Electrical Characterization of N- and B- Doped Amorphous Carbon Film from Palmyra Sugar

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Structure of amorphous carbon can be composed of sp2 (graphite), or sp3 (diamond), or a combination of both, depending on their fractions. Therefore, many researchers were exploring to use it as solar cell material. This research used the amorphous carbon of bio-product as a basic material in the form of palmyra sugar which was synthesized through the heating and doping process to produce n-type and p-type semiconductors. This research aims to analyze the effect of dopant and deposition time on electrical properties. The heating process was carried out at 250°C and the doping process was carried out by adding NH4OH for a-C:N and H3BO3 for a-C:B. The deposition process was carried out by the nano-spray method using a variety of deposition time on the ITO substrate. The result of scanning electron microscopy (SEM) showed that the film thickness increased with the increase of deposition time. Besides, the result of four-point probe (FPP) showed that the dopant can increase electrical conductivity, but the film thickness did not influence it. The electrical conductivity obtained was 5x10-1 - 6x10-1 S/cm. And the result of further analysis, it can be concluded that electrical conductivity was still in the range of semiconducting material.

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196-201

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August 2020

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© 2020 Trans Tech Publications Ltd. All Rights Reserved

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[1] Mukarromah, D.I. Pamungkas, Darminto, Structural characterization of amorphous carbon films from palmyra cap, Proc. Int. Conf. Biol. Appl. Sci. (ICOBAS), Malang, Indonesia, (2019).

DOI: 10.1063/1.5115687

Google Scholar

[2] F. Risplendi, B. Marco, C. Giancarlo, C.G. Jeffrey, Structure-property relations in amorphous carbon for photovoltaics, App. Phys. Lett. 105 (2014) 043903.

DOI: 10.1063/1.4891498

Google Scholar

[3] R.J. Yeo, Ultrathin Carbon-Based Overcoats for Extremely High-Density Magnetic Recording, First ed., Springer, Berlin, (2017).

DOI: 10.1007/978-981-10-4882-1

Google Scholar

[4] J. Robertson, Diamond-like amorphous carbon, Mater. Sci. Eng. R Rep. 37 (2002) 129-281.

Google Scholar

[5] D.I. Pamungkas, A. Haikal, M.A. Baqiya, Y. Cahyono, Darminto, Synthesis of amorphous carbon from bio-products by drying method, Proc. 3rd Int. Conf. Mater. Metall. Eng. Technol. (ICOMMET 2017), Surabaya, Indonesia, (2018).

DOI: 10.1063/1.5030281

Google Scholar

[6] P.V.K.J. Rao, M. Das, S.K. Das, Changes in physical and thermo-physical properties of sugarcane, palmyra-palm, and date-palm juices at different concentration of sugar, J. Food Eng 90 (2009) 559-566.

DOI: 10.1016/j.jfoodeng.2008.07.024

Google Scholar

[7] S.M. Sze, Semiconductor Devices, Physics and Technology, 2nd ed., John Wiley & Sons Inc., USA, (2002).

Google Scholar

[8] H. Zhu, J. Wei, K. Wang, D. Wu, Applications of carbon materials in photovoltaic solar cells, Sol. Energy Mater. Sol. Cells 93 (2009) 1461-1470.

DOI: 10.1016/j.solmat.2009.04.006

Google Scholar

[9] M. Ishak, M. Rusop, Electrical properties of nitrogen-doped amorphous carbon films fromethanol precursor, Int. J. Sci. Technol. Res. 3 (2014) 12-15.

Google Scholar

[10] R. Zhu, Q. Tao, M. Lian, X. Feng, J. Liu, M. Ye, X. Wang, S. Dong, T. Cui, P. Zhu, Modulating band gap of boron doping in amorphous carbon nano-film, Materials 12 (2019) 1780.

DOI: 10.3390/ma12111780

Google Scholar

[11] R. Rajan, A.B. Pandit, Correlations to predict droplet size in ultrasonic atomization, Ultrasonics 39 (2001) 235–255.

DOI: 10.1016/s0041-624x(01)00054-3

Google Scholar