Use of Waste Glass as a Reinforce Material in Calcined-Kaolin Based Geopolymer

Article Preview

Abstract:

Geopolymer is widely known as an environmentally-friendly construction material due to the remarkably low emission of CO2 in its manufacturing process. This inorganic polymer can be produced via two precursors: solid component and alkaline activator. In the present work, the studied program was divided into two steps. In Step 1, the molarity of NaOH was investigated. The calcined-kaolin from Lampang city (Thailand source) was used as base alumino-silicate material. In addition, the concentrations of NaOH (5M, 10M, 15M and 20M) were utilized as alkaline activator for geopolymerization. After mixing, the geopolymer slurry was casted into a size of a 50 mm ´ 50 mm ´ 50 mm steel mold. The curing condition of all specimens was maintained at 60°C for 7 days. The compressive strength of all specimens was tested. The utilization of 10M of NaOH yielded the highest compressive strength with the value of 22.01 MPa. In Step 2, 10M of NaOH was fixed and used as alkaline activator. In this case, the amount of waste glass (0%, 10%, 20%, 30%, 40% and 50% by weight) was studied on partial calcined-kaolin replacement. However, the compressive strength of all samples slightly changed with an increasing weight percentage of waste glass (0% - 20 %). The highest compressive strength of 20 wt% waste glass was 25.22 MPa. Although, all samples showed a Si-O-Al bond in the FTIR result, indicating the geopolymer degree strenghened. However, the compressive strength of samples tended to decrease with an increase in the amount of waste glass (30 to 50 wt%) as a result of micro-cracks observed and distributed in the samples.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

556-562

Citation:

Online since:

August 2017

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2017 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] L.Y. Gomez-Zamorano, E. Vega-Cordero and L. Struble, Composite geopolymers of metakaolin and geothermal nanosilica waste, Constr. Build. Mater. 115 (2016) 269-276.

DOI: 10.1016/j.conbuildmat.2016.03.002

Google Scholar

[2] Z.H. Zhang, H.J. Zhu, C.H. Zhou and H. Wang, Geopolymer from kaolin in China: An overview, Appl. Clay Sci. 119 (2016) 31-41.

DOI: 10.1016/j.clay.2015.04.023

Google Scholar

[3] Y.H. Liew, C.Y. Heah, A.M. Mustafa Al Bakri and H. Kamarudin, Structure and properties of clay-based geopolymer cements. A review, Prog. Mater. Sci. 83 (2016) 595-629.

DOI: 10.1016/j.pmatsci.2016.08.002

Google Scholar

[4] P. Nath and P.K. Sarker, Use of OPC to improve setting and early strength properties of low calcium fly ash geopolymer concrete cured at room temperature, Cem. Concr. Comp. 55 (2015) 205-214.

DOI: 10.1016/j.cemconcomp.2014.08.008

Google Scholar

[5] H. Wang, H. Li and F. Yan, Synthesis and mechanical properties of metakaolinite-based geopolymer, Coll. Surf. -A Physicochem Eng. Asp. 268 (2005) 1–6.

Google Scholar

[6] R.A. Robayo-Salazar, R.M. de Gutiérrez and F. Puertas, Effect of metakaolin on natural volcanic pozzolan-based geopolymer cement, Appl. Clay Sci. 132-133 (2016) 491-497.

DOI: 10.1016/j.clay.2016.07.020

Google Scholar

[7] C.Y. Heah, H. Kamarudin, A.M. Mustafa Al Bakri, M. Bnhussain, M. Luqman, I. Khairul Nizar, C.M. Ruzaidi and Y.M. Liew, Study on solids-to-liquid and alkaline activator ratios on kaolin-based geopolymers, Constr. Build. Mater. 35 (2012) 912-922.

DOI: 10.1016/j.conbuildmat.2012.04.102

Google Scholar

[8] H.Y. Leong, D.E.L. Ong, J.G. Sanjayan and A. Nazari, The effect of different Na2O and K2O ratios of alkali activator on compressive strength of fly ash based-geopolymer, Constr. Build. Mater. 106 (2016) 500-511.

DOI: 10.1016/j.conbuildmat.2015.12.141

Google Scholar

[9] G. Gorhan, R. Aslaner and O. Sinik, The effect of curing on the properties of metakaolin and fly ash-based geopolymer paste, Comp. Part B 97 (2016) 329-335.

DOI: 10.1016/j.compositesb.2016.05.019

Google Scholar

[10] A. Vásquez, V. Cárdenas, R.A. Robayo and R. Mejía de Gutiérrez, Geopolymer based on concrete demolition waste, Adv. Powder Tech. 27 (2016) 1173-1179.

DOI: 10.1016/j.apt.2016.03.029

Google Scholar

[11] H.K. Tchakouté, C.H. Rüscher, S. Kong, E. Kamseu and C. Leonelli, Geopolymer binders from metakaolin using sodium waterglass from waste glass and rice husk ash as alternative activators: A comparative study, Constr. Build. Mater. 114 (2016).

DOI: 10.1016/j.conbuildmat.2016.03.184

Google Scholar

[12] S.O. Sore, A. Messan, E. Prud'homme, G. Escadeillas and F. Tsobnang, Synthesis and characterization of geopolymer binders based on local materials from Burkina Faso – Metakaolin and rice husk ash, Constr. Build. Mater. 124 (2016) 301-311.

DOI: 10.1016/j.conbuildmat.2016.07.102

Google Scholar

[13] A.I. Badanoiu, T.H. Abood Al Saadi, S. Stoleriu and G. Voicu, Preparation and characterization of foamed geopolymers from waste glass and red mud, Constr. Build. Mater. 84 (2015) 284-293.

DOI: 10.1016/j.conbuildmat.2015.03.004

Google Scholar

[14] R.M. Novais, G. Ascensão, M.P. Seabra, J.A. Labrincha, Waste glass from end-of-life fluorescent lamps as raw material in geopolymers, Waste Management 52 (2016) 245-255.

DOI: 10.1016/j.wasman.2016.04.003

Google Scholar

[15] M. Arikan, K. Sobolev, T. Ertun, A. Yeginobali and P. Turker, Properties of blended cements with thermally activated kaolin, Constr. Build. Mater. 23 (2009) 62–70.

DOI: 10.1016/j.conbuildmat.2008.02.008

Google Scholar