In Situ Reactive Interfacial Compatibilization of Poly(Ethylene Terephthalate)/Metallocene Polyethylene Blends

Article Preview

Abstract:

Poly (ethylene terephthalate) (PET) was melt blended with metallocene polyethylene (m-PE) with an effort to achieve excellent mechanical properties, a terpolymer elastomer, ethylene-methyl acrylate-glycidyl methacrylate (E-MA-GMA), was loaded as compatibilizer through in situ reacting with the end groups of PET to bond two immiscible phases. In order to investigate the in situ effects of the compatibilizer, scanning electron microscopy (SEM) and mechanical analysis was applied to investigate PET/m-PE blends’ properties along with the variation of compatibilizer content. Statistics of particle size were applied to demonstrate the variation of the blends’ properties along with morphology. The results revealed that an appropriate loading of compatibilizer can obtain stiffness-toughness balanced blends.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

12-17

Citation:

Online since:

October 2018

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2018 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] H. S. Zhang, W. H. Guo, Y. B. Yu, B. Y. Li, C. F. Wu, Structure and properties of compatibilized recycled poly (ethylene terephthalate)/linear low-density polyethylene blends, European Polym. J. 43 (2007) 3662-3670.

DOI: 10.1016/j.eurpolymj.2007.05.001

Google Scholar

[2] H. S. Zhang, Y. Zhang, W. H. Guo, D.D. Xu, C.F. Wu, Thermal properties and morphology of recycled poly(ethylene terephthalate)/maleic anhydride grafted linear low-density polyethylene blends, J. Appl. Polym. Sci. 109 (2008) 3546-3553.

DOI: 10.1002/app.28456

Google Scholar

[3] M. Pracella, D. Chionna, R. Ishak, A. Galeski, Recycling of PET and Polyolefin Based Packaging Materials by Reactive Blending, Polym. Plast. Tech. Eng. 43 (2004) 1711-1722.

DOI: 10.1081/ppt-200040075

Google Scholar

[4] Y. Zhang, H.S. Zhang, Y.B. Yu, W.H. Guo, C.F. Wu, Recycled Poly(ethylene terephthalate)/ Linear Low-Density Polyethylene Blends Through Physical Processing, J. Appl. Polym. Sci. 114 (2009) 1187-1194.

DOI: 10.1002/app.30030

Google Scholar

[5] G.Z. Zhang, T. Wu, W.Y. Lin, Y.B. Tan, R.Y. Chen, Z.X. Huang, X.C. Yin, J.P. Qu, Preparation of polymer/clay nanocomposites via melt intercalation under continuous elongation flow, Compos. Sci. Technol. 145 (2017) 157-164.

DOI: 10.1016/j.compscitech.2017.04.005

Google Scholar

[6] Y. Zhang, W.H. Guo, H.S. Zhang, C.F. Wu, Influence of chain extension on the compatibilization and properties of recycled poly(ethylene terephthalate)/linear low-density polyethylene blends, Polym. Degrad. Stabil. 94(2009) 1135-1141.

DOI: 10.1016/j.polymdegradstab.2009.03.010

Google Scholar

[7] M. Xanthos, S.S. Dagli, Compatibilization of polymer blends by reactive processing, Polym. Eng. Sci. 31(1991) 929-935.

DOI: 10.1002/pen.760311302

Google Scholar

[8] K. Jayanarayanan, A. Ravichandran, D. Rajendran, M. Sivathanupillai, A. Venkatesan, S. Thomas, K. Joseph, Morphology and Mechanical Properties of Normal Blends and In-Situ Microfibrillar Composites from Low-Density Polyethylene and Poly(ethylene terephthalate), Polym-Plast. Technol. 49 (2010).

DOI: 10.1080/03602550903414043

Google Scholar

[9] J. Scheirs, W. Kaminsky, Metallocene-Based polyolefins, Wiley, New York. (2000).

Google Scholar

[10] M. Y. Hao, H. W. Wu, Z. H. Zhu, In situ reactive interfacial compatibilization of polylactide/sisal fiber biocomposites via melt-blending with an epoxy-functionalized terpolymer elastomer, Res. Adv. 7 (2017) 32399-32412.

DOI: 10.1039/c7ra03513f

Google Scholar