Synthesis of Patchouli Acetate and Propionate from Patchouli Oil through Esterification Reaction Using Homogeneous and Heterogeneous Catalysts

Priatmoko Priatmoko; Muhammad Idham Darussalam Mardjan; Vera Juniati

doi:10.4028/p-3cv57p

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HomeMaterials Science ForumMaterials Science Forum Vol. 1061Synthesis of Patchouli Acetate and Propionate from...

Synthesis of Patchouli Acetate and Propionate from Patchouli Oil through Esterification Reaction Using Homogeneous and Heterogeneous Catalysts

Abstract:

Synthesis of patchouli acetate and propionate from patchouli oil and carboxylic acids (acetic acid and propionic acid) has been carried out through esterification reaction. The reaction was carried out at 100 °C for 3 h in the presence of homogeneous (HCl and H₂SO₄) and heterogeneous (activated zeolite) catalysts. The esterification products were characterized using Fourier Transform Infrared Spectrometer and Gas Chromatography-Mass Spectrometer. The results showed that the reaction using acetic acid as the acid precursor in the presence of HCl, H₂SO₄, and zeolite gave patchouli acetate in 42, 48, and 38%, respectively. In addition, the esterification of patchouli oil using propionic acid in the presence of HCl, H₂SO₄, and zeolite produced patchouli propionate in 40, 54, and 36%, respectively.

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Periodical:

Materials Science Forum (Volume 1061)

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157-161

DOI:

https://doi.org/10.4028/p-3cv57p

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Online since:

May 2022

Authors:

Priatmoko Priatmoko*, Muhammad Idham Darussalam Mardjan, Vera Juniati

Keywords:

Heterogeneous Catalyst, Homogeneous Catalyst, Patchouli Acetate, Patchouli Oil, Patchouli Propionate

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