Graphite Foil Waste to Graphene: New Carbon Precursors for Synthesis of Graphene and its Oxides

Article Preview

Abstract:

In this paper, graphene oxide (GO) was obtained by oxidation of powdered graphite foil wastes (pGFW) at 0 - 40°C. Oxidizing reagents can easily penetrate the layers of graphite foil and thus, the intercalation or functionalization-oxidation processes may occur resulting in graphite oxide formation. The methods of synthesis of GO and its separation from the reaction mixture were partially corrected. GO was reduced, also, to the reduced graphene oxide (rGO) by using hydroiodic acid, ascorbic acid, zinc powder, hydrazine, and Alnus extract. Thermal treatment of GO powders and GO films, obtained from pGFW was implemented at 20-300° C in air and at 20-1000° C under argon flow and in a vacuum. At high-temperature treatment (1000°C) of GO graphene was obtained with a defective structure.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

68-74

Citation:

Online since:

July 2021

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2021 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] A.K. Geim, K.S. Novoselov: The Rise of Graphene, Nature Materials, 2007, vol.6, pp.183-191.

Google Scholar

[2] W.S. Hummers, R.E. Offeman: Preparation of Graphitic Oxide, Journal of the American Chemical Society, 1958, 80, p.1339.

DOI: 10.1021/ja01539a017

Google Scholar

[3] D.C. Marcano, D.V. Kosynkin, J.M. Berlin, A. Sinitskii, Z. Sun, A. Slesarev, L.B. Alemany, W. Lu, J.M. Tour: Improved Synthesis of Graphene Oxide. ACS Nano, 2010, 4, pp.4806-4814.

DOI: 10.1021/nn1006368

Google Scholar

[4] M.P. Lavin-Lopez, M. Valverde Palomino, L. Sanchez-Silva, A. Romero Izquierdo: Recent Advances in Graphene Research. INTECH, 2016, pp.122-133.

Google Scholar

[5] L. Sun, B. Fugetsu: Mass Production of Graphene Oxide from Expanded Graphite. Materials Letters, 2013¬, 109, pp.207-210.

DOI: 10.1016/j.matlet.2013.07.072

Google Scholar

[6] N.I. Kovtyukhova, P.J. Ollivier, B.R. Martin, T.E. Mallouk, S.A. Chizhik, E.V. Buzaneva, A.D. Gorchinskiy: Layer-by-layer Assembly of Ultrathin Composite Films from Micron-sized Graphite Oxide Sheets and Polycations. Chemistry of Materials, 1999, 11, pp.771-778.

DOI: 10.1021/cm981085u

Google Scholar

[7] X. Hu, Y. Yu; J. Zhou, L. Song: Effect of Graphite Precursor on Oxidation Degree, Hydrophilicity and Microstructure of Graphene Oxide. Nano, 2014, 9(3), 1450037, pp.1-8.

DOI: 10.1142/s1793292014500374

Google Scholar

[8] A. Ambrosi, Ch.K. Chua, B. Khezri, Z. Sofer, R.D. Webster, M. Pumera: Chemically ReducedGgraphene Contains Inherent Metallic Impurities Present in Parent Natural and Synthetic Graphite, Proceedings of the National Academy of Sciences of the United States of America, 2012, 109 (32), pp.12899-12904.

DOI: 10.1073/pnas.1205388109

Google Scholar

[9] H. Yang, H. Li, J. Zhai, L. Sun, H. Yu: Simple Synthesis of Graphene Oxide Using Ultrasonic Cleaner from Expanded Graphite. Industrial & Engineering Chemistry Research, 2014, 53(46), pp.17878-17883.

DOI: 10.1021/ie503586v

Google Scholar

[10] A. Abbas, L.T. Mariana, A.N. Phan: Biomass-waste Derived Graphene Quantum Dots and their Applications, Carbon, 2018, 140, pp.77-99.

DOI: 10.1016/j.carbon.2018.08.016

Google Scholar

[11] G. Supriyanto, N.K. Rukman, A.K. Nisa, M. Jannatin, B. Piere, A. Abdullah, M.Z Fahmi, H.S Kusuma: Graphene Oxide from Indonesian Biomass: Synthesis and Characterization, BioResources, 2018, 13 (3), 4832-4840.

DOI: 10.15376/biores.13.3.4832-4840

Google Scholar

[12] N.G. Barbakadze, V.G. Tsitsishvili, T.V. Korkia, Z.G. Amiridze, N.V. Jalabadze, R.V. Chedia: Synthesis of Graphene Oxide and Reduced Graphene Oxide from Industrial Graphite Foil Wastes, European Chemical Bulletin, 2018, 7, pp.329-333.

DOI: 10.17628/ecb.2018.7.329-333

Google Scholar

[13] Information on: www.mersen.com; http://www.toyotanso.com/index.html; http://www.geegraphite.com; /https://www.canadacarbon.com/; https://sealwiz.com/.

DOI: 10.1089/glre.2016.201011

Google Scholar

[14] X. Chen, D. Meng, B. Wang, B.W. Li, C.W. Bielawski, R.S. Ruoff: Rapid Thermal Decomposition of Confined Graphene Oxide Films in Air. Carbon, 2016, 101, pp.71-76.

DOI: 10.1016/j.carbon.2016.01.075

Google Scholar

[15] H.B. Zhang, J.W. Wang, Q. Yan, W.G. Zheng, C. Chen, Z.Z. Yu: Vacuum-assisted Synthesis of Graphene from Thermal Exfoliation and Reduction of Graphite Oxide, Journal of Materials Chemistry, 2011, 21(14), pp.5392-5397.

DOI: 10.1039/c1jm10099h

Google Scholar

[16] W. Lu, D.M. Tang, Y.B. He, C.H. You, Z.Q. Shi, X.C. Chen: Low-temperature Exfoliated Graphenes: Vacuum-promoted Exfoliation and Electrochemical Energy Storage, ACS Nano, 2009, 3(11), pp.3730-3736.

DOI: 10.1021/nn900933u

Google Scholar

[17] L.X. Jiat, H. Billie, Y. Zhang, L.K. Chiew, L.L Yee, S.G. Suyin, J. Thangalazhy-Gopakumar, S. Rigby: Review on Graphene and its Derivatives: Synthesis Methods and Potential Industrial Implementation. Journal of the Taiwan Institute of Chemical Engineers 2019, 98, pp.163-180.

DOI: 10.1016/j.jtice.2018.10.028

Google Scholar