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HomeKey Engineering MaterialsKey Engineering Materials Vol. 790Synthesis and Ionic Conductivity of MAlSi3O8 (M =...

Synthesis and Ionic Conductivity of MAlSi₃O₈(M = Li, Na, K)

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Abstract:

MAlSi₃O₈ (M = Li, Na, K) was synthesized by solid-phase reaction at 1000 °C using M₂CO₃ (M = Li, Na, K), Al₂O₃, and SiO₂ as the starting materials, and its ionic conduction was studied in the temperature range 475–800 K. It was confirmed from powder X-ray diffraction profiles that the crystalline phases of the prepared MAlSi₃O₈ were the same as those of orthoclase. Moreover, the ionic conductivity of NaAlSi₃O₈ was about 10 times higher than that of LiAlSi₃O₈ and KAlSi₃O₈. The activation energies for ionic conduction were estimated to be in the range of 0.70–0.77 eV, with NaAlSi₃O₈ exhibiting the lowest activation energy. The result suggests that the magnitude of the activation energy cannot be determined only from the ionic radius.

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Advanced Micro-Device Engineering VIII

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Periodical:

Key Engineering Materials (Volume 790)

Pages:

9-14

DOI:

https://doi.org/10.4028/www.scientific.net/KEM.790.9

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Online since:

November 2018

Authors:

Shin Ichi Furusawa, Yohei Minami

Keywords:

Ionic Conductivity, Lithium Aluminium Silicate, Potassium Aluminium Silicate, Sodium Aluminium Silicate

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© 2018 Trans Tech Publications Ltd. All Rights Reserved

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[1] P. Knauth, Inorganic solid Li ion conductors: An overview, Solid State Ionics 180 (2009) 911–916.

DOI: 10.1016/j.ssi.2009.03.022

[2] J. W. Fergus, Ceramic and polymeric solid electrolytes for lithium-ion batteries, J. Power Sources 195 (2010) 4554–4569.

DOI: 10.1016/j.jpowsour.2010.01.076

[3] J. W. Fergus, Ion transport in sodium ion conducting solid electrolytes, Solid State Ionics 227 (2012) 102-112.

DOI: 10.1016/j.ssi.2012.09.019

[4] B. L. Ellis and L. F. Nazar, Sodium and sodium-ion energy storage batteries, Curr. Opin. Solid State Mater. Sci. 16 (2012) 168–177.

DOI: 10.1016/j.cossms.2012.04.002

[5] M. Marcinek, J. Syzdek, M. Marczewski, M. Piszcz, L. Niedzicki, M. Kalita, A. Plewa-Marczewska, A. Bitner, P. Wieczorek, T. Trzeciak, M. Kasprzyk, P.Łężak, Z. Zukowska, A. Zalewska, W. Wieczorek, Electrolytes for Li-ion transport – Review, Solid State Ionics 276 (2015).

DOI: 10.1016/j.ssi.2015.02.006

[6] E. I. Burmakin and G. Sh. Shekhtman, Potassium-conducting solid electrolytes in the K3− 2xCdxPO4 system, Russ. J. Electrochem. 50 (2014) 496-499.

DOI: 10.1134/s1023193514050036

[7] A. Eftekhari, Potassium secondary cell based on Prussian blue cathode, J. Power Sources 126 (2004) 221–228.

DOI: 10.1016/j.jpowsour.2003.08.007

[8] Luo W, Wan J, Ozdemir, Bao W, Chen Y, Dai J, Lin H, Xu Y, Gu F, Barone V, Hu L, Potassium Ion Batteries with Graphitic Materials, Nano Lett. 15 (2015) 7671−7677.

DOI: 10.1021/acs.nanolett.5b03667

[9] S. Furusawa and Y. Minami, Synthesis and Ionic Conductivity of KAlSi3O8, Key Eng. Mater. 698 (2016) 8-12.

[10] D. Stroud, The effective medium approximations: Some recent developments, Superlattices and Microstructures, 23 (1998) 567-573.

DOI: 10.1006/spmi.1997.0524

[11] D. B. McWhan, S. J. Allen, Jr., J. P. Remeika, and P. D. Dernier, Ion-Ion Correlations and Diffusion in β-Alumina, Phys. Rev. Lett. 35 (1975) 953-956.

DOI: 10.1103/physrevlett.35.953

[12] J.C. Wang, M. Gaffari, and Sang-il Choi, On the ionic conduction in β-alumina: Potential energy curves and conduction mechanism, J. Chem. Phys. 63 (1975) 772-778.

DOI: 10.1063/1.431356

[13] P. Padma Kumar and S. Yashonath, Ionic conduction in the solid state, J. Chem. Sci. 118 (2006) 135–154.

[14] K. Funke, B. Roling, and M. Lange, Dynamics of mobile ions in crystals, glasses and melts, Solid State Ionics 105 (1998) 195–208.

DOI: 10.1016/s0167-2738(97)00465-7

[15] B. Roling, A. Happe, K. Funke, and M. D. Ingram, Carrier Concentrations and Relaxation Spectroscopy: New Information from Scaling Properties of Conductivity Spectra in Ionically Conducting Glasses, Phys. Rev. Lett. 78 (1997) 2160-2163.

DOI: 10.1103/physrevlett.78.2160

[16] B. Roling, Scaling properties of the conductivity spectra of glasses and supercooled melts, Solid State Ionics 105 (1998) 185-193.

DOI: 10.1016/s0167-2738(97)00463-3

[17] R. Belin, R Belin, G Taillades, A Pradel, M Ribes, Ion dynamics in superionic chalcogenide glasses: Complete conductivity spectra, Solid State Ionics 136-137 (2000) 1025-1029.

DOI: 10.1016/s0167-2738(00)00556-7