Upgrading of Waste Gypsum for Building Materials

Article Preview

Abstract:

In this research, waste gypsum (CaSO4·2H2O), a by-product material from industrial factory, was upgraded and then used as raw material for building materials. The by-product gypsum possessed a high acidic value of 3-point pH scale and moisture content of 40 %. The two properties had an impact on setting reaction and hardening of gypsum. Therefore, the studies of gypsum phase transformation to calcium sulfate hemihydrate (CaSO4·0.5H2O) were focused on washing process and amount of calcium carbonate (CaCO3) added at 0, 1, 3 and 5 % wt. After washing, waste gypsum and washed water were reduced from high acidic value to neutralization (pH = 7) as a result of CaCO3. Next, the neutralized gypsum was heated to the optimal temperature at 160 °C for 2 hours and transformed to hemihydrate gypsum phase observed by XRD. Finally, the relationship of amount of CaCO3-mechanical property such as bending strength will be investigated.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

211-216

Citation:

Online since:

April 2018

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2018 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] N. Lushnikova, L. Dvorkin, Sustainability of gypsum products as a construction material, Sustainability of construction material. (2016) 643-681.

DOI: 10.1016/b978-0-08-100370-1.00025-1

Google Scholar

[2] B. Guan, L. Yang, H. Fu, B. Kong, T. Li, L. Yang, α-calcium sulfate hemihydrate preparation from FGD gypsum in recycling mixed salt solutions, Chem. Eng. J. 174 (2011) 296–303.

DOI: 10.1016/j.cej.2011.09.033

Google Scholar

[3] C. Liu, Q. Zhao, Y. Wang, P. Shi, M. Jiang, Hydrothermal synthesis of calcium sulfate whisker from flue gas desulfurization gypsum, Chinese J. Chem. Eng. 24 (2016) 1552–1560.

DOI: 10.1016/j.cjche.2016.04.024

Google Scholar

[4] W. Xiaoqin, T. Shitang, G. Baohong, W. Zhongbiao, Transformation of flue-gas-desulfurization gypsum to α-hemihydrated gypsum in salt solution at atmospheric pressure, Chinese J. Chem. Eng. 19 (2011) 349-355.

DOI: 10.1016/s1004-9541(11)60175-4

Google Scholar

[5] B. Guan, B. Kong, H. Fu, J. Yu, G. Jiang, L. Yang, Pilot scale preparation of α-calcium sulfate hemihydrate from FGD gypsum in Ca-K-Mg aqueous solution under atmospheric pressure, Fuel. 98 (2012) 48-54.

DOI: 10.1016/j.fuel.2012.03.032

Google Scholar

[6] N.M.P.D. Silva, Y. Rong, F. Espitalier, F. Baillon, A. Gaunand, Solvothermal recrystallization of α-calcium sulface hemihydrate: Batch reactor experiments and kinetic modelling, J. Cryst. Growth. (2017).

DOI: 10.1016/j.jcrysgro.2017.02.010

Google Scholar

[7] P.T. rek, J. Drchalova, J. K. sko, P. R. kova, R. erny, Flue gas desulfurization gypsum: Study of basic mechanical, hydric and thermal properties, Constr. Build. Mater. 21 (2007) 1500–1509.

DOI: 10.1016/j.conbuildmat.2006.05.009

Google Scholar

[8] H. Sun, D. Tan, T. Peng, Y. Liang, Preparation of calcium sulfate whisker by atmospheric acidification method from flue gas desulfurization gypsum, Procdia Environmental Sciences. 31 (2016) 621-626.

DOI: 10.1016/j.proenv.2016.02.112

Google Scholar

[9] M. Singh, Treating waste phosphogypsum for cement and plaster manufacture, Cement Concrete Res. 32 (2002) 1033 – 1038.

DOI: 10.1016/s0008-8846(02)00723-8

Google Scholar

[10] Q.L. Lu, H.J.H. Brouwers, Development of a self-compacting gypsum-based lightweight composite, Cement Concrete comp. 34 (2012) 1033-1043.

DOI: 10.1016/j.cemconcomp.2012.05.004

Google Scholar

[11] A.J. Rivero, A.D.G. Baez, J.G. Navarro, New composite gypsum plaster – ground waste rubber coming from pipe foam insulation, Constr. Build. Mater. 55 (2014) 146-152.

DOI: 10.1016/j.conbuildmat.2014.01.027

Google Scholar

[12] A. Vimmrova, M. Keppert, L. Svoboda, R. Cerny, Lightweight gypsum composites: Design strategies for multi-functionality, Cement Concrete comp. 33 (2011) 84-89.

DOI: 10.1016/j.cemconcomp.2010.09.011

Google Scholar

[13] A. Telesca, M. Marroccoli, D. Calabrese, G.L. Valenti, F. Montagnaro, Flue gas desulfurization gypsum and coal fly ash as basic components of prefabricated building materials, Waste Manage. 33 (2013) 628-633.

DOI: 10.1016/j.wasman.2012.10.022

Google Scholar

[14] J. Zhou, C. Liu, Z. Shu, D. Yu, Q. Zhang, T. Li, Q. Xue, Preparation of specific gypsum with advanced hardness and bending strength by a novel in-situ loading-hydration process, Cement Concrete Res. 67 (2015) 179-183.

DOI: 10.1016/j.cemconres.2014.09.004

Google Scholar