Synthesis and Characterizations of Nickel Supported on Activated Charcoal and its Application for Green Fuel Production

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Abstract:

Waste cooking oil (WCO) that contained triglycerides and fatty acid derivatives can be transformed to green fuel that have similar properties to the fossil fuel. Hence, this study was focusing on the production of green fuel hydrocarbons from feedstock of waste cooking oil by deoxygenation process. The deoxygenation reaction of WCO was conducted using different loading of nickel (Ni) (5, 10, 15 and 20 % w/w) supported on commercial activated charcoal. Based on the catalytic deoxygenation (DO) reaction, the highest conversion of hydrocarbon was achieved when the reaction undergo using Ni20%AC as catalyst at 350°C for 3 hours under inert atmosphere. The present of the higher loading active metal showed high DO reaction by decarboxylation and decarbonylation pathways with high hydrocarbon yield of 83% and high selectivity of n-C15 and n-C17. DO reaction also favoured the optimum strength of acidity. This study revealed that Ni20%AC catalyst is a promising catalyst for the green fuel production in WCO.

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Materials Science Forum (Volume 1010)

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424-430

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September 2020

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© 2020 Trans Tech Publications Ltd. All Rights Reserved

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[1] P. Priecel, D. Kubička, L. Čapek, Z. Bastl, and P. Ryšánek, The role of Ni species in the deoxygenation of rapeseed oil over NiMo-alumina catalysts,, Appl. Catal. A Gen., vol. 397, no. 1–2, p.127–137, (2011).

DOI: 10.1016/j.apcata.2011.02.022

Google Scholar

[2] J. K. Satyarthi and D. Srinivas, Fourier Transform Infrared Spectroscopic Method for Monitoring Hydroprocessing of Vegetable Oils To Produce Hydrocarbon-Based Biofuel,, Energy and Fuels, vol. 25, p.3318–3322, (2011).

DOI: 10.1021/ef200722q

Google Scholar

[3] H. S. Roh, I. H. Eum, D. W. Jeong, B. E. Yi, J. G. Na, and C. H. Ko, The effect of calcination temperature on the performance of Ni/MgO-Al2O3catalysts for decarboxylation of oleic acid,, Catal. Today, vol. 164, no. 1, p.457–460, (2011).

DOI: 10.1016/j.cattod.2010.10.048

Google Scholar

[4] T. Morgan, D. Grubb, E. Santillan-Jimenez, and M. Crocker, Conversion of triglycerides to hydrocarbons over supported metal catalysts,, Top. Catal., vol. 53, no. 11–12, p.820–829, (2010).

DOI: 10.1007/s11244-010-9456-1

Google Scholar

[5] N. Asikin-mijan, H. V Lee, T. S. Marliza, and Y. H. Taufiq-Yap, Pyrolytic-deoxygenation of triglycerides model compound and non-edible oil to hydrocarbons over SiO 2 -Al 2 O 3 supported NiO-CaO catalysts,, J. Anal. Appl. Pyrolysis, vol. 129, no. November 2017, p.221–230, (2018).

DOI: 10.1016/j.jaap.2017.11.009

Google Scholar

[6] G. Abdulkareem-Alsultan, N. Asikin-mijan, H. V. Lee, A. S. Albazzaz, and Y. H. Taufiq-Yap, Deoxygenation of waste cooking to renewable diesel over walnut shell- derived nanorode activated carbon supported CaO-La 2 O 3 catalyst,, Energy Convers. Manag., vol. 151, no. October, p.311–323, (2017).

DOI: 10.1016/j.enconman.2017.09.001

Google Scholar

[7] L. K. H. Pham et al., Formation and activity of activated carbon supported Ni 2 P catalysts for atmospheric deoxygenation of waste cooking oil,, Fuel Process. Technol., vol. 185, no. December 2018, p.117–125, (2019).

DOI: 10.1016/j.fuproc.2018.12.009

Google Scholar

[8] C. Kordulis, K. Bourikas, M. Gousi, E. Kordouli, and A. Lycourghiotis, Development of nickel based catalysts for the transformation of natural triglycerides and related compounds into green diesel: A critical review,, Appl. Catal. B Environ., vol. 181, p.156–196, (2016).

DOI: 10.1016/j.apcatb.2015.07.042

Google Scholar

[9] S. Zulkepli, J. C. Juan, H. V. Lee, N. S. A. Rahman, P. L. Show, and E. P. Ng, Modified mesoporous HMS supported Ni for deoxygenation of triolein into hydrocarbon-biofuel production,, Energy Convers. Manag., vol. 165, no. December 2017, p.495–508, (2018).

DOI: 10.1016/j.enconman.2018.03.087

Google Scholar

[10] N. Asikin-Mijan, H. V. Lee, G. Abdulkareem-Alsultan, A. Afandi, and Y. H. Taufiq-Yap, Production of green diesel via cleaner catalytic deoxygenation of Jatropha curcas oil,, J. Clean. Prod., vol. 167, p.1048–1059, (2017).

DOI: 10.1016/j.jclepro.2016.10.023

Google Scholar

[11] L. N. Silva, I. C. P. Fortes, F. P. De Sousa, and V. M. D. Pasa, Biokerosene and green diesel from macauba oils via catalytic deoxygenation over Pd / C,, Fuel, vol. 164, p.329–338, (2016).

DOI: 10.1016/j.fuel.2015.09.081

Google Scholar

[12] B. C. Ang, I. I. Yaacob, and I. Nurdin, Investigation of Fe2O3/SiO2 Nanocomposite by FESEM and TEM,, J. Nanomater., vol. 2013, no. March 2013, (2013).

Google Scholar

[13] N. Asikin-Mijan et al., Promoting deoxygenation of triglycerides via Co-Ca loaded SiO2-Al2O3catalyst,, Appl. Catal. A Gen., vol. 552, no. August 2017, p.38–48, (2018).

DOI: 10.1016/j.apcata.2017.12.020

Google Scholar

[14] G. Abdulkareem-Alsultan, N. Asikin-Mijan, H. V. Lee, and Y. H. Taufiq-Yap, A new route for the synthesis of La-Ca oxide supported on nano activated carbon via vacuum impregnation method for one pot esterification-transesterification reaction,, Chem. Eng. J., vol. 304, p.61–71, (2016).

DOI: 10.1016/j.cej.2016.05.116

Google Scholar

[15] E. Santillan-Jimenez and M. Crocker, Catalytic deoxygenation of fatty acids and their derivatives to hydrocarbon fuels via decarboxylation/decarbonylation,, J. Chem. Technol. Biotechnol., vol. 87, no. 8, p.1041–1050, (2012).

DOI: 10.1002/jctb.3775

Google Scholar