Improvement of Electrical Conductivity of Polyurethane/Polypyrrole Blends by Graphene

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Polyurethane (TPU)/polypyrrole (PPy) blends were successfully prepared by the solution blending process with different contents of reduce graphene oxide (rGO). The controlled synthesis of PPy/rGO composites was reported by varying graphene contents of 10, 20, 30 and 40% w/v. Fourier transform infrared (FTIR) and Scanning electron microscope (SEM) were used to characterize their structures and morphologies. The SEM images show the growing of PPy along the surface of graphene. FTIR illustrated that the PPy/rGO composites were in the doped state. The electrical conductivity of PPy/rGO composites with the concentration of graphene at 40% was about 30 times higher than that of pure PPy. Thermogravimetric analyzer (TGA) thermograms indicated that the PPy/rGO composites have better thermal stability than pure PPy.

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122-126

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February 2020

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© 2020 Trans Tech Publications Ltd. All Rights Reserved

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[1] J. Wang, L. Xiao, X. Du, J. Wang, H. Ma, Polypyrrole composites with carbon materials for supercapacitors, Chem. Pap. 71(2) (2017) 293-316.

DOI: 10.1007/s11696-016-0048-9

Google Scholar

[2] L. Dai, Intelligent macromolecules for smart devices from materials synthesis to device applications, Springer, 1(1) (2004) 43-46.

Google Scholar

[3] M. Kotal, S. K. Srivastava, B. Paramanik, Enhancements in conductivity and thermal stabilities of polyurethane/polypyrrole nanoblends, J. Phys. Chem. C, 115(5) (2011) 1496-1505.

DOI: 10.1021/jp1081643

Google Scholar

[4] S. Pei, H. M. Cheng, The reduction of graphene, Carbon, 50(9) (2012) 3210-3228.

Google Scholar

[5] M. J. Fernández-Merino, L. Guardia, J. I. Paredes, S. Villar-Rodil, P. Solís-Fernández, Vitamin C is an ideal substitute for hydrazine in the reduction of graphene oxide suspensions, J. Phys. Chem. C, 114(14) (2010) 6426-6432.

DOI: 10.1021/jp100603h

Google Scholar

[6] S. Bose, N. H. Kim, T. Kuila, K. T. Lau, J. H. Lee, Electrochemical performance of a graphene–polypyrrole nanocomposite as a supercapacitor electrode, Nanotechnol. 22(29) (2011) 295202.

DOI: 10.1088/0957-4484/22/29/295202

Google Scholar

[7] T. M. Wu, S. H. Lin, Synthesis characterization and electrical properties of polypyrrole/ multiwalled carbon nanotube composites, J. Polym. Sci., Part A: Polym. Chem. 44(21) (2006) 6449-6457.

DOI: 10.1002/pola.21724

Google Scholar

[8] L. Wang, F. Liu, C. Jin, T. Zhang, Q. Yin, Preparation of polypyrrole/graphene nanosheets composites with enhanced thermoelectric properties, RCS Adv. 4(86) (2014) 46187-46193.

DOI: 10.1039/c4ra07774a

Google Scholar

[9] R. N. Rothon, The use of fillers in polymers, Particulate filler of polymers, (2002) 21-23.

Google Scholar