Studies of Structural and Optical Properties of Nickel Chloride and Glycine Doped Potassium Hydrogen Phthalate (KHP) Crystal

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A semi-organic single crystal of potassium hydrogen phthalate (KHP, K(C6H4COOH.COO)) doped with Nickel Chloride (NiCl2) and Glycine (C₂H₅NO₂) was successfully harvested at room temperature to enhance the characteristics of KHP using a slow evaporation approach. The concentration of 1 mol % of Nickel Chloride and 6 mol % Glycine was used during the fabrication of the Nickel Chloride and Glycine doped KHP single crystal. Powder X-Ray diffraction (XRD), ultraviolet visible spectroscopy (UV-Vis), and Fourier transform Infrared (FTIR) analysis were used to analyze the grown single crystal. Powder XRD investigation verified an orthorhombic crystal structure and lattice parameter .To evaluate optical energy band gap and optical transparency using UV-Vis spectral. According to, FTIR analysis, and dielectric studies, it is evident that the crystal modification noticeably by adding dopant.

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December 2024

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[1] D. VijiNiraimathil and C. Shanthi. Journal of Chemical and Pharmaceutical Research. 8(3) (2016) 926-929.

Google Scholar

[2] R. K. Raju, S. M. Dharamaprakash, H. S. Jayanna. Advance in materials Physics and Chemistry. 5(10) (2015) 399-407.

Google Scholar

[3] A. Miniewicz, S. Bartkiewicz, Adv. Mater. Opt. Electron. 2 (1993) 157.

Google Scholar

[4] F. Kajzar, A. Lorin, J. Le Moigne, J. Szpunar, Acta Phys. Pol. A 87 (1995) 713.

DOI: 10.12693/aphyspola.87.713

Google Scholar

[5] M.V. Shankar, K.B.R. Varma, Ferroelectr. Lett. Sect.21 (1996) 55.

Google Scholar

[6] A.C. Sajikumara, V.T. Jishab. Materials Today: Proceedings, 11 (2019) 944–951.

Google Scholar

[7] Chityal Ganesh, Kumar Sujitha, Pombala Yedla, Poornachandra Sankalp, Vinod Agarwal. Applications of Nanobiomaterials, William Andrew, applied science publication, 6 103-152.

DOI: 10.1016/b978-0-323-42864-4.00004-x

Google Scholar

[8] Holzwarth, U., Gibson, N. The Scherer equation versus the 'Debye-Scherrer equation'. Nature Nanotech 6 (2011) 534.

DOI: 10.1038/nnano.2011.145

Google Scholar

[9] A O Bokuniaeva and A S Vorokh, Estimation of particle size using the Debye equation and the Scherrer formula for polyphasic TiO2 powder, J. Phys.: Conf. Ser. 1410 012057 (2019).

DOI: 10.1088/1742-6596/1410/1/012057

Google Scholar

[10] Swarnalatha Kurapati, Prathima Kumari Srivastava, International Journal Of Management, Technology And Engineering, 8, 12 (2018) 81-84.

Google Scholar

[11] G. K. Williamson and R. E. Smallman, Philosophical Magazine, 1 1 (1956) 34-46.

Google Scholar

[12] Adhish V. Raval, L. K. Saini, D. V. Shah and Shweta K. Patel. AIP conference proceeding. 2220(090029) (2020) 1-6.

Google Scholar

[13] M. Baig, M. Anis, M. Shirsat, S. Hussaini, H. Algarni, Optik. 203 (2020) 163903.(dielectric).

DOI: 10.1016/j.ijleo.2019.163903

Google Scholar

[14] B.C. Hemaraju, A.P. Gnana Prakash, Chemical Data Collections (2020).

Google Scholar

[15] S R Thilagavathy, P Rajesh, P Ramasamy, K Ambujam, Spectrochim Acta A Mol Biomol Spectrosc, 5 (2014) 248-255.

Google Scholar

[16] Beck L., Stemmler P, Legrand F, Rev. Sci. Instrum., 66 (1995) 1601.

Google Scholar

[17] K. Venkateswarlu, M.Sandhyarani, T. A. Nellaippn, and N. Ramesh babu, Procedia Materials Science,5 (2014) 212–221.

Google Scholar

[18] N. Sivakumar, R. Mohan Kumar and G. Anbalagan Advanced Materials Research 1662-8985, 584 ,(2012) 116-120

Google Scholar

[19] Shaikh Kalim Shaikh Hanif, A. B. Lad and B. H. Pawar Advances in Applied Science Research, 6(1) (2015) 11-14

Google Scholar

[20] S.R. Thilagavathy, P. Rajesh, P. Ramasamy, K. Ambujam Molecular and Biomolecular Spectroscopy 127 (2014) 248–255

DOI: 10.1016/j.saa.2014.01.137

Google Scholar

[21] A. C. Sajikumar and V.T. Jisha International Journal of Materials Physics 7, (2016) 1- 8

Google Scholar

[22] Rajesh Krishnana, Mani Ayyanarb, Anandan Kasinathana, Praveen Kumar Materials Research. 21(2) (2018) 20170329

Google Scholar