110 (2008) 2218-2226.

DOI: 10.1002/app.28446

Google Scholar

[3] S. Hemsri, C. Thongpina, N. Supatti, P. Manomai, A. Socharoentham, Bio-based blends of wheat gluten and maleated natural rubber: morphology, mechanical properties and water absorption, Energ. Proc. 89 (2016) 264-273.

DOI: 10.1016/j.egypro.2016.05.034

Google Scholar

[4] M. Gallstedt, A. Mattozzi, E. Johansson, M. S. Hedenqvist, Transport and tensile properties of compression-molded wheat gluten films, Biomacromolecules, 5 (2004) 2020-(2028).

DOI: 10.1021/bm040044q

Google Scholar

[5] N. Gontrd, S. Guilbert, J. Cuq, Water and glycerol as plasticizers affect mechanical and water vapor barrier properties of an edible wheat gluten film, J. Food Sci. 58 (1993) 206-211.

DOI: 10.1111/j.1365-2621.1993.tb03246.x

Google Scholar

[6] J. Irissin-Mangata, G. Bauduin, B. Boutevin, N. Gontard, New plasticizers for wheat gluten films, Eur. Polym. J. 37 (2001) 1533-1541.

DOI: 10.1016/s0014-3057(01)00039-8

Google Scholar

[7] Y. Song, Q. Zheng, Improved tensile strength of glycerol-plasticized gluten bioplastic cotaining hydrophobic liquid, Bioresour. Technol. 99 (2008) 7665-7671.

DOI: 10.1016/j.biortech.2008.01.075

Google Scholar

[8] M. T. Kalichevsky, E. M. Jaroszkiewicz, J. M. V. Blanshard, Glass transition of gluten. 2: The effect of lipids and emulsifiers, Int. J. Biol. Macromol. 14 (1992) 267-273.

DOI: 10.1016/s0141-8130(05)80039-x

Google Scholar

[9] S. Hemsri, C. Thongpin, P. Somkid, S. Sae-arma, A. Paiykaew, Improvement of toughness and water resistance of bioplastic based on wheat gluten using epoxidized natural rubber, IOP Conf. Series: Materials Science and Engineering 87 (2015) 012049.

DOI: 10.1088/1757-899x/87/1/012049

Google Scholar

[10] T. R. Neo, R. Parker, S. R. Ring, A. S. Tatham, The glass transition behavior of wheat gluten proteins, Int. J. Biol. Macromol. 17 (1995) 81-85.

Google Scholar

[11] C. M. Hansen, Hansen Solubility Parameters: A User's Handbook, second ed. CRC Press, New York, (2007).

Google Scholar

[12] C. Nakoson, M. Marathichat, C. Kummerlowe, N. Vennemann, Thermoplastic natural rubber on polyamide-12 blended with various types of natural rubber: Effect of processing oil and plasticizer, J. Elastomers & Plastics J. Elastom. Plast. 45 (2013).

DOI: 10.1177/0095244312445522

Google Scholar