Latest Research and Developing Tendency of Hyperbranched Polymers Fabrication

Abstract:

Hyperbranched polymers (HBPs) have been applied in various fields because of its outstanding biodegradability and biocompatibility. At present, there are a variety of methods that are used to fabricate HBPs, such as polycondensation, reactive polymerization and ring-opening polymerization according to reaction mechanism. These methods are all environmental-friendly and high-efficient to generate HBPs, and are valuable for industrialization. In this work, we conclude some common methods of HBPs fabrication and make the comparison between them to analyze their advantages and disadvantages, which contribute in how to improve the synthesis process in the future research.

• Periodical: Key Engineering Materials (Volume 896)
• Pages: 45-50
• DOI: https://doi.org/10.4028/www.scientific.net/KEM.896.45
• Online since: August 2021
• Authors: Lian Yi Huo, Xue Tao Shi*, Si Ming Chen, Meng Yao Zhang
• Keywords: Applications, Developing Trendency, Hyperbranched Polylactic Acid, Hyperbranched Polymers, Synthesis Methods

References

[1] Chen S. Structural design, mechanism and application of hyperbranched polymers[D]: University of Science and Technology of China (In Chinese with English abstract); (2016).

[2] Flory PJ. Molecular Size Distribution in Three Dimensional Polymers. VI. Branched Polymers Containing A—R—Bf-1 Type Units. Journal of the American Chemical Society. 1952;74(11).

DOI: 10.1021/ja01131a008

[3] Kim YH, Webster OW. Hyperbranched polyphenylenes. Macromolecules. 1992;25(21):5561-72.

DOI: 10.1021/ma00047a001

[4] Martinez-Garcia M, Kormpa A, van der Maarel MJEC. The glycogen of Galdieria sulphuraria as alternative to starch for the production of slowly digestible and resistant glucose polymers. Carbohydrate Polymers. 2017;169:75-82.

DOI: 10.1016/j.carbpol.2017.04.004

[5] Lee SB, Ha DI, Cho SK, Kim SJ, Lee YM. Temperature/pH‐sensitive comb‐type graft hydrogels composed of chitosan and poly(N‐isopropylacrylamide). Journal of Applied Polymer Science. 2010;92(4):2612-20.

DOI: 10.1002/app.20265

[6] Xing A, Sun Q, Meng Y, Zhang Y, Han B. A hydroxyl-containing hyperbranched polymer as a multi-purpose modifier for a dental epoxy. Reactive and Functional Polymers. 2020;149:104505-.

DOI: 10.1016/j.reactfunctpolym.2020.104505

[7] Li W. Expression and identification of recombinant adenovirus mediated macaca mulatta PD-L1Ig and CD40L extracellular region gene in mulatta immature dendritic cells: Kunming Medical University; (2015).

[8] Xu T. Fabrication of 3D-printed PLGA hybrid scaffolds for tissue engineering: East China University of Science and Technology; (2015).

[9] Asif A, Huang C, Shi W. Structure–property study of waterborne, polyurethane acrylate dispersions based on hyperbranched aliphatic polyester for UV-curable coatings. Colloid and Polymer Science. 2004;283(2):200-8.

DOI: 10.1007/s00396-004-1123-2

[10] Samuelsson J, Sundell PE, Johansson M. Synthesis and polymerization of a radiation curable hyperbranched resin based on epoxy functional fatty acids. Progress in Organic Coatings. 2004;50(3):193-8.

DOI: 10.1016/j.porgcoat.2004.02.005

[11] Wang Z, Tong S. Synthesis and characterization of hyperbranched polyester amide polymers for coatings. Paint & Coatings Industry. 2005(11):9-12+70 (In Chinese with English abstract).

[12] Tsubokawa N, Hayashi S, Nishimura J. Grafting of hyperbranched polymers onto ultrafine silica: postgraft polymerization of vinyl monomers initiated by pendant initiating groups of polymer chains grafted onto the surface. Progress in Organic Coatings. 2002;46(2):193-201.

DOI: 10.1016/s0300-9440(01)00252-1

[13] Itoh T, Horii S, Hashimoto S, Uno T, Kubo M. Polymer electrolytes plasticized with hyperbranched polymer for lithium polymer batteries. Ionics. 2004;10(5-6):450-7.

DOI: 10.1007/bf02378007

[14] Xiao W, Hu J, Xu W. Advance in synthesis and applications of hyperbranched polymers. Chemical Industry and Engineering Progress. 2007(09):1253-7 (In Chinese with English abstract).

[15] Wang H, Pu X. The Structure and Properties of a Novel Hydroxyl‐Terminated Hyperbranched Polymer for Inhibiting Shale Hydration. ChemistrySelect. 2019;4(38).

DOI: 10.1002/slct.201902524

[16] Zhou C. Progress in synthesis and application of new hyperbranched polymers. China Rubber/Plastics Technology and Equipment(In Chinese with English Abstract). 2019(14):10.

[17] Sun P. Preparation and Properties of Polylactic acid-based Biomedical Composites Changchun University of Technology; (2019).

[18] Rothen-Weinhold A, Besseghir K, Vuaridel E, Sublet E, Oudry N, Kubel F, et al. Injection-molding versus extrusion as manufacturing technique for the preparation of biodegradable implants. European journal of pharmaceutics and biopharmaceutics. 1999;48(2):113-21.

DOI: 10.1016/s0939-6411(99)00034-x

[19] Tchernof A, Bélanger C, Morisset A-S, Richard C, Mailloux J, Laberge P, et al. Regional differences in adipose tissue metabolism in women: minor effect of obesity and body fat distribution. Diabetes. 2006;55(5):1353-60.

DOI: 10.2337/db05-1439

[20] Lei Z, Bai Y, Wang S. Synthesis of high molecular weight polylactic acid from aqueous lactic acid co-catalyzed by tin (II) chloride dihydrate and succinic anhydride. Chinese Science Bulletin. 2005;50(20):2390-2.

DOI: 10.1360/982005-1208

[21] Zhao Y, Wang Z, Wang J, Mai H, Yan B, Yang F. Direct synthesis of poly (D, L‐lactic acid) by melt polycondensation and its application in drug delivery. Journal of applied polymer science. 2004;91(4):2143-50.

DOI: 10.1002/app.13354

[22] Ren Z, Lu D, Zhou T, Lei Z. Synthesis of Degradable Hyperbranched Poly (lactic Acid) by Melt Polycondesation. Journal of Lanzhou Jiaotong University (In Chinese with English abstract) 2008;27(1):164-8.

[23] Coady DJ, Engler AC, Horn HW, Bajjuri KM, Fukushima K, Jones GO, et al. Catalyst chelation effects in organocatalyzed ring-opening polymerization of lactide. ACS Macro Letters. 2012;1(1):19-22.

DOI: 10.1021/mz2000048

[24] Persson PV, Casas J, Iversen T, Córdova A. Direct Organocatalytic Chemoselective Synthesis of a Dendrimer-like Star Polyester. Macromolecules. 2006;39(8):2819-22.

DOI: 10.1021/ma0521710

[25] Parzuchowski PG, Stefańska M, Świderska A, Roguszewska M, Zybert M. Hyperbranched polyglycerols containing amine groups—Synthesis, characterization and carbon dioxide capture. Journal of CO2 Utilization. 2018;27:145-60.

DOI: 10.1016/j.jcou.2018.07.010

[26] Shi W, Huang H. Progress in Hyperbranched Polymers. Chemical Journal of Chinese Universities (In Chinese with English abstract). 1997(08):1398-405 (In Chinese with English abstract).

[27] Bourissou D, Martin-Vaca B, Dumitrescu A, Graullier M, Lacombe F. Controlled Cationic Polymerization of Lactide. Macromolecules. 2005;38(24):9993-8.

DOI: 10.1021/ma051646k

[28] Shen X, Xiao N, Li J. The synthesis and analysis of PLLA. Applied Science and Technology. 2008;035(012):54-9 (In Chinese with English abstract).

[29] Liu H, Wang X, Zhang L. Synthesis of High Molecular Weight Poly Lactic Acid by Lactide Ring-opening Polymerization. Guangzhou Chemical Industry (In Chinese with English abstract). 2015;43(16):123-6+89(In Chinese with English abstract).

[30] Burillo G, Castillo-Rojas S, Arrieta H. Cu (II) immobilization in AAc/NIPAAm-based polymer systems synthesized using ionizing radiation. Radiation Physics and Chemistry. 2012;81(3):278-83.

DOI: 10.1016/j.radphyschem.2011.11.010

[31] Qin X, Chen Y. Research progress in synthesis and application of hyperbranched polymers. New chemical materials. 2020;48(7):6-10.