Research of Modified Polyamide Waste Agglomerate: Regulatory Issues and Technological Features

Article Preview

Abstract:

In this article, a regulatory processes study and technological properties of polyamide waste agglomerate modification is carried out. The legal support issues for polymer waste management in Ukraine are considered, ways to improve the most problematic aspects in this area are proposed. The technological properties of polyamide-6 waste agglomerate modification processes were studied in order to improve its technological and strength characteristics. MW-PA CB10 masterbatch modifier impact on the polyamide-6 waste agglomerate technological and strength characteristics complex was studied. It was established that the best is polyamide-6 waste agglomerate with 2 % wt. of masterbatch MW-PA CB10. For this composition the impact strength is 43.5 MPa, breaking stress during bending is 126.4 MPa, tensile strength is 342 N and elongation at break is 117 %. It can be recommended for reuse in traditional fields of primary polyamide-6 to obtain engineering and technical products.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

99-106

Citation:

Online since:

September 2024

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2024 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] J. Nilsen-Nygaard, E. Noriega Fernández, T. Radusin, B.T. Rotabakk, J. Sarfaz, N. Sharmin, M. Sivertsvik, I. Sone, M.K. Petersen, Current status of biobased and biodegradable food packaging materials: Impact on food quality and effect of innovative processing technologies. Comprehensive Reviews in Food Science and Food Safety. 20(2) 2021 1333–1380.

DOI: 10.1111/1541-4337.12715

Google Scholar

[2] V.R. Feig, H. Tran, Z.Bao, Biodegradable polymeric materials in degradable electronic devices. ACS Central Science. 4 (2018) 337–348.

DOI: 10.1021/acscentsci.7b00595

Google Scholar

[3] V. Lebedev, T. Tykhomyrova, I. Litvinenko, S. Avina, Z. Saimbetova, Design and Research of Eco-Friendly Polymer Composites. Materials Science Forum. 1006 (2020) 259–266.

DOI: 10.4028/www.scientific.net/msf.1006.259

Google Scholar

[4] V. Lebedev, T. Tykhomyrova, O. Filenko, A. Cherkashina, O. Lytvynenko, Sorption Resistance Studying of Environmentally Friendly Polymeric Materials in Different Liquid Mediums. Materials Science Forum. 1038 (2021)168–174.

DOI: 10.4028/www.scientific.net/msf.1038.168

Google Scholar

[5] V. Lebedev, T. Tykhomyrova, O. Lytvynenko, A. Grekova, S. Avina, Sorption characteristics studies of eco-friendly polymer composites. E3S Web of Conferences. 280 (2021) 11001.

DOI: 10.1051/e3sconf/202128011001

Google Scholar

[6] V. Lebedev, D. Miroshnichenko, Z. Xiaobin, S. Pyshyev, D. Savchenko, Technological Properties of Polymers Obtained from Humic Acids of Ukrainian Lignite, Petroleum and Coal. 63(3) (2021) 646–654.

Google Scholar

[7] V. Lebedev, D. Miroshnichenko, Z. Xiaobin, S. Pyshyev, D. Savchenko, Y. Nikolaichuk, Use of Humic Acids from Low-Grade Metamorphism Coal for the Modification of Biofilms Based on Polyvinyl Alcohol. Petroleum and Coal. 63(4) (2021) 953–962.

Google Scholar

[8] V. Lebedev, D. Miroshnichenko, T. Tykhomyrova, A. Kariev, M. Zinchenko, N. Bukatenko, O. Filenko, Design and research of environmentally friendly polymeric materials modificated by derivatives of coal, Petroleum and Coal. 65(2) (2023) 334–340.

DOI: 10.1063/5.0119925

Google Scholar

[9] V. Lebedev, D. Miroshnichenko, D. Savchenko, D. Bilets, V. Mysiak, T. Tykhomyrova, Computer Modeling of Chemical Composition of Hybrid Biodegradable Composites. Lecture Notes on Data Engineering and Communications Technologies. 178 (2023) 446–458.

DOI: 10.1007/978-3-031-35467-0_27

Google Scholar

[10] V. Lebedev, T. Tykhomyrova, Miroshnichenko, O. Filenko, A. Kariev, T. Grigorova, Design and research of environmental friendly polymeric materials modified by humic substances. AIP Conference Proceedings. 2684 (1) (2023) 040014.

DOI: 10.1063/5.0119925

Google Scholar

[11] D. Sahalai, D. Bilets, V. Lebedev, V. Mysiak, D. Miroshnichenko, A. Sinitsyna, Hybrid Biopolymer Nanocomposite Materials for Ecological and Biomedical Applications. 2022 IEEE 12th International Conference Nanomaterials: Applications & Properties (NAP). (2022) 1-5.

DOI: 10.1109/nap55339.2022.9934293

Google Scholar

[12] V. Lebedev, D. Miroshnichenko, D. Bilets, T. Tykhomyrova, O. Tsereniuk, N. Krygina, Design And Researching Conductive Hybrid Biopolymer Nanocomposite Materials For Micro-And Nanoelectronics. 2022 IEEE 3rd KhPI Week on Advanced Technology (KhPIWeek). (2022) 1–4.

DOI: 10.1109/khpiweek57572.2022.9916360

Google Scholar

[13] E. Bäckström, K. Odelius, M. Hakkarainen, Designed from recycled: turning polyethylene waste to covalently attached polylactide plasticizers. ACS Sustainable Chemistry & Engineering. 7 (2019) 11004–11013.

DOI: 10.1021/acssuschemeng.9b02092

Google Scholar

[14] R. Fiorentino, G. Preka, R. De Carolis, G. Barberio, The challenge of plastics in a circular perspective. Frontiers in Sustainable Cities. 4 (2022) 920242.

DOI: 10.3389/frsc.2022.920242

Google Scholar

[15] C. Alberti, R. Figueira, M. Hofmann, S. Koschke, S. Enthaler, Chemical recycling of end-of-life polyamide 6 via ring closing depolymerization. Chemistry Select. 4 (2019) 12638–12642.

DOI: 10.1002/slct.201903970

Google Scholar

[16] M. Rides, C. Allen, H. Omloo, K. Nakayama, G. Cancelli, Interlaboratory comparison of melt flow rate testing of moisture sensitive plastics, Polymer Testing. 28 (2009) 572–591.

DOI: 10.1016/j.polymertesting.2009.03.013

Google Scholar

[17] R. Buchdahl, D.A. Zaukelies, Deformationsprozesse und die struktur von kristallinen polymeren, angew. Angewandte Chemie. 74 (1962) 569–573.

DOI: 10.1002/ange.19620741509

Google Scholar

[18] A. K. Sokolova, T. В. Vilchyk, M. K. Cherkashyna, Ensuring the environmental rights as a prerequisite for the rights to health in Ukraine and the European Union. Wiadomości lekarskie. LXXII (12 (II)) (2019) 2489–2495.

Google Scholar

[19] A. K. Sokolova, M. K. Cherkashyna, Legal aspects of using natural resources for health and recreational purposes to ensure human right to health care. Wiadomości lekarskie. LXXIV (11(2)) (2021) 3077–3084.

DOI: 10.36740/wlek202111237

Google Scholar

[20] A. Sokolova, M. Cherkashyna, The legal regulation of the use of natural healing resources: the theory and practice of disputes resolution. Access to Justice in Eastern Europe. 2(10) (2021) 144–163.

DOI: 10.33327/ajee-18-4.2-n000065

Google Scholar

[21] Decision of the National Security and Defense Council of Ukraine "On challenges and threats to the national security of Ukraine in the environmental sphere and priority measures for their neutralization" dated March 23, 2021.

Google Scholar

[22] Law of Ukraine "On the Basic Principles (Strategy) of State Environmental Policy for the Period Until 2030" dated February 28 (2019). https://zakon.rada.gov.ua/laws/show/2697-19#Text (accessed on 15 March 2024) [in Ukrainian].

Google Scholar

[23] Law of Ukraine "On Environmental Protection" dated June 25, 1991 URL: https://zakon.rada.gov.ua/laws/show/1264-12#Text (accessed on 15 March 2024) [in Ukrainian].

Google Scholar

[24] Directive 2008/98/EC of the European Parliament and of the Council of 19 November 2008 on waste and repealing certain Directives.

Google Scholar

[25] Directive (EU) 2018/851 of the European Parliament and of the Council of 30 May 2018 amending Directive 2008/98/EC on waste.

Google Scholar

[26] Directive 94/62/EC of European Parliament and Council of 20 December 1994 on packaging and packaging waste.

DOI: 10.1093/jel/7.2.323

Google Scholar

[27] On the approval of the National Waste Management Strategy in Ukraine until 2030: Decree of the Cabinet of Ministers of Ukraine dated November 8, 2017 No. 820-p. https://zakon.rada.gov.ua/laws/show/820-2017-%D1%80#Text (accessed on 15 March 2024).

Google Scholar

[28] On waste management: Law of Ukraine dated June 20, 2022 No. 2320-IX. Official Gazette of Ukraine, 2022. No. 56. p.21. Art. 3270. https://zakon.rada.gov.ua/laws/show/2320-20#Text (accessed on 15 March 2024) [in Ukrainian].

Google Scholar

[29] Association Agreement between Ukraine, on the one hand, and the European Union, the European Atomic Energy Community and their member states, on the other hand. https://zakon.rada.gov.ua/laws/show/984_011#Text (accessed on 15 March 2024) [in Ukrainian].

DOI: 10.37405/1729-7206.2020.2(39).201-205

Google Scholar

[30] Basel convention on the control of transboundary transportation of hazardous wastes and their disposal adopted on 22 March 1989 //Website of Basel convention on the control of transboundary transportation of hazardous wastes and their disposal adopted on 22 March 1989. https://www.basel.int/Portals/4/Basel%20Convention/docs/text/BaselConvention Texte.pdf (accessed on 15 March 2024).

DOI: 10.18356/529fe93d-en-fr

Google Scholar