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HomeKey Engineering MaterialsKey Engineering Materials Vol. 911Effect of ZnO, SiO2 and Al2O3 Doped on...

Effect of ZnO, SiO₂ and Al₂O₃ Doped on Morphological, Optical, Structural and Mechanical Properties of Polylactic Acid

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Abstract:

In this study, an experimental investigation of the effect of addition of Alumina (Al₂O₃), Zinc Oxide (ZnO), and Silicon Oxide (SiO₂) particles powders on the mechanical behavior and crystallinity of the PLA films was carried. Granulated of Polylactic acid (PLA) and ceramic powders with different concentrations were prepared to form PLA/ZnO and PLA/ZnO-SiO₂-Al₂O₃ composites films using a solvent casting process. Morphology of PLA and composite films were examined by optical microscopy, chemical and crystal structures of composites are analyzed by (ATR-FTIR) spectroscopy and XRD techniques. Tensile strength and young modulus are determined by traction test. The obtained result by optical microscopy shows the micrograph of PLA samples with different composition are evenly distributed on the film surface. The intensity of the absorption band located at 754 cm^-1 which correspond to the crystalline phase of PLA is verified by the ATR-FTIR characterization. The XRD diffraction shows that the ceramic particles influence on the peaks intensity of PLA films localized at 19.5 ° C and 22.5 ° C, which indicate an augmentation in the crystallinity of the composite films. Mechanical tests show Tensile strength and Elasticity modulus are improved after the addition of Oxide Particles to Polylactic acid films.

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Materials Engineering and Science II

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Periodical:

Key Engineering Materials (Volume 911)

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105-113

DOI:

https://doi.org/10.4028/p-79tw2s

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Online since:

February 2022

Authors:

Amirouche Bouamer*, Abderrahmane Younes

Keywords:

Crystallinity, Mechanical Behavior, Optical Properties, Oxides Particles, Poly Lactic Acid (PLA)

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© 2022 Trans Tech Publications Ltd. All Rights Reserved

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[1] Ding, L. Bo, J. Rui, and J. T. Li, Preparation and Properties of PLA/Nano-ZnO Composite, Applied Mechanics and Materials 392 (2013) 41-45.

DOI: 10.4028/www.scientific.net/amm.392.41

[2] R.G. Sinclair, The Case for Polylactic Acid as a Commodity Packaging Plastic, Journal of Macromolecular Science, Part A, 33 (2006) 585-597.

DOI: 10.1080/10601329608010880

[3] R. Auras, B. Harte, S. Selke, An Overview of Polylactides as Packaging Materials, Macromolecular Bioscience 4 (2004) 835-864.

DOI: 10.1002/mabi.200400043

[4] Zheng, H. Juan, Z. W. Zhao, Y. L. Liu, X. F. Zhao, and K. H. Xi., Preparation of PLA/Nano-ZnO Composites, Advanced Materials Research, 476–478 (2012)1901- (1904).

DOI: 10.4028/www.scientific.net/amr.476-478.1901

[5] C. Mana, C. Zhang, Y. Liu, W. Wang, W. Ren, L. Jiang, F. Reisdorffer, T. Phap Nguyen, Y. Dana, Poly (lactic acid)/titanium dioxide composites: Preparation and performance under ultraviolet irradiation", Polymer Degradation and Stability, 97 (2012) 856-862.

DOI: 10.1016/j.polymdegradstab.2012.03.039

[6] M. S. Nasab; M. Tabari; M. H. Azizi. Morphological and mechanical properties of Poly (lactic Acid) /zinc oxide nanocomposite films, Nanomedicine Research Journal, 3 (2018) 96-101.

[7] M. Ranjbar, G. D. Noudeh, M. A. Hashemipour, I. Mohamadzadeh, A systematic study and effect of PLA/Al2O3 nanoscaffolds as dental resins: mechanochemical properties, Artificial Cells, Nanomedicine, and Biotechnology, 47 (2019) 201-209.

DOI: 10.1080/21691401.2018.1548472

[8] X. Wen, K. Zhang, Y. Wang, L. Han, C. Han, H. Zhang, S. Chen, L. Dong, Study of the thermal stabilization mechanism of biodegradable poly(L-lactide)/silica nanocomposites, Polymer International 60 (2011) 202-210.

DOI: 10.1002/pi.2927

[9] J.W. Huang, Y.C. Hung, Y.L. Wen, C.C. Kang, M.Y. Yeh, Polylactide/nano- and micro-scale silica composite films. II. Melting behavior and cold crystallization, Journal of Applied Polymer Science 112 (2009) 3149-3156.

DOI: 10.1002/app.29699

[10] P.A. Tsai, W.M. Chiu, C.E. Lin &J.H. Wu, Fabrication and Characterization of PLA/SiO2/Al2O3 Composites Prepared by Sol-Gel Process 52 (2013)1488-1495.

DOI: 10.1080/03602559.2013.820751

[11] Li, X. Dong, J. M. Tian, C. Wang, and L. M. Dong., Surface Crystallization of ZnO-Al2O3-SiO2 Glass. Key Engineering Materials 280-283 (2007)1655-1658.

DOI: 10.4028/www.scientific.net/kem.280-283.1655

[12] Ehrt, Doris, H.T. Vu, A. Herrmann, and Günter Völksch. Luminescent ZnO-Al2O3-SiO2 Glasses and Glass Ceramics., Advanced Materials Research 39-40 (2008) 231-236.

DOI: 10.4028/www.scientific.net/amr.39-40.231

[13] B. Mailhot, A. Rivaton, J.L. Gardette, A. Moustaghfir, E. Tomasella, M. Jacquet, X.G. Ma, K. Komvopoulos, Enhancement of the photoprotection and nanomechanical properties of polycarbonate by deposition of thin ceramic coatings, Journal of Applied Physics 99 (104310) (2006)1- 7.

DOI: 10.1063/1.2197030

[14] R. Yang, Y. Li, J. Yu, Photo-stabilization of linear low density polyethylene by inorganic nano-particles, Polymer Degradation and Stability 88 (2005)168-174.

DOI: 10.1016/j.polymdegradstab.2003.12.005

[15] M. Murariu, A. Doumbia, L. Bonnaud, A. L. Dechief, Y. Paint, M. Ferreira, C. Campagne, E. Devaux, and P. Dubois, High-Performance Polylactide/ZnO Nanocomposites Designed for Films and Fibers with Special End-Use Properties, Biomacromolecules 12 (2011) 1762-1771.

DOI: 10.1021/bm2001445

[16] J. Shojaeiarani, D. Bajwa, L. Jiang, J. Liaw, K. Hartman, Insight on the influence of nano zinc oxide on the thermal, dynamic mechanical, and flow characteristics of Poly (lactic acid)– zinc oxide composites, Polymer Engineering and Science 59 (2019) 1242-1249.

DOI: 10.1002/pen.25107

[17] J.T. Yeh, W.L. Chai, C.S. Wu, Study on the Preparation and Characterization of Biodegradable Polylactide/SiO2–TiO2 Hybrids, Polymer-Plastics Technology and Engineering 47(2008) 887-894.

DOI: 10.1080/03602550802189076

[18] J.W. Huang, Y. C. Hung, Y.L. Wen, C.C. Kang, M.Y. Yeh, Polylactide/nano and microscale silica composite films. I. Preparation and characterization, Journal of Applied Polymer Science 112 (2009) 1688-1694.

DOI: 10.1002/app.29616

[19] S. Shankar, L.F. Wang, J.W. Rhim, Incorporation of zinc oxide nanoparticles improved the mechanical, water vapor barrier, UV-light barrier, and antibacterial properties of PLA-based nanocomposite films, Materials Science and Engineering: C 93 (2018) 289-298.

DOI: 10.1016/j.msec.2018.08.002

[20] P. Qu, Y. Goa, G.F. Wu, and L.P. Zhang, Nanocomposite of poly (lactid acid) reinforced with cellulose nanofibrils, BioResources 5 (2010) 1811-1823.

[21] X. Wen, Y. Lin, C. Han, K. Zhang, X. Ran, Y. Li, L. Dong, Thermomechanical and optical properties of biodegradable poly(L-lactide)/silica nanocomposites by melt compounding, Journal of Applied Polymer Science 114 (2009) 3379-3388.

DOI: 10.1002/app.30896

[22] A. Bouamer, N. Benrekaa, A. Younes and H. Amar, Characterization of the Polylactic acid stretched uniaxial and annealed by Raman spectrometry and Differential scanning calorimetry. IOP Conference Series.: Material Science Engineering 461(2018) 1-6.

DOI: 10.1088/1757-899x/461/1/012006

[23] E. P. Elisabeta, M. Râpă, O. Popa, G. Mustatea,V. I. Popa, A. C. Mitelut, M. Elena, Polylactic Acid/Cellulose Fibres Based Composites for Food Packaging Applications, Material Plastice 4(2017) 673-677.

DOI: 10.37358/mp.17.4.4923

[24] Z. Chu, T. Zhao, L. Li, J. Fan, and Y. Qin, Characterization of Antimicrobial Poly (Lactic Acid)/Nano-Composite Films with Silver and Zinc Oxide Nanoparticles, Materials 6 (2017) 1-13.

DOI: 10.3390/ma10060659

[25] I. Kim, K. Viswanathan, G. Kasi, K. Sadeghi, S. Thanakkasaranee and J. Seo, Poly (Lactic Acid)/Zno Bionanocomposite Films with Positively Charged Zno as Potential Antimicrobial Food Packaging Materials, Polymers 11 (2019) 1-17.

DOI: 10.3390/polym11091427

[26] I. Restrepo, N. Benito, C. Medinam, R. V. Mangalaraja, P. Flores, L. Rodriguez-, S. lamazares, Development and characterization of polyvinyl alcohol stabilized polylactic acid/ZnO nanocomposites, Materials Research Express 4 (2017) 1-23.

DOI: 10.1088/2053-1591/aa8b8d

[27] N.A. Ali, I.A. AL-Ajaj, F.T.M. Noori, Effect of Nano SiO2 on Some Mechanical Properties of Biodegradable Polylactic Acid, International Journal of Mechanical Engineering and Technology 5(2014) 1-7.

[28] J.H. Wu, M.S. Yen, C.P. Wu, C.H. Li & M. C. Kuo, Effect of Biaxial Stretching on Thermal Properties, Shrinkage and Mechanical Properties of Poly (Lactic Acid) Films, Journal of Polymers and the Environment 21(2013) 303-311.

DOI: 10.1007/s10924-012-0523-5

[29] I. R. Mustapa, R.A. Shanks and I. Kong, Melting Behavior and Dynamic Mechanical Properties of Poly (lactic acid)-Hemp Nanosilica Composites, Asian Transactions on Basic and Applied Sciences 3 (2013) 29-37.

[30] X. Wen, One-pot route to graft long-chain polymer onto silica nanoparticles and its application for high performance poly(L-lactide) nanocomposites, The Royal Society of Chemistry 9 (2019) 13908-13915.

DOI: 10.1039/c9ra01360a