Characteristics of Ni- Cr Binary Alloys Produced by Conventional Powder Metallurgy

Article Preview

Abstract:

The characteristics of Ni-Cr porous alloys containing 0.5 wt%Cr up to 12 wt%Cr were determined. The alloys were prepared from a mix of Ni-particles with filamentary shape and Cr-particles with irregular shape which then mixed with 0.5 wt% paraffin wax as a binder. The samples were formed by compaction and then sintered at 1200 °C for 1 h. The microstructure of samples was found to consist of a Ni-Cr solid solution matrix with X-ray energy dispersive analysis of Cr% less than 0.33 wt%. The matrix microstructure which composed of equiaxed grains (20-60 μm) surrounded high Cr content islands which also contained γ phase (Ni2.88 Cr1.22). The apparent density of the alloys was found to decrease with Cr content from 8.32 g/cm3 for samples containing 0.5 wt%Cr to 7.26 g/cm3 for samples containing 12 wt%Cr. Therefore, the estimated porosity was found to increase from 6.4% to 16.6% with increasing Cr content from 0.5 wt% to 12 wt%. The microhardness of the samples varied from 153.6 to 284.2 VHN for the equiaxed grains and from 119.6 to 240.6 VHN for the island areas.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

214-222

Citation:

Online since:

March 2020

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2020 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] V. Coman, B. Robotin, P. Ilea, Nickel recovery/removal from industrial wastes: A review, Resources, Conservation and Recycling, 73 (2013) 229-238.

DOI: 10.1016/j.resconrec.2013.01.019

Google Scholar

[2] X. Maoquan, High temperature oxidation and wear behavior of powder metallurgically developed Ni-Cr-W-Al-Ti-MoS2 composite" Indian J Eng Mater Sci, 16 (2009) 111-115.

Google Scholar

[3] L.Z. Mohamed, W.A. Ghanem, O.A. El Kady, M.M. Lotfy, H.A. Ahmed, F.A. Elrefaie, Oxidation characteristics of porous-nickel prepared by powder metallurgy and cast-nickel at 1273 K in air for total oxidation time of 100 h, J Adv. Res.(JAR), 8 (2017) 717–729.

DOI: 10.1016/j.jare.2017.08.004

Google Scholar

[4] L.Z. Mohamed, W.A. Ghanem, O.A. El Kady, M.M. Lotfy, H.A. Ahmed, F.A. Elrefaie, Oxidation characteristics of porous nickel low-chromium binary alloys in air at 1273K for 100 h, KEM, 786 (2018) 37-43.

DOI: 10.4028/www.scientific.net/kem.786.37

Google Scholar

[5] C.H. Zhou, R.Y. Pan, H. Zhang, X.G. Guan, Oxidation behavior of Ni-10Cr alloy under the compressive stress at 900 ℃, 3rd Asia-Pacific Electronics and Electrical Eng. Conf. (EEEC 2018), (2018).

DOI: 10.12783/dtetr/eeec2018/26886

Google Scholar

[6] L.Z. Mohamed, W.A. Ghanem, O.A. El Kady, M.M. Lotfy, H.A. Ahmed, F.A. Elrefaie, Oxidation characteristics of porous Ni-12 wt%Cr alloy at 1000 ℃ in air, Ain Shams Eng. J., 9 (2018) 2993–3000.

DOI: 10.1016/j.asej.2018.02.001

Google Scholar

[7] C. Quan, S. Deng, Y. Jiang, C. Jiang, M. Shuai, Characteristics and high temperature oxidation behavior of Ni-Cr-Y2O3 nanocomposite coating prepared by cathode plasma electrolytic deposition, J. Alloy Compd., 793 (2019) 170-178.

DOI: 10.1016/j.jallcom.2019.04.063

Google Scholar

[8] K. Narinder, K. Manoj, S.K. Sharmaa, D.Y. Kima, S. Kumarc, N.M. Chavanc, S.V. Joshic, S. Narinder, S. Harpreet, Study of mechanical properties and high temperature oxidation behavior of a novel cold-spray Ni-20Cr coating on boiler steels, Appl Surf Sci., 328 (2015) 13-25.

DOI: 10.1016/j.apsusc.2014.12.033

Google Scholar

[9] K. Ercan, K. Mustafa, Effect of microstructural evolution and elevated temperature on the mechanical properties of Ni–Cr–Mo alloys, J Alloy Compd., 619 (2015) 82–90.

DOI: 10.1016/j.jallcom.2014.09.036

Google Scholar

[10] T. Benoît, A. Catherine, N. Bernard, Electronic and transport properties of passive films grown on different Ni-Cr binary alloys in relation to the pitting susceptibility, Electrochim Acta, 133 (2014) 373-381.

DOI: 10.1016/j.electacta.2014.04.067

Google Scholar

[11] L. Chaman, S. Eric, High nickel alloys offering a combination of high strength and high impact properties, Powder Metall Conf. (2013).

Google Scholar

[12] B.J. Babalola, M.B. Shongwe, B.A. Obadele, P.A. Olubambi, Densification, microstructure and mechanical properties of spark plasma sintered Ni-17%Cr binary alloys, The Int. J Adv. Manufacturing Tech., 101 (2019) 1573–1581.

DOI: 10.1007/s00170-018-3062-y

Google Scholar

[13] E.H. Kottcamp, et.al, ASM handbook, 3 (1992) 692.

Google Scholar

[14] Y. Ustinovshikov, Phase transformations in alloys of the Ni–Cr system, J Alloy Compd, 543 (2012) 227–232.

DOI: 10.1016/j.jallcom.2012.05.120

Google Scholar

[15] P. Nash, The Cr-Ni (chromium-nickel) system, Bull Alloy Phase Diagr, 7(5) (1986) 455-476.

Google Scholar

[16] K.S. Chan, P. Yi-ming, L. Yi-der, Computation of Ni-Cr phase diagram via a combined first-principles quantum mechanical and CALPHAD approach, Metall Mater Trans A, 37A (2006) (2039).

DOI: 10.1007/bf02586124

Google Scholar

[17] P.W. Lee, et.al, ASM Handbook, 7 (1998) 915, 1052.

Google Scholar

[18] M.M. Mohammed, O.A. Elkady, A.W. Abdelhameed, Effect of alumina particles addition on physico-mechanical properties of AL-matrix composites, O J Metal, 3 (2013) 72-79.

DOI: 10.4236/ojmetal.2013.34011

Google Scholar

[19] J.C. Lippold, S.D. kiser, Welding metallurgy and weldability of nickel-base alloys, (2009) 420.

DOI: 10.1002/9780470500262

Google Scholar

[20] P. Bayliss, D.C. Erd, M.E. Mrose, A.P. Sabina, D.K. Smith, Mineral powder diffraction file- data book, (1986) 227,830.

Google Scholar

[21] H.E. Swanson, E. Tatge, Standard X-ray diffraction powder patterns, Natl. Bur. Stand. (US) Circ, 539(1) (1953) 13.

Google Scholar

[22] Swanson et al, Standard X-ray diffraction powder patterns, Natl. Bur. Stand. (US) Circ, (1955) 539- 20.

Google Scholar

[23] O. Bergman, Key aspects of sintering powder metallurgy steel prealloyed with chromium and manganese. PhD, Gothenburg, Sweden, (2011).

Google Scholar

[24] B.W. Roberts, R.A. Swalin, Concerning an order-disorder transition in the Ni-Cr system, Trans Am Inst Min Metall Pet Eng, 209 (1957) 209- 845.

DOI: 10.1007/bf03397927

Google Scholar

[25] R.W. Heckel, M. Balasubramaniam, The effects of heat treatment and deformation on the homogenization of compacts of blended powders, Metall Trans, 2 (1971) 379-391.

DOI: 10.1007/bf02663325

Google Scholar

[26] C. Tien-Fu, G.P. Tiwari, I. Yoshiaki, Y. Kiyoshi, Volume and grain boundary diffusion of chromium in Ni-base Ni–Cr–Fe alloys, Mater Trans, 44(1) (2003) 40-46.

DOI: 10.2320/matertrans.44.40

Google Scholar

[27] W. Qiong, L. Shu-Suo, M. Yue, G. Sheng-Kai, First principles calculations of alloying element diffusion coefficients in Ni using the five-frequency model, Chin Phys B, 21(10) (2012) (109102-1) -(109102-7).

DOI: 10.1088/1674-1056/21/10/109102

Google Scholar

[28] G.F. Vander. et.al, ASM handbook, 9 (2004)1987-1991.

Google Scholar

[29] C.S. Pande, B.B. Rath, M.A. Imam, Effect of annealing twins on Hall-Petch relation in polycrystalline materials, Mater Sci Eng A, 367 (2004) 171-175.

DOI: 10.1016/j.msea.2003.09.100

Google Scholar

[30] F.J. Humphreys, M. Hatherly, Recrystallization and related annealing phenomena. Second Ed, (2004) 292-313.

Google Scholar