Effect of Frequency and Duty Cycle on Growth, Structure and Corrosion Resistance of Micro Arc Oxidation Coating on RZ5 Magnesium Alloy

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Magnesium alloys inherently possess poor corrosion resistance. One of the surface modification techniques to improve the corrosion resistance of magnesium alloys is Micro Arc Oxidation (MAO). Application of RZ5 magnesium alloy in aircraft industries demands assured corrosion resistance of RZ5. The quality of the ceramic oxide coating developed by MAO is influenced by various operating parameters. In this study, oxide coatings on RZ5 Magnesium alloy were developed by MAO at two different frequency levels (100Hz and 1000Hz) and at two duty cycles (10% and 90%) at a constant current density of 0.06A/cm2 for 15 minutes in a silicate based electrolyte (10g/l Na2SiO3.9H2O + 4g/l KOH). Results showed that the coating produced with the combination of higher frequency and lower duty cycle exhibits a better corrosion resistance than the coating produced with other combinations of parameters.

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291-297

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August 2018

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© 2018 Trans Tech Publications Ltd. All Rights Reserved

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[1] J.E. Gray, B. Luan, Protective coatings on magnesium and its alloys - a critical review, J. Alloys Compd. 336 (2002) 88–113.

DOI: 10.1016/s0925-8388(01)01899-0

Google Scholar

[2] L. Chang, Growth regularity of ceramic coating on magnesium alloy by plasma electrolytic oxidation, J. Alloys Compd. 468 (2009) 462–465.

DOI: 10.1016/j.jallcom.2008.01.069

Google Scholar

[3] G.L. Song, Corrosion prevention of magnesium alloys, in: B.L. Jiang, Y.F. Ge (Eds.), Micro-arc oxidation (MAO) to improve the corrosion resistance of magnesium (Mg) alloys, Woodhead Publishing Limited, 2013, pp.163-196.

DOI: 10.1533/9780857098962.2.163

Google Scholar

[4] S. Gowtham, T. Arunnellaiappan, N. Rameshbabu, An investigation on pulsed DC plasma electrolytic oxidation of Cp-Ti and its corrosion behaviour in simulated body fluid, Surf. Coatings Technol. 301 (2016) 63–73.

DOI: 10.1016/j.surfcoat.2016.02.043

Google Scholar

[5] Information on https://www.magnesium-elektron.com/product__service/aerospace.

Google Scholar

[6] T. Arunnellaiappan, N. Kishore Babu, L. Rama Krishna, N. Rameshbabu, Influence of frequency and duty cycle on microstructure of plasma electrolytic oxidized AA7075 and the correlation to its corrosion behavior, Surf. Coatings Technol. 280 (2015).

DOI: 10.1016/j.surfcoat.2015.08.043

Google Scholar

[7] P. Bala Srinivasan, J. Liang, C. Blawert, M. Störmer, W. Dietzel, Effect of current density on the microstructure and corrosion behaviour of plasma electrolytic oxidation treated AM50 magnesium alloy, Appl. Surf. Sci. 255 (2009) 4212–4218.

DOI: 10.1016/j.apsusc.2008.11.008

Google Scholar

[8] T. S. N. Sankara Narayanan, Il-Song Park and Min-Ho Lee, Surface Modification of Magnesium and its Alloys for Biomedical Applications Volume 2: Modification and Coating Techniques, in: C. Blawert, S.P. Sah, N. Scharnagl, M.B. Kannan (Eds.), Plasma electrolytic oxidation/micro-arc oxidation of magnesium and its alloys, Woodhead Publishing Limited, 2015, pp.193-227.

DOI: 10.1016/b978-1-78242-078-1.00008-6

Google Scholar

[9] V. Dehnavi, B. Li, D.W. Shoesmith, X. Yang, S. Rohani, Effect of duty cycle and applied current frequency on plasma electrolytic oxidation (PEO) coating growth behavior, Surf. Coat. Technol. 226 (2013) 100–107.

DOI: 10.1016/j.surfcoat.2013.03.041

Google Scholar

[10] G.H. Lv, H. Chen, W.C. Gu, L. Li, E.W. Niu, X.H. Zhang, S.Z. Yang, Effects of current frequency on the structural characteristics and corrosion property of ceramic coatings formed on magnesium alloy by PEO technology, J. Mater. Process. Technol. 208 (2008).

DOI: 10.1016/j.jmatprotec.2007.12.125

Google Scholar

[11] Y. Tang, X. Zhao, K. Jiang, J. Chen, Y. Zuo, The influences of duty cycle on the bonding strength of AZ31B magnesium alloy by microarc oxidation treatment, Surf. Coat. Technol. 205 (2010) 1789–1792.

DOI: 10.1016/j.surfcoat.2010.05.016

Google Scholar

[12] P.B. Srinivasan, J. Liang, R.G. Balajeee, C. Blawert, M. Störmer, W. Dietzel, Effect of pulse frequency on the microstructure, phase composition and corrosion performance of a phosphate-based plasma electrolytic oxidation coated AM50 magnesium alloy, Appl. Surf. Sci. 256 (2010).

DOI: 10.1016/j.apsusc.2010.01.052

Google Scholar