Physical Properties Modification of Co-Precipitated CoLa_0.1Fe_1.9O₄ Nanoparticle with Different Fe³⁺ Raw Material

Abstract:

Lanthanum-substituted cobalt ferrite nanoparticles (CoLa_0.1Fe_1.9O₄) with different Fe³⁺ cation sources i.e., using standard chemical lab (sample A) and a Bengawan Solo River fine sediment (sample B), were synthesized using the co-precipitation method. FTIR analysis showed that the absorption of the two nanoparticles sample appeared at a peak of v₁=586.39 cm^-1, whereas the v₂ appear at 461.97/cm and 435.93/cm respectively. It is suggested that the La³⁺ cation has succeeded in replacing the original structure of the cobalt ferrite. X-ray diffraction analysis showed that nanoparticles produce using a standard chemical lab (sample A) have smaller crystallite sizes, D=18.16 nm than the natural source of fine sediment (sample B), D=24.56 nm, respectively. Furthermore, the VSM results showed that the magnitude coercive field of Hc = 3100 Oe and Hc = 100 Oe for samples A and B, respectively. Meanwhile, the obtained saturated magnetization Ms of 15.55 emu/g for sample A and the Ms is 58.40 emu/g for sample B. This result informs that if a hard magnetic material is desired then the use of lab raw materials is more promising, while if soft magnetic is desired then a natural source of fine sediment is more appropriate to use.

• Periodical: Key Engineering Materials (Volume 941)
• Pages: 191-198
• DOI: https://doi.org/10.4028/p-k1yes4
• Online since: March 2023
• Authors: Nurdiyantoro Putra Prasetya, Utari Utari, Yofentina Iriani, Budi Purnama*
• Keywords: CoLa_0.1Fe_1.9O₄, Co-Precipitation, Fine Sediment, Laboratory Materials

References

[1] H. Ghorbani, M. Eshraghi, & A. A. Sabouri Dodaran, Structural and magnetic properties of cobalt ferrite nanoparticles doped with cadmium, Physica B: Condensed Matter. 634 (2022) 413816.

DOI: 10.1016/j.physb.2022.413816

[2] S. Zhang, J. Wu, F. Li, & L. Li, Enhanced photocatalytic performance of spinel ferrite (MFe2O4, M=Zn, Mn, Co, Fe, Ni) catalysts: The correlation between morphology–microstructure and photogenerated charge efficiency, Journal of Environmental Chemical Engineering. 10 (2022) 107702.

DOI: 10.1016/j.jece.2022.107702

[3] J. N. Pavan Kumar Chintala, S. Bharadwaj, M. Chaitanya Varma, & G. S. V. R. K. Choudary, Impact of cobalt substitution on cation distribution and elastic properties of Ni–Zn ferrite investigated by X-ray diffraction, infrared spectroscopy, and Mössbauer spectral analysis, Journal of Physics and Chemistry of Solids. 160 (2022) 110298.

DOI: 10.1016/j.jpcs.2021.110298

[4] V. A. M. Brabers, Chapter 3 Progress in spinel ferrite research, Handbook of Magnetic Materials. (1995) 189–324.

DOI: 10.1016/s1567-2719(05)80032-0

[5] R. K. Kotnala, & J. Shah, Ferrite Materials, Handbook of Magnetic Materials. (2015) 291–379.

DOI: 10.1016/b978-0-444-63528-0.00004-8

[6] H. L. Andersen, M. Saura-Múzquiz, C. Granados-Miralles, E. Canévet, N. Lock, & M. Christensen, Crystalline and magnetic structure–property relationship in spinel ferrite nanoparticles, Nanoscale. 10 (2018) 14902–14914.

DOI: 10.1039/c8nr01534a

[7] C. Shu, & H. Qiao, Tuning Magnetic Properties of Magnetic Recording Media Cobalt Ferrite Nano-Particles by Co-Precipitation Method, 2009 Symposium on Photonics and Optoelectronics. (2009).

DOI: 10.1109/sopo.2009.5230167

[8] A. López-Ortega, E. Lottini, C. de J. Fernández, & C. Sangregorio, Exploring the Magnetic Properties of Cobalt-Ferrite Nanoparticles for the Development of a Rare-Earth-Free Permanent Magnet, Chemistry of Materials. 27 (2015) 4048–4056.

DOI: 10.1021/acs.chemmater.5b01034

[9] O. Caltun, I. Dumitru, M. Feder, N. Lupu, & H. Chiriac, Substituted cobalt ferrites for sensors applications, Journal of Magnetism and Magnetic Materials. 320 (2008) e869–e873.

DOI: 10.1016/j.jmmm.2008.04.067

[10] S. Swathi, R. Yuvakkumar, P. S. Kumar, G. Ravi, & D. Velauthapillai, Annealing temperature effect on cobalt ferrite nanoparticles for photocatalytic degradation, Chemosphere. 281 (2021) 130903.

DOI: 10.1016/j.chemosphere.2021.130903

[11] N. Sanpo, C. C. Berndt, & J. Wang, Microstructural and antibacterial properties of zinc-substituted cobalt ferrite nanopowders synthesized by sol-gel methods, Journal of Applied Physics. 112 (2012) 084333.

DOI: 10.1063/1.4761987

[12] E. Mazario, N. Menéndez, P. Herrasti, M. Cañete, V. Connord, & J. Carrey, Magnetic Hyperthermia Properties of Electrosynthesized Cobalt Ferrite Nanoparticles, The Journal of Physical Chemistry C. 117 (2013) 11405–11411.

DOI: 10.1021/jp4023025

[13] H. Wu, G. Liu, X. Wang, J. Zhang, Y. Chen, J. Shi, … S. Yang, Solvothermal synthesis of cobalt ferrite nanoparticles loaded on multiwalled carbon nanotubes for magnetic resonance imaging and drug delivery, Acta Biomaterialia. 7 (2011) 3496–3504. doi:10.1016/j.actbio. 2011.05.031.

DOI: 10.1016/j.actbio.2011.05.031

[14] P. Kumar, S. K. Sharma, M. Knobel, & M. Singh, Effect of La3+ doping on the electric, dielectric and magnetic properties of cobalt ferrite processed by co-precipitation technique, Journal of Alloys and Compounds. 508 (2010) 115–118.

DOI: 10.1016/j.jallcom.2010.08.007

[15] B. Purnama, R. Arilasita, N. Rikamukti, Utari, S. Budiawanti, Suharno, … K. Matsuyama, Annealing temperature dependence of crystalline structure and magnetic properties in nano-powder strontium-substituted cobalt ferrite, Nano-Structures & Nano-Objects. 30 (2022) 100862.

DOI: 10.1016/j.nanoso.2022.100862

[16] M. Sajjia, M. Oubaha, M. Hasanuzzaman, & A. G. Olabi, Developments of cobalt ferrite nanoparticles prepared by the sol–gel process, Ceramics International. 40 (2014) 1147–1154.

DOI: 10.1016/j.ceramint.2013.06.116

[17] D. T. Rahardjo, S. Budiawanti, Suharno, Y. Iriani, A. Supriyanto, & B. Purnama, Temperature sintering dependence of crystalline structure in cobalt ferrite prepared by the sol-gel auto-combustion procedure, Journal of Physics: Conference Series. 1951 (2021) 012026.

DOI: 10.1088/1742-6596/1951/1/012026

[18] Y. Köseoğlu, F. Alan, M. Tan, R. Yilgin, & M. Öztürk, Low temperature hydrothermal synthesis and characterization of Mn doped cobalt ferrite nanoparticles, Ceramics International. 38 (2012) 3625–3634.

DOI: 10.1016/j.ceramint.2012.01.001

[19] Shyamaldas, M. Bououdina, & C. Manoharan, Dependence of structure/morphology on electrical/magnetic properties of hydrothermally synthesised cobalt ferrite nanoparticles, Journal of Magnetism and Magnetic Materials. 493 (2020) 165703. doi: 10.1016/j.jmmm. 2019.165703.

DOI: 10.1016/j.jmmm.2019.165703

[20] F. R. Mariosi, J. Venturini, A. da Cas Viegas, & C. P. Bergmann, Lanthanum-doped spinel cobalt ferrite (CoFe2O4) nanoparticles for environmental applications, Ceramics International. 46 (2020) 2772–2779.

DOI: 10.1016/j.ceramint.2019.09.266

[21] Y. Lu, M. Yousaf, M. N. Akhtar, A. Noor, M. Akbar, M. A. K. Y. Shah, … F. Wang, Effect of Gd and Co contents on the microstructural, magneto-optical and electrical characteristics of cobalt ferrite (CoFe2O4) nanoparticles, Ceramics International. 48 (2022) 2782–2792.

DOI: 10.1016/j.ceramint.2021.10.067

[22] H. Ghorbani, M. Eshraghi, A. A. Sabouri Dodaran, P. Kameli, S. Protasowicki, C. Johnson, & D. Vashaee, Effect of Yb doping on the structural and magnetic properties of cobalt ferrite nanoparticles, Materials Research Bulletin. 147 (2022) 111642. doi:10.1016/j.materresbull. 2021.111642.

DOI: 10.1016/j.materresbull.2021.111642

[23] M. Gupta, A. Das, S. Dutta, S. Mohapatra, & A. Datta, Magnetic and Mössbauer Study of Lanthanum Doped Nanosized Cobalt Ferrite Assembly, SSRN Electronic Journal. (2022).

DOI: 10.2139/ssrn.4085275

[24] A. T. Mubarok, H. Widiyandari, Utari, & B. Purnama, Annealing Temperature Effects in Co-Precipitated CoFe2O4 Nanoparticles Using Bengawan Solo River Fine Sediment, Key Engineering Materials. 855 (2020) 64–69.

DOI: 10.4028/www.scientific.net/kem.855.64

[25] R. I. Setiyani, Utari, Y. Iriani, & B. Purnama, Comparison of the Crystalline Structure and Magnetic Properties in Coprecipitated CoFe2O4 and CoLa0.1Fe1.9O4, Key Engineering Materials. 855 (2020) 16–21.

DOI: 10.4028/www.scientific.net/kem.855.16

[26] M. Gharagozlu, Synthesis and characterization of nanocrystalline magnetic pigmen via coordinated precursors, Progress in Color, Colorants and Coatings. 2 (2009) 35-43. https://www.sid.ir/en/journal/ViewPaper.aspx?id=226537.

[27] H. Kumar, J. P. Singh, R. C. Srivastava, P. Negi, H. M. Agrawal, & K. Asokan, FTIR and Electrical Study of Dysprosium Doped Cobalt Ferrite Nanoparticles, Journal of Nanoscience. 2014 (2014) 1–10.

DOI: 10.1155/2014/862415

[28] M. A. Amer, T. M. Meaz, S. S. Attalah, & A. I. Ghoneim, Structural phase transformation of as-prepared Mg–Mn nanoferrites by annealing temperature, Materials Characterization. 110 (2015) 197–207.

DOI: 10.1016/j.matchar.2015.10.032

[29] E. H. El-Ghazzawy, Effect of heat treatment on structural, magnetic, elastic and optical properties of the co-precipitated Co0.4Sr0.6Fe2O4, Journal of Magnetism and Magnetic Materials. 497 (2020) 166017.

DOI: 10.1016/j.jmmm.2019.166017

[30] B. Abraime, K. El Maalam, L. Fkhar, A. Mahmoud, F. Boschini, M. Ait Tamerd, … O. Mounkachi, Influence of synthesis methods with low annealing temperature on the structural and magnetic properties of CoFe2O4 nanopowders for permanent magnet application, Journal of Magnetism and Magnetic Materials. 500 (2020) 166416. doi:10.1016/j.jmmm.2020. 166416.

DOI: 10.1016/j.jmmm.2020.166416

[31] M. Kaur, S. Rana, & P. S. Tarsikka, Comparative analysis of cadmium doped magnesium ferrite Mg(1−x) Cdx Fe2O4 (x=0.0, 0.2, 0.4, 0.6) nanoparticles, Ceramics International. 38 (2012) 4319–4323.

DOI: 10.1016/j.ceramint.2012.02.013

[32] Y. Waseda, E. Matsubara, & K. Shinoda, Scattering and Diffraction, X-Ray Diffraction Crystallography. (2011) 67–106.

DOI: 10.1007/978-3-642-16635-8_3

[33] M. Nazarkovsky, B. Czech, A. Żmudka, V. M. Bogatyrov, O. Artiushenko, V. Zaitsev, … J. Dupont, Structural, optical and catalytic properties of ZnO-SiO2 colored powders with the visible light-driven activity, Journal of Photochemistry and Photobiology A: Chemistry. 421 (2021) 113532.

DOI: 10.1016/j.jphotochem.2021.113532

[34] Y. Jiang, R. C. Gu, M. Peterlechner, Y. W. Liu, J. T. Wang, & G. Wilde, Impurity effect on recrystallization and grain growth in severe plastically deformed copper, Materials Science and Engineering: A. 824 (2021) 141786.

DOI: 10.1016/j.msea.2021.141786

[35] C. Suryanarayana, & M. G. Norton, Practical Aspects of X-Ray Diffraction, X-Ray Diffraction. (1998) 63–94.

DOI: 10.1007/978-1-4899-0148-4_3

[36] A. K. Kole, & P. Kumbhakar, Cubic-to-hexagonal phase transition and optical properties of chemically synthesized ZnS nanocrystals, Results in Physics. 2 (2012) 150–155.

DOI: 10.1016/j.rinp.2012.09.010

[37] M. Yousaf, M. N. Akhtar, B. Wang, & A. Noor, Preparations, optical, structural, conductive and magnetic evaluations of RE's (Pr, Y, Gd, Ho, Yb) doped spinel nanoferrites, Ceramics International. 46 (2020) 4280-4288. doi.org/.

DOI: 10.1016/j.ceramint.2019.10.149

[38] Nitika, A. Rana, V. Kumar, & A. M. Awasthi, Effect of dopant concentration and annealing temperature on electric and magnetic properties of lanthanum substituted CoFe2O4 nanoparticles for potential use in 5G wireless communication systems, Ceramics International. 47 (2021) 20669–20677.

DOI: 10.1016/j.ceramint.2021.04.077