Synthesis, Single Crystal X-Ray Structure, Hirshfeld Surface Analysis of a New Isopolymolybdate Based Supramolecular Hybrid

Abstract:

Design and synthesis of supramolecular hybrids with low dimensionality is currently an attractive research topic. The reaction of Schiff base metal complex with isopolymolybdate leads to the isolation of a new isopolymolybdate based supramolecular hybrid, [Mn(salen)(H₂O)₂]₂[Mo₈O₂₆]Na₂·2H₂O (1) (salen = N,N'-bis(salicylidene)ethylenediamine). The supramolecular hybrid was characterized by single crystal X-ray structure analyses, elemental analyses and X-ray crystallography. Crystal data for 1: triclinic, P-1, a=10.0206(8)Å, b = 11.7416(10)Å, c= 13.1494(13)Å, V = 1382.8(2)ų, Z= 1, R_gt(F) = 0.0353 and wR_ref(F²) = 0.1009. Structural analyses reveal that 1 represents the first example of [Mo₈O₂₆]^4- chains formed POM-Schiff-base hybrid. Hirshfeld surface analysis and fingerprint plots are used for decoding intermolecular interactions in 1. Additionally, magnetic property of 1 indicates that there is an antiferromagnetic coupling between the metal centers in the complex.

• Periodical: Key Engineering Materials (Volume 842)
• Pages: 223-230
• DOI: https://doi.org/10.4028/www.scientific.net/KEM.842.223
• Online since: May 2020
• Authors: Jian Chang Xiao, Jun Li, Jin Rong Sun, Yan Xu, Fang Jiang, Yuan Lei, Tian Yu Li, Xin Di Xu, Mei Fen Huang, Qiong Wu*
• Keywords: Hirshfeld Surface Analysis, Inorganic Chain, Magnetic Behaviour, Schiff Base

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