Effects of Curing Temperature and Pressure on the Mechanical Properties of Gasket Material Used for Polymer Electrolyte Membrane Fuel Cells

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The long-term mechanical stability of the gasket material is critical to sealing and electrochemical performance of the polymer electrolyte membrane (PEM) fuel cells. In this paper, the silicone rubber material, which is being considered as gasket material for PEM fuel cells, was fabricated at different curing temperatures and different curing pressures. Effects of the curing temperatures and curing pressures on the mechanical properties of the silicone rubber material were investigated. The tensile test results show that tensile strength of the specimen cured at the curing temperature of 160 was larger than that for the specimens cured at the curing temperature of 150 or 170 under the same curing pressure. The test results of the compression stress-strain, compression set and compression stress relaxation show that the curing temperature and curing pressure affected significantly the compression elastic modulus, compression set rate and compression stress relaxation behavior. It is found that the silicone rubber material cured at the curing temperature of 160 under the curing pressure of 10MPa had good compression mechanical properties compared to the materials cured at the other curing temperatures and curing pressure in this work.

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93-101

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March 2019

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© 2019 Trans Tech Publications Ltd. All Rights Reserved

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[1] J.Z. Tan, Y.J. Chao, M. Yang, C.T. Williams, J.W.V. Zee, Degradation characteristics of elastomeric gasket materials in a simulated PEM fuel cell environment. Journal of Materials Engineering and Performance, 17(6), (2008) 785-792.

DOI: 10.1007/s11665-008-9233-5

Google Scholar

[2] S. Pehlivan-Davis, J. Clarke, S. Armour, Comparison of accelerated aging of silicone rubber gasket material with aging in a fuel cell environment. Journal of Applied Polymer Science, 129(3), (2013) 1446-1454.

DOI: 10.1002/app.38837

Google Scholar

[3] F.H. Yan, X.B. Zhang, F. Liu, X.H. Li, Z.J. Zhang, Adjusting the properties of silicone rubber lled with nanosilica by changing the surface organic groups of nano-silica, Composites Part B: Engineering, 75, (2015) 47-52.

DOI: 10.1016/j.compositesb.2015.01.030

Google Scholar

[4] N. Iqbal, M.B. Khan, S. Sagar, A. Maqsood, Fabrication and Characterization of Multiwalled Carbon Nanotubes / Silicone Rubber Composites, Journal of Applied Polymer Science, 128(4), (2013) 2439-2446.

DOI: 10.1002/app.38410

Google Scholar

[5] B.J. Zhou, J.S. Zhang, Q.J. Wang, Q.M. Chen, Improvement in Compression Performance of the Polysulfide Sealant by Thiol-Acrylate Reaction. Polymer Engineering & Science, 52(4), (2012) 912-919.

DOI: 10.1002/pen.22158

Google Scholar

[6] J.P. Song, L.X. Ma, Y. He, H.Q. Yan, Z. Wu, W. Li, Modified graphite filled natural rubber composites with good thermal conductivity, Chinese Journal of Chemical Engineering, 23(5), (2015) 853-859.

DOI: 10.1016/j.cjche.2014.05.022

Google Scholar

[7] H. Zhao, Y.J. Xia, Z.M. Dang, J.W. Zha, G.H Hu, Composition Dependence of Dielectric Properties, Elastic Modulus, and Electroactivity in (Carbon Black-BaTiO3)/Silicone Rubber Nanocomposites. Journal of Applied Polymer Science, 127(6), (2013) 4440-4445.

DOI: 10.1002/app.38044

Google Scholar

[8] J.L Leblanc, Effect of Temperature on Dynamic Rheological Properties of Uncured Rubber Materials in Both the Linear and the Nonlinear Viscoelastic Domains. Journal of Applied Polymer Science, 126(2), (2012) 408-422.

DOI: 10.1002/app.37006

Google Scholar

[9] S.M. Javadi, M. Moghiman, M.R. Erfanian, N. Hosseini, Numerical Investigation of Curing Process in Reaction Injection Molding of Rubber for Quality Improvements. Key Engineering Materials, 462(10), (2011) 1282-1292.

DOI: 10.4028/www.scientific.net/kem.462-463.1206

Google Scholar

[10] E.P. Cao, X.Q. Cui, K.Wang, Y.Y. Li, W.H. Guo, Improving properties of ceramic silicone rubber composites using high vinyl silicone oil. Journal of Applied Polymer Science, 132(19), (2015) 1-7.

DOI: 10.1002/app.41864

Google Scholar

[11] Y. Meng, J.F. Chu, C.H. Liu, Z. Wei, L.Q. Zhang, Oil Resistance and Mechanical Properties of Polysiloxane Nanocomposites Prepared by In Situ Reaction of Reactive Polar Monomers. Journal of Applied Polymer Science, 131(21), (2014) 8558-8572.

DOI: 10.1002/app.40983

Google Scholar

[12] L. Pan, J.Z. Tan, X.M. Han, P. Li, W.J. Zhang, Effects of elevated temperature and crude oil on the properties of a hydrogenated nitrile butadiene rubber elastomer, Journal of Applied Polymer Science, 133(40), 44012 (2016).

DOI: 10.1002/app.44012

Google Scholar

[13] T. Cui, Y.J. Chao, J.W.V. Zee, Stress relaxation behavior of EPDM seals in polymer electrolyte membrane fuel cell environment. International Journal of Hydrogen Energy, 37(18), (2012) 13478-13483.

DOI: 10.1016/j.ijhydene.2012.06.098

Google Scholar

[14] J.Z. Tan, Y.J. Chao, J.W.V. Zee, X.D. Li, X.N. Wang, M. Yang, Assessment of mechanical properties of fluoroelastomer and EPDM in a simulated PEM fuel cell environment by microindentation test. Materials Science and Engineering A, 496(1), (2008) 464-470.

DOI: 10.1016/j.msea.2008.05.052

Google Scholar