Morphology of Micro-Porous Membrane of Waste Cigarette Butts Using Phase Inversion Method

Article Preview

Abstract:

The separation technique in industrial processes with membrane technology is very important. Ultrafiltration membrane is one type of membrane using the principle of pressure-push force. One of the most commonly used ultrafiltration membrane materials is cellulose acetate (CA) membrane. The advantage of CA as a membrane material is that easily produced and its raw material which is a renewable source. The aim of this work is to present a simple experimental and simulation studies to illustrate the phase separation in the membrane synthesis process by the phase inversion technique. Simulation is used to determine the surface characteristics of the synthesized membrane. Two systems commonly used for the preparation of membrane synthesis are waste cigarette butts (WCB)/acetone/water. The effect of adding WCB concentrations (1 and 2 pieces) to the initial polymer casting solution was studied through simulation and compared with available experimental data. The experimental results are in accordance with the simulation was carried out. It shows that the surface profile of the membrane with the composition of the polymer film during precipitation can provide important information about the structure and substructure of the membrane formed. This also shows that the influence of CA concentration is closely related to changes in pore size on the membranes that are formed. The asymmetrical membrane structure prepared by the phase inversion process is influenced by the type and concentration of the polymer (WCB), solvent, membrane thickness and temperature and processing time.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

310-314

Citation:

Online since:

August 2020

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2020 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] W. Liu, M. Cui, Y. Shen, G. Zhu, L. Luo, L. M. Li, J. Li, Waste cigarette filter as nanofibrous membranes for on-demand immiscible oil/water mixtures and emulsions separation, J. Colloid Interface Sci. 549 (2019) 114–122.

DOI: 10.1016/j.jcis.2019.04.057

Google Scholar

[2] W. Lu, Z. Yuan, Y. Zhao, H. Zhang, H. Zhang, X. Li, Porous membranes in secondary battery technologies, Chem. Soc. Rev. 46 (2017) 2199–2236.

DOI: 10.1039/c6cs00823b

Google Scholar

[3] X. Wang, X. Ba, N. Cui, Z. Ma, L. Wang, Z. Wang, X. Gao, Preparation, characterisation, and desalination performance study of cellulose acetate membranes with MIL-53(Fe) additive, J. Memb. Sci. 590 (2019) 117057.

DOI: 10.1016/j.memsci.2019.04.061

Google Scholar

[4] M. Mulder, Basic Principles Of Membrane Technology, second ed. : Free Download, Borrow, and Streaming : Internet Archive. (1996).

Google Scholar

[5] A. F. Ismail, T. Matsuura, Progress in transport theory and characterization method of Reverse Osmosis (RO) membrane in past fifty years, Desalination 434 (2018) 2–11.

DOI: 10.1016/j.desal.2017.09.028

Google Scholar

[6] Y.K. Tsui, S. Gogolewski, Microporous biodegradable polyurethane membranes for tissue engineering, J. Mater. Sci. Mater. Med. 20 (2009) 1729–1741.

DOI: 10.1007/s10856-009-3722-4

Google Scholar

[7] M.R. Esfahani, S.A. Aktij, Z. Dabaghian, M.D. Firouzjaei, A.Rahimpour, J. Ecke, I. C. Escobar, M. Abolhassani, L. F. Greenlee, A.R. Esfahani, A. Sadmani, N. Koutahzadeh, Nanocomposite membranes for water separation and purification: Fabrication, modification, and applications, Sep. Purif. Technol. 213 (2019) 465–499.

DOI: 10.1016/j.seppur.2018.12.050

Google Scholar

[8] H. Abdallah, M.S. Shalaby, M.A. Saad, A.M. Shaban, Supporting polyvinylchloride polymeric blend membrane with coated woven fabric, J. Membr. Sci. Res. 4 (2018) 174–180.

Google Scholar

[9] S.-S. Shen, H. Chen, R. hua Wang, W. Ji, Y. Zhang, R. Bai, Preparation of antifouling cellulose acetate membranes with good hydrophilic and oleophobic surface properties, Mater. Lett. 252 (2019) 1–4.

DOI: 10.1016/j.matlet.2019.03.089

Google Scholar

[10] G. Arthanareeswaran, P. Thanikaivelan, K. Srinivasn, D. Mohan, M. Rajendran, Synthesis, characterization and thermal studies on cellulose acetate membranes with additive, Eur. Polym. J. 40 (2004) 2153-2159.

DOI: 10.1016/j.eurpolymj.2004.04.024

Google Scholar

[11] G.-D Kang, Y.-M. Cao, Application and modification of poly(vinylidene fluoride) (PVDF) membranes - A review, J. Memb. Sci. 463 (2014) 145–165.

DOI: 10.1016/j.memsci.2014.03.055

Google Scholar

[12] H.J. Tanudjaja, C.A. Hejase, V.V. Tarabara, A.G. Fane, J.W. Chew, Membrane-based separation for oily wastewater: A practical perspective, Water Res.156 (2019) 347–365.

DOI: 10.1016/j.watres.2019.03.021

Google Scholar

[13] M. Sivakumar, D.R. Mohan, R. Rangarajan, Studies on cellulose acetate-polysulfone ultrafiltration membranes: II. Effect of additive concentration, J. Memb. Sci. 268 (2006) 2018-219.

DOI: 10.1016/j.memsci.2005.06.017

Google Scholar

[14] B. Han, D. Zhang, Z. Shao, L. Kong, S. Lv, Preparation and characterization of cellulose acetate/carboxymethyl cellulose acetate blend ultrafiltration membranes, Desalination 311 (2013) 80-89.

DOI: 10.1016/j.desal.2012.11.002

Google Scholar

[15] X. Shan, H. Chen, Lattice Boltzmann model for simulating flows with multi phases and components, Phys. Rev. E 47 (1993) 1815–1819.

DOI: 10.1103/physreve.47.1815

Google Scholar

[16] F. Bai, X. He, X. Yang, R. Zhou, C. Wang, Three dimensional phase-field investigation of droplet formation in microfluidic flow focusing devices with experimental validation, Int. J. Multiph. Flow 93 (2017) 130–141.

DOI: 10.1016/j.ijmultiphaseflow.2017.04.008

Google Scholar