Effect of Graphene for Ablation Study of Advanced Composite Materials for Aerospace Applications

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Abstract:

Graphene was incorporated into elastomeric Matrices using dispersion kneader and two roller mixing mill to fabricate ablative nanocomposites used in hyperthermal environment encountered by space vehicle or rocket motor. The addition of graphene in the host matrix has remarkably reduced the backface temperature elevation during the ablation testing of the ablatives. The linear and mass ablation resistances have been diminished while insulation indexes of the nanocomposites have been increased the graphene incorporation into the elastomeric matrix. Thermal stability and heat absorbance capability of the polymer nanocomposites were progressed with increasing the filler to matrix ratio. Thermal conductivity of the ablatives have been conducted according to the ASTM E1225-99 and D5470-03, respectively to execute the effect of graphene concentration on the thermal transport characteristics of the tested specimens. Tensile strength of the nanocomposite specimen was augmented with increasing graphene to polymer ratio. Scanning electron microscopy was used to scrutinize the evenly dispersed graphene in the polymer matrix, polymer pyrolysis, and voids formation in the ablated nanocomposites.

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[1] M. Moniruzzaman, K.I. Winey, Polymer nanocomposites containing carbon nanotubes, Macromolecu., 39 (2006) 5194-5205.

DOI: 10.1021/ma060733p

Google Scholar

[2] H. Ma, L. Tong, Z. Xu, Z. Fang, Synergistic effect of carbon nanotube and clay for improving the flame retardancy of ABS resin, Nanotechnol., 18 (2007) 375602.

DOI: 10.1088/0957-4484/18/37/375602

Google Scholar

[3] M.A. Atieh, Effect of Functionalized Carbon Nanotubes with Carboxylic Functional Group on the Mechanical and Thermal Properties of Styrene Butadiene Rubber, Fuller. Nanotub. Carbon Nanostruct., 19 (2011) 617-627.

DOI: 10.1080/1536383x.2010.504953

Google Scholar

[4] N. Iqbal, S. Sagar, M.B. Khan, H.M. Rafique, Ablation, thermal stability/transport and mechanical investigations of modified nanokaolinite impregnated acrylonitrile butadiene rubber composites, J. Comp. Mater., 48 (2013) 1221-1231.

DOI: 10.1177/0021998313484948

Google Scholar

[5] J.K. Park, T.J. Kang, Thermal and ablative properties of low temperature carbon fiber–phenol formaldehyde resin composites, Carbon. 40 (2002) 2125-2134.

DOI: 10.1016/s0008-6223(02)00063-5

Google Scholar

[6] N. Iqbal, S. Sagar, M.B. Khan, M.I. Bassyouni, Z.M. Khan, Aluminum silicate fibers impregnated acrylonitrile butadiene rubber composites: Ablation, thermal transport/stability, and mechanical inspection, J. Appl. Poly. Sci., 130 (2013) 4392-4400.

DOI: 10.1002/app.39717

Google Scholar

[7] S.S. Iqbal, F. Inam, A. Bahadar, M.A. Bashir, F. Hassan, M.B. Khan, Z.M. Khan, T. Jamil, Ablation, thermal stability/transport/phase transition study of carbon nanofiber-reinforced elastomeric nanocomposites, J. Therm. Analy. Calorim., (2017).

DOI: 10.1007/s10973-017-6831-1

Google Scholar

[8] S. Sagar, N. Iqbal, A. Maqsood, U. Javaid, Thermogravimetric, differential scanning calorimetric and experimental thermal transport study of MWCNT/NBR nanocomposites, J. Therm. Analy. Calorim. 114 (2013) 161-167.

DOI: 10.1007/s10973-013-2949-y

Google Scholar

[9] N. Iqbal, S. Sagar, M.B. Khan, Comprehensive ablation characteristics of ceramic fibers impregnated rubber composites, Intern. J. Eng. Technol., 6 (2014) 162-167.

DOI: 10.7763/ijet.2014.v6.688

Google Scholar

[10] S.S. Iqbal, N. Iqbal, T. Jamil, A. Bashir, Z.M. Khan, Tailoring in thermomechanical properties of ethylene propylene diene monomer elastomer with silane functionalized multiwalled carbon nanotubes, J. Appl. Poly. Sci., 26 (2015) 232-239.

DOI: 10.1002/app.43221

Google Scholar

[11] S. Sagar, N. Iqbal, A. Maqsood, Multiwalled carbon nanotubes impregnated rubber nanocomposites: thermal transport/decomposition and differential scanning calorimetric study, J. Reinfor. Plast. Compo., 32 (2013) 1052-1061.

DOI: 10.1177/0731684413484184

Google Scholar

[12] N. Iqbal, S. Sagar, M.B. Khan, H.M. Rafique, Elastomeric ablative nanocomposites used in hyperthermal environments, Poly. Eng. Sci., 54 (2013) 255-263.

DOI: 10.1002/pen.23573

Google Scholar

[13] F. Jamshaid, A. Ahmad, M. Adrees, S.S. Iqbal, H. Zaheer, T. Jamil, J. Ahmad, T. Hussain, Tuning the interlaminar shear strength and thermo-mechanical properties of glass fiber composites by incorporation of (3-mercaptopropyl) trimethoxysilane-functionalized carbon black, Iran. Poly. J., 11 (2017).

DOI: 10.1007/s13726-017-0576-3

Google Scholar